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arXiv:2104.11424 · Nature

Evidence for the association of triatomic molecules in ultracold 23Na40K + 40K mixtures

H. X. Yang, Xinyao Wang, Zhen Su, Jin Cao, De-Chao Zhang, Jun Rui, Bo Zhao, Chunli Bai, Jian-Wei Pan

Published Feb 9, 2022• 47 citations
arXivHTMLPDF
DOI
10.1038/s41586-021-04297-2

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In recent years, there has been notable progress in the preparation and control of ultracold gases of diatomic molecules. The next experimental challenge is the production of ultracold polyatomic molecular gases. Here, we report the creation of an ultracold gas of 23 Na 40 K 2 triatomic molecules from a mixture of ground-state sodium-23–potassium-40 ( 23 Na 40 K) molecules and potassium-40 ( 40 K) atoms. The triatomic molecules were created by adiabatic magneto-association through an atom–diatomic molecule Feshbach resonance. We obtained clear evidence for the creation of triatomic molecules by directly detecting them using radio-frequency dissociation. Approximately 4000 triatomic molecules with a high-peak phase-space density of 0.05 could be created. The ultracold triatomic molecules can serve as a launchpad to probe the three-body potential energy surface and may be used to prepare quantum degenerate triatomic molecular gases.
An ultracold three-species Bose–Fermi–Fermi degenerate atomic mixture 87 Rb– 40 K– 6 Li was realized very recently (Tagliber M et al 2008 Phys. Rev. Lett. 100 010401). Here, we study the creation of heteronuclear triatomic molecules in this mixture, and show that a constructive triple-path interference can lead to an almost ideal conversion rate, in comparison with the single- or double-path cases. The important effect of the initial population imbalance on the atom–molecule dark state is also investigated.