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arXiv:2104.12173 · Physical review. E

Bounds on fluctuations for finite-time quantum Otto cycle

Sushant Saryal, Bijay Kumar Agarwalla

Published Jun 25, 2021• 32 citations
arXivHTMLPDF

Abstract

For quantum Otto engine driven quasistatically, we provide exact full statistics of heat and work for a class of working fluids that follow a scale-invariant energy eigenspectra under driving. Equipped with the full statistics we go on to derive a universal expression for the ratio of nth cumulant of output work and input heat in terms of the mean Otto efficiency. Furthermore, for nonadiabatic driving of quantum Otto engine with working fluid consisting of either a (i) qubit or (ii) a harmonic oscillator, we show that the relative fluctuation of output work is always greater than the corresponding relative fluctuation of input heat absorbed from the hot bath. As a result, the ratio between the work fluctuation and the input heat fluctuation receives a lower bound in terms of the square value of the average efficiency of the engine. The saturation of the lower bound is received in the quasistatic limit of the engine.

DOI
10.1103/physreve.103.l060103

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For quantum Otto engine driven quasistatically, we provide exact full statistics of heat and work for a class of working fluids that follow a scale-invariant energy eigenspectra under driving. Equipped with the full statistics we go on to derive a universal expression for the ratio of nth cumulant of output work and input heat in terms of the mean Otto efficiency. Furthermore, for nonadiabatic driving of quantum Otto engine with working fluid consisting of either a (i) qubit or (ii) a harmonic oscillator, we show that the relative fluctuation of output work is always greater than the corresponding relative fluctuation of input heat absorbed from the hot bath. As a result, the ratio between the work fluctuation and the input heat fluctuation receives a lower bound in terms of the square value of the average efficiency of the engine. The saturation of the lower bound is received in the quasistatic limit of the engine.
For a four-stroke asymmetrically driven quantum Otto engine with working medium modeled by a single qubit, we study the bounds on nonequilibrium fluctuations of work and heat. We find strict relations between the fluctuations of work and individual heat for hot and cold reservoirs in arbitrary operational regimes. Focusing on the engine regime, we show that the ratio of nonequilibrium fluctuations of output work to input heat from the hot reservoir is both upper and lower bounded. As a consequence, we establish a hierarchical relation between the relative fluctuations of work and heat for both cold and hot reservoirs and further make a connection with the thermodynamic uncertainty relations. We discuss the fate of these bounds also in the refrigerator regime. The reported bounds, for such asymmetrically driven engines, emerge once both the time-forward and the corresponding reverse cycles of the engine are considered on an equal footing. We also extend our study and report bounds for a parametrically driven harmonic oscillator Otto engine.
Recently, measurement-based quantum thermal machines have drawn more attention in the field of quantum thermodynamics. However, the previous results on quantum Otto heat engines were either limited to special unital and nonunital channels in the bath stages, or a specific driving protocol at the work strokes and assuming the cycle being time-reversal symmetric, i.e., V^{†}=U (or V=U). In this paper, we consider a single spin-1/2 quantum Otto heat engine, by first replacing one of the heat baths by an arbitrary unital channel, and then we give the exact analytical expression of the characteristic function from which all the cumulants of heat and work emerge. We prove that under the effect of monitoring, ν_{2}>ν_{1} is a necessary condition for positive work, either for a symmetric or asymmetric-driven Otto cycle. Furthermore, going beyond the average we show that the ratio of the fluctuations of work and heat is lower and upper-bounded when the system is working as a heat engine. However, differently from the previous results in the literature, we consider the third and fourth cumulants as well. It is shown that the ratio of the third (fourth) cumulants of work and heat is not upper-bounded by unity nor lower-bounded by the third (fourth) power of the efficiency, as is the case for the ratio of fluctuations. Finally, we consider applying a specific unital map that plays the role of a heat bath in a coherently superposed manner, and we show the role of the initial coherence of the control qubit on efficiency, on the average work and its relative fluctuations.
