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arXiv:1911.03622 · Physical review. E

Finite-time quantum Otto engine: Surpassing the quasistatic efficiency due to friction

Sangyun Lee, Meesoon Ha, Jong-Min Park, Hawoong Jeong

Published Feb 24, 2020• 32 citations
arXivHTMLPDF

Abstract

In finite-time quantum heat engines, some work is consumed to drive a working fluid accompanying coherence, which is called "friction." To understand the role of friction in quantum thermodynamics, we present a couple of finite-time quantum Otto cycles with two different baths: Agarwal versus Lindbladian. We solve them exactly and compare the performance of the Agarwal engine with that of the Lindbladian engine. In particular, we find remarkable and counterintuitive results that the performance of the Agarwal engine due to friction can be much higher than that in the quasistatic limit with the Otto efficiency, and the power of the Lindbladian engine can be nonzero in the short-time limit. Based on additional numerical calculations of these outcomes, we discuss possible origins of such differences between two engines and reveal them. Our results imply that, even with an equilibrium bath, a nonequilibrium working fluid brings on the higher performance than what an equilibrium working fluid does.

DOI
10.1103/physreve.101.022127

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In finite-time quantum heat engines, some work is consumed to drive a working fluid accompanying coherence, which is called "friction." To understand the role of friction in quantum thermodynamics, we present a couple of finite-time quantum Otto cycles with two different baths: Agarwal versus Lindbladian. We solve them exactly and compare the performance of the Agarwal engine with that of the Lindbladian engine. In particular, we find remarkable and counterintuitive results that the performance of the Agarwal engine due to friction can be much higher than that in the quasistatic limit with the Otto efficiency, and the power of the Lindbladian engine can be nonzero in the short-time limit. Based on additional numerical calculations of these outcomes, we discuss possible origins of such differences between two engines and reveal them. Our results imply that, even with an equilibrium bath, a nonequilibrium working fluid brings on the higher performance than what an equilibrium working fluid does.
The concept of inner friction, by which a quantum heat engine is unable to follow adiabatically its strokes and thus dissipates useful energy, is illustrated in an exact physical model where the working substance consists of an ensemble of misaligned spins interacting with a magnetic field and performing the Otto cycle. The effect of this static disorder under a finite-time cycle gives a new perspective of the concept of inner friction under realistic settings. We investigate the efficiency and power of this engine and relate its performance to the amount of friction from misalignment and to the temperature difference between heat baths. Finally we propose an alternative experimental implementation of the cycle where the spin is encoded in the degree of polarization of photons.
For quantum Otto engine driven quasistatically, we provide exact full statistics of heat and work for a class of working fluids that follow a scale-invariant energy eigenspectra under driving. Equipped with the full statistics we go on to derive a universal expression for the ratio of nth cumulant of output work and input heat in terms of the mean Otto efficiency. Furthermore, for nonadiabatic driving of quantum Otto engine with working fluid consisting of either a (i) qubit or (ii) a harmonic oscillator, we show that the relative fluctuation of output work is always greater than the corresponding relative fluctuation of input heat absorbed from the hot bath. As a result, the ratio between the work fluctuation and the input heat fluctuation receives a lower bound in terms of the square value of the average efficiency of the engine. The saturation of the lower bound is received in the quasistatic limit of the engine.
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cycle, which are dependent on the time duration along each process. With these, we derive the analytical expressions for the thermodynamic quantities of the two-level heat engine, such as total work, thermodynamic efficiency, entropy production, and work fluctuations, in which effects of coherence, squeezing, inner friction and finite-time heat exchange are included. We then numerically determine the thermodynamic quantities and the fluctuations using the parameters employed in the experimental implementation. Our results clarify the role of coherence and squeezing in the performance and fluctuations in the quantum Otto engines.
The working substance fueling a quantum heat engine may contain prominent quantum properties such as coherence and nonclassical correlations. In particular, coherence has been somewhat related to quantum friction, whose origin has been mostly associated with the noncommutativity of a driven Hamiltonian at different times. Here, we consider a quantum Otto heat engine operated at finite time and undergoing incomplete thermalization with a heat source. We introduce analytical expressions relating the engine efficiency and extractable power to the coherence measured in the energy basis of the working substance during the engine cycle. We show that coherence, which has been related to an increase in entropy production and irreversibility, can in also be employed to improve the quantum engine performance, mitigating quantum friction. Such an improvement may be achieved by carefully tuning cycle parameters. To illustrate this coherent improvement we performed a numerical analysis in an experimentally feasible example.
The working substance fueling a quantum heat engine may contain coherence in its energy basis, depending on the dynamics of the engine cycle. In some models of quantum Otto heat engines, energy coherence has been associated with entropy production and quantum friction. We considered a quantum Otto heat engine operating at finite time. Coherence is generated and the working substance does not reach thermal equilibrium after interacting with the hot heat reservoir, leaving the working substance in a state with residual energy coherence. We observe an interferencelike effect between the residual coherence (after the incomplete thermalization) and the coherence generated in the subsequent finite-time stroke. We introduce analytical expressions highlighting the role of coherence and examine how this dynamical interference effect influences the engine performance. Additionally, in this scenario in which coherence is present along the cycle, we argue that the careful tuning of the cycle parameters may exploit this interference effect and make coherence acts like a dynamical quantum lubricant. To illustrate this, we numerically consider an experimentally feasible example and compare the engine performance to the performance of a similar engine where the residual coherence is completely erased, ruling out the dynamical interference effect.
The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square root of the temperature ratio in the quasistatic limit where their reversibility is dominated by heat conductance to the temperature ratio to the power of 1/4 in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.