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arXiv:2104.00115

Adaptive Quantum Heat Engines

M. Khanahmadi, A. T. Rezakhani

Published Mar 31, 2021• 0 citations
arXivHTMLPDF

Abstract

For heat engines working between two heat baths, functionality is often conditioned on a set of fixed constraints such as given internal structure of the engine and given temperatures for the baths. It is, however, important to devise heat engines which can function adaptively, in particular when the engine is a quantum system and the baths are subject to fluctuations. Here we study a model for an adaptive quantum heat engine whose heat baths can have variable temperatures. We obtain conditions under which such an engine can still operate. Moreover, we propose an enhancement of the heat engine by coupling it with an appropriate controller which changes the internal structure of the engine. Interestingly, we prove that this enhanced engine can always operate and we also obtain conditions for maximum power extraction from this engine for all temperatures of the heat baths.

DOI
10.48550/arxiv.2104.00115

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For heat engines working between two heat baths, functionality is often conditioned on a set of fixed constraints such as given internal structure of the engine and given temperatures for the baths. It is, however, important to devise heat engines which can function adaptively, in particular when the engine is a quantum system and the baths are subject to fluctuations. Here we study a model for an adaptive quantum heat engine whose heat baths can have variable temperatures. We obtain conditions under which such an engine can still operate. Moreover, we propose an enhancement of the heat engine by coupling it with an appropriate controller which changes the internal structure of the engine. Interestingly, we prove that this enhanced engine can always operate and we also obtain conditions for maximum power extraction from this engine for all temperatures of the heat baths.
In a quantum Stirling heat engine, the heat exchanged with two thermal baths is partly utilized for performing work by redistributing the energy levels of the working substance. We analyze the thermodynamics of a quantum Stirling engine operating in finite time. We develop a model in which a time-dependent potential barrier changes the energy-level structure of the working substance. The process takes place under a constant interaction with the thermal bath. We further show that in the limit of slow operation of the cycle and low temperature, the efficiency of such an engine approaches Carnot efficiency. We also show that the maximum output power, for the strokes that affect the energy levels, is obtained at an intermediate operating speed, demonstrating the importance of a finite-time analysis.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.
Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study both from a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is, its performance, but, additionally, its constancy, that is, the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency, and constancy scale with the number of spins composing the engine and introduce a well-defined macroscopic limit where analytical expressions are obtained. Our results predict power enhancements, in both finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, accompanied by coherence-enhanced constancy for finite sizes. We discuss these quantities in connection to thermodynamic uncertainty relations.
Heat engines constitute the major building blocks of modern technologies. However, conventional heat engines with higher power yield lesser efficiency and vice versa and respect various power-efficiency trade-off relations. This is also assumed to be true for the engines operating in the quantum regime. Here we show that these relations are not fundamental. We introduce quantum heat engines that deliver maximum power with Carnot efficiency in the one-shot finite-size regime. These engines are composed of working systems with a finite number of quantum particles and are restricted to one-shot measurements. The engines operate in a one-step cycle by letting the working system simultaneously interact with hot and cold baths via semilocal thermal operations. By allowing quantum entanglement between its constituents and, thereby, a coherent transfer of heat from hot to cold baths, the engine implements the fastest possible reversible state transformation in each cycle, resulting in maximum power and Carnot efficiency. Finally, we propose a physically realizable engine using quantum optical systems.
The question of whether quantum coherence is a resource beneficial or detrimental to the performance of quantum heat engines has been thoroughly studied but remains undecided. To isolate the contribution of coherence, we analyze the performance of a purely coherence-driven quantum heat engine, a device that does not include any heat flow during the thermodynamic cycle. The engine is powered by the coherence of a multiqubit system, where each qubit is charged via interaction with a coherence bath using the Jaynes-Cummings model. We demonstrate that optimal coherence charging and hence extractable work is achieved when the coherence bath has an intermediate degree of coherence. In our model, the extractable work is maximized when four copies of the charged qubits are used. Meanwhile, the efficiency of the engine, given by the extractable work per input coherence flow, is optimized by avoiding the coherence being stored in the system-bath correlations that is inaccessible to work. We numerically find that the highest efficiency is obtained for slightly lower temperatures and weaker system-bath coupling than those for optimal coherence charging.
We consider a class of quantum heat engines consisting of two subsystems interacting with a work-source and coupled to two separate baths at different temperatures Th>Tc. The purpose of the engine is to extract work due to the temperature difference. Its dynamics is not restricted to the near equilibrium regime. The engine structure is determined by maximizing the extracted work under various constraints. When this maximization is carried out at finite power, the engine dynamics is described by well-defined temperatures and satisfies the local version of the second law. In addition, its efficiency is bounded from below by the Curzon-Ahlborn value 1-radical Tc/Th and from above by the Carnot value 1-(Tc/Th). The latter is reached-at finite power--for a macroscopic engine, while the former is achieved in the equilibrium limit Th-->Tc . The efficiency that maximizes the power is strictly larger than the Curzon-Ahloborn value. When the work is maximized at a zero power, even a small (few-level) engine extracts work right at the Carnot efficiency.