In this work we study the effect of quantum and thermal fluctuations on the statistics of quantum heat engine performance parameters, like efficiency and power. We begin by deriving an explicit solution for the characteristic function of the heat distribution of a thermal quantum harmonic oscillator. We then derive a general framework based on the standard two-point-measurement scheme to compute the efficiency distribution of a quantum Otto cycle. We analyze the generic properties of this distribution for scale-invariant driving Hamiltonians which describe a large class of single-particle, many-body, and nonlinear systems. We find that the efficiency is deterministic and that its mean is equal to the macroscopic efficiency for adiabatic driving. We continue our research by studying the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follow the ’universal’ theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We can relate this unusual property to the perfect anticorrelation between work output and heat input that suppresses thermal as well as quantum fluctuations. We then probe our findings in an experimental NMR setup using spin-1/2 systems and find them to agree rather well with our theoretical predictions. Afterward, we move on to the finite-time quantum Carnot cycle and investigate its power fluctuations. In particular, we consider how level degeneracy and level number, two commonly found properties in quantum systems, influence the relative work fluctuations. We find that their optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results highlight that these parameters can be employed to realize high-performance, high-stability cyclic quantum heat engines.
Homothetic quantum Otto engines---where all populated energy gaps are rescaled by a common factor---provide a reference model in which the quasistatic stochastic efficiency is trajectory-independent while work remains fluctuating. For arbitrary finite homothetic spectra we derive the two-point-measurement work distribution and reduce the first two work moments to endpoint energy moments. Specializing to a uniformly spaced ladder gives closed finite-NNN expressions for the full work distribution, mean work, variance, and signal-to-width reliability. This ladder connects the qubit and oscillator limits, reveals a finite-NNN reliability crossover, and demonstrates that the high-temperature and infinite-dimensional limits do not commute. The noncommutation reflects a bounded-versus-unbounded spectral distinction: at fixed finite NNN the Gibbs state has a normalizable infinite-temperature limit, whereas the oscillator retains an ever-expanding thermal tail. The exact formulas are used to compare standard mean-output prescriptions with work reliability, showing that maximum mean output and maximum dimensionless reliability select different operating points. The benchmark is extended to incomplete diagonal reset and to finite-time unitary strokes described by transition matrices, with a finite-ladder protocol and a harmonic sudden-switch oscillator benchmark as controlled examples. Weak deviations from exact homothety are treated perturbatively, showing how level-dependent gap distortions reintroduce quasistatic efficiency fluctuations and modify work reliability. Together, these results separate finite-size, incomplete thermalization, finite-time, and weak spectral-distortion contributions to work unreliability in quantum Otto engines.
We consider a generic four-stroke quantum Otto engine consisting of two unitary and two thermalization strokes with an arbitrary many-body working medium. Using the Schwinger-Keldysh nonequilibrium Green's function formalism, we provide an analytical expression for the cumulant generating function corresponding to the joint probability distribution of nonequilibrium work and heat. The obtained result is valid up to the second order of the external driving amplitude. We then focus on the linear response limit and obtained Onsager's transport coefficients for the generic Otto cycle and show that the traditional fluctuation-dissipation relation for the total work is violated in the quantum domain, whereas for heat it is preserved. This leads to remarkable consequences in obtaining universal constraints on heat and work fluctuations for engine and refrigerator regimes of the Otto cycle and further allows us to make connections to the thermodynamic uncertainty relations. These findings are illustrated using a paradigmatic model that can be feasibly implemented in experiments.
In finite-time quantum heat engines, some work is consumed to drive a working fluid accompanying coherence, which is called "friction." To understand the role of friction in quantum thermodynamics, we present a couple of finite-time quantum Otto cycles with two different baths: Agarwal versus Lindbladian. We solve them exactly and compare the performance of the Agarwal engine with that of the Lindbladian engine. In particular, we find remarkable and counterintuitive results that the performance of the Agarwal engine due to friction can be much higher than that in the quasistatic limit with the Otto efficiency, and the power of the Lindbladian engine can be nonzero in the short-time limit. Based on additional numerical calculations of these outcomes, we discuss possible origins of such differences between two engines and reveal them. Our results imply that, even with an equilibrium bath, a nonequilibrium working fluid brings on the higher performance than what an equilibrium working fluid does.