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arXiv:2106.13817 · Physical review. E

Collective effects on the performance and stability of quantum heat engines

Leonardo da Silva Souza, Gonzalo Manzano, Rosario Fazio, Fernando Iemini

Published Jul 28, 2022• 36 citations
arXivHTMLPDF

Abstract

Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study both from a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is, its performance, but, additionally, its constancy, that is, the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency, and constancy scale with the number of spins composing the engine and introduce a well-defined macroscopic limit where analytical expressions are obtained. Our results predict power enhancements, in both finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, accompanied by coherence-enhanced constancy for finite sizes. We discuss these quantities in connection to thermodynamic uncertainty relations.

DOI
10.1103/physreve.106.014143

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Recent predictions for quantum-mechanical enhancements in the operation of small heat engines have raised renewed interest in their study both from a fundamental perspective and in view of applications. One essential question is whether collective effects may help to carry enhancements over larger scales, when increasing the number of systems composing the working substance of the engine. Such enhancements may consider not only power and efficiency, that is, its performance, but, additionally, its constancy, that is, the stability of the engine with respect to unavoidable environmental fluctuations. We explore this issue by introducing a many-body quantum heat engine model composed by spin pairs working in continuous operation. We study how power, efficiency, and constancy scale with the number of spins composing the engine and introduce a well-defined macroscopic limit where analytical expressions are obtained. Our results predict power enhancements, in both finite-size and macroscopic cases, for a broad range of system parameters and temperatures, without compromising the engine efficiency, accompanied by coherence-enhanced constancy for finite sizes. We discuss these quantities in connection to thermodynamic uncertainty relations.
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Abstract The performances of quantum thermometry in thermal equilibrium together with the output power of certain class of quantum engines share a common characteristic: both are determined by the heat capacity of the probe or working medium. After noticing that the heat capacity of spin ensembles can be significantly modified by collective coupling with a thermal bath, we build on the above observation to investigate the respective impact of such collective effect on quantum thermometry and quantum engines. We find that the precision of the temperature estimation is largely increased at high temperatures, reaching even the Heisenberg scaling—inversely proportional to the number of spins. For Otto engines operating close to the Carnot efficiency, collective coupling always enhances the output power. Some tangible experimental platforms are suggested.
Conventional continuous quantum heat engines with incoherent heat transfer perform poorly as they exploit two-body interactions between the system and hot or cold baths, thus having limited capability to outperform their classical counterparts. We introduce distinct continuous quantum heat engines that utilize coherent heat transfer with baths, yielding genuine quantum enhancement in performance. These coherent engines consist of one qutrit system and two photonic baths and enable coherent heat transfer via two-photon transitions involving three-body interactions between the system and hot and cold baths. We demonstrate that coherent engines deliver significantly higher power output with much greater reliability, i.e., lower signal-to-noise ratio of the power, by hundreds of folds over their incoherent counterparts. Importantly, coherent engines can operate close to or at the maximal achievable reliability allowed by the quantum thermodynamic uncertainty relation. Moreover, coherent engines manifest more nonclassical features than incoherent engines because they violate the classical thermodynamic uncertainty relation by a greater amount and for a wider range of parameters. These genuine enhancements in the performance of coherent engines are directly attributed to their capacity to harness higher energetic coherence for the resonant driving case. The experimental feasibility of coherent engines and the improved understanding of how quantum properties can enhance performance may find applications in quantum enabled technologies.
In this work we study the effect of quantum and thermal fluctuations on the statistics of quantum heat engine performance parameters, like efficiency and power. We begin by deriving an explicit solution for the characteristic function of the heat distribution of a thermal quantum harmonic oscillator. We then derive a general framework based on the standard two-point-measurement scheme to compute the efficiency distribution of a quantum Otto cycle. We analyze the generic properties of this distribution for scale-invariant driving Hamiltonians which describe a large class of single-particle, many-body, and nonlinear systems. We find that the efficiency is deterministic and that its mean is equal to the macroscopic efficiency for adiabatic driving. We continue our research by studying the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follow the ’universal’ theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We can relate this unusual property to the perfect anticorrelation between work output and heat input that suppresses thermal as well as quantum fluctuations. We then probe our findings in an experimental NMR setup using spin-1/2 systems and find them to agree rather well with our theoretical predictions. Afterward, we move on to the finite-time quantum Carnot cycle and investigate its power fluctuations. In particular, we consider how level degeneracy and level number, two commonly found properties in quantum systems, influence the relative work fluctuations. We find that their optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results highlight that these parameters can be employed to realize high-performance, high-stability cyclic quantum heat engines.
We study a quantum information engine (QIE) modeled by a multiqubit working medium (WM) collectively coupled to a single thermal bath. We show that one can harness the collective effects to significantly enhance the performance of the QIE, as compared to equivalent engines lacking collective effects. We use one bit of information about the WM magnetization to extract work from the thermal bath. We analyze the work output, noise-to-signal ratio, and thermodynamic uncertainty relation (TUR), and contrast these performance metrics of a collective QIE with that of an engine whose WM qubits are coupled independently to a thermal bath. We show that in the limit of high temperatures of the thermal bath, a collective QIE always outperforms its independent counterpart. In contrast to quantum heat engines, where collective enhancement in specific heat plays a direct role in improving the performance of the engines, here the collective advantage stems from higher occupation probabilities for the higher-energy levels of the positive magnetization states, as compared to the independent case. Furthermore, we show that in the limit of high temperatures, the TUR for both the collective as well as the independent QIEs violate the standard heat engine TUR bound of 2.
Abstract Quantum cycles in established heat engines can be modeled with various quantum systems as working substances. As for example, heat engine can be modeled with an infinite potential well as the working substance to determine the efficiency and work done. However, in this method, the relationship between the quantum observables and the physically measurable parameters, i.e., the efficiency and work done is not well understood from the quantum mechanics approach. A detailed analysis is needed to link the thermodynamical variables (on which the efficiency and work done depends) with the uncertainty principle for better understanding. Here, we present the connection of sum uncertainty relation of position and momentum operators with thermodynamic variables in the quantum heat engine model. We are able to determine the upper and lower bounds on the efficiency of the heat engine through uncertainty relation.