In recent years, there has been notable progress in the preparation and control of ultracold gases of diatomic molecules. The next experimental challenge is the production of ultracold polyatomic molecular gases. Here, we report the creation of an ultracold gas of 23 Na 40 K 2 triatomic molecules from a mixture of ground-state sodium-23–potassium-40 ( 23 Na 40 K) molecules and potassium-40 ( 40 K) atoms. The triatomic molecules were created by adiabatic magneto-association through an atom–diatomic molecule Feshbach resonance. We obtained clear evidence for the creation of triatomic molecules by directly detecting them using radio-frequency dissociation. Approximately 4000 triatomic molecules with a high-peak phase-space density of 0.05 could be created. The ultracold triatomic molecules can serve as a launchpad to probe the three-body potential energy surface and may be used to prepare quantum degenerate triatomic molecular gases.In recent years, there has been notable progress in the preparation and control of ultracold gases of diatomic molecules. The next experimental challenge is the production of ultracold polyatomic molecular gases. Here, we report the creation of an ultracold gas of 23 Na 40 K 2 triatomic molecules from a mixture of ground-state sodium-23–potassium-40 ( 23 Na 40 K) molecules and potassium-40 ( 40 K) atoms. The triatomic molecules were created by adiabatic magneto-association through an atom–diatomic molecule Feshbach resonance. We obtained clear evidence for the creation of triatomic molecules by directly detecting them using radio-frequency dissociation. Approximately 4000 triatomic molecules with a high-peak phase-space density of 0.05 could be created. The ultracold triatomic molecules can serve as a launchpad to probe the three-body potential energy surface and may be used to prepare quantum degenerate triatomic molecular gases.

ScienceDec 1, 202239 citations

Triatomic continuum resonances for large negative scattering lengths

Francis G. Bringas, Marcelo Takeshi Yamashita, T. Frederico

We study triatomic systems in the regime of large negative scattering lengths which may be more favorable for the formation of condensed trimers in trapped ultracold monoatomic gases as the competition with the weakly bound dimers is absent. The manipulation of the scattering length can turn an excited weakly bound Efimov trimer into a continuum resonance. Its energy and width are described by universal scaling functions written in terms of the scattering length and the binding energy ${B}_{3}$ of the shallowest triatomic molecule. For ${a}^{\ensuremath{-}1}<\ensuremath{-}0.0297\sqrt{m{B}_{3}∕{\ensuremath{\hbar}}^{2}}$, the excited Efimov state turns into a continuum resonance.We study triatomic systems in the regime of large negative scattering lengths which may be more favorable for the formation of condensed trimers in trapped ultracold monoatomic gases as the competition with the weakly bound dimers is absent. The manipulation of the scattering length can turn an excited weakly bound Efimov trimer into a continuum resonance. Its energy and width are described by universal scaling functions written in terms of the scattering length and the binding energy ${B}_{3}$ of the shallowest triatomic molecule. For ${a}^{\ensuremath{-}1}<\ensuremath{-}0.0297\sqrt{m{B}_{3}∕{\ensuremath{\hbar}}^{2}}$, the excited Efimov state turns into a continuum resonance.

arXiv:cond-mat/0312291Physical Review AApr 15, 200449 citations

Atom-atom interactions in ultracold gases

Claude N. Cohen-Tannoudji

Apr 25, 20071 citation

Exotic Phases of Ultracold Gases

W. Vincent Liu

Aug 30, 20170 citations

Molecule formation in ultracold atomic gases

Hutson, J M, Soldan, P H

This review describes recent experimental and theoretical advances in forming molecules in ultracold gases of trapped alkali metal atoms, both by magnetic tuning through Feshbach resonances and by photoassociation. Molecular Bose-Einstein condensation of long-range states of both boson dimers and fermion dimers was achieved in 2002-3. Condensates of boson dimers were found to be short-lived, but long-lived condensates of fermion dimers have been produced. Signatures of triatomic and tetraatomic molecules have recently been observed. Both homonuclear and heteronuclear molecules have been formed by photoassociation, mostly in very high vibrational levels. Recent attempts to produce ultracold molecules in short-range states (low vibrational levels) are described. Experimental and theoretical work on collisions of ultracold molecules is discussed.This review describes recent experimental and theoretical advances in forming molecules in ultracold gases of trapped alkali metal atoms, both by magnetic tuning through Feshbach resonances and by photoassociation. Molecular Bose-Einstein condensation of long-range states of both boson dimers and fermion dimers was achieved in 2002-3. Condensates of boson dimers were found to be short-lived, but long-lived condensates of fermion dimers have been produced. Signatures of triatomic and tetraatomic molecules have recently been observed. Both homonuclear and heteronuclear molecules have been formed by photoassociation, mostly in very high vibrational levels. Recent attempts to produce ultracold molecules in short-range states (low vibrational levels) are described. Experimental and theoretical work on collisions of ultracold molecules is discussed.

Jul 26, 200682 citations

{B}_{3}

of the shallowest triatomic molecule. For ${a}^{\ensuremath{-}1}<\ensuremath{-}0.0297\sqrt{m{B}_{3}∕{\ensuremath{\hbar}}^{2}}$, the excited Efimov state turns into a continuum resonance.