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arXiv:2103.12042 · Physical Review A

Unified Gorini-Kossakowski-Lindblad-Sudarshan quantum master equation beyond the secular approximation

Anton Sergeevich Trushechkin

Published Jun 29, 2021• 104 citations
arXivHTMLPDF

Abstract

Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account nonsecular effects, but nevertheless has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan form (in particular, it preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The nonsecular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.

DOI
10.1103/physreva.103.062226

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Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account nonsecular effects, but nevertheless has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan form (in particular, it preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The nonsecular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.
Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account non-secular effects, but, nevertheless, has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) form (in particular, preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The non-secular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.
Master equations under appropriate assumptions are efficient tools for the study of open quantum systems. For many-body systems, subsystems of which locally couple to thermal baths and weakly interact with each other, the local approach provides a more convenient description than the global approach. However, these local master equations are believed to generate inconsistencies with the laws of thermodynamics when intersubsystem interactions exist. Here we develop an alternative local master equation by virtue of similar approximations used in deriving the traditional Gorini-Kossakowski-Lindblad-Sudarshan master equation. In particular, we stick to using eigenstates of each subsystem to construct quantum jump operators, and the secular approximation is also employed to modify the intersubsystem interactions. Our results show that violations of thermodynamic laws will be avoided after correcting intersubsystem interactions. Finally, we study a two-qubit heat transfer model and this further shows the validity of our modified master equation.
Recently, a "unified" quantum master equation was derived and shown to be of the Gorini-Kossakowski-Lindblad-Sudarshan form. This equation describes the dynamics of open quantum systems in a manner that forgoes the full secular approximation and retains the impact of coherences between eigenstates close in energy. We implement full counting statistics with the unified quantum master equation to investigate the statistics of energy currents through open quantum systems with nearly degenerate levels. We show that, in general, this equation gives rise to dynamics that satisfy fluctuation symmetry, a sufficient condition for the Second Law of Thermodynamics at the level of average fluxes. For systems with nearly degenerate energy levels, such that coherences build up, the unified equation is simultaneously thermodynamically consistent and more accurate than the fully secular master equation. We exemplify our results for a "V" system facilitating energy transport between two thermal baths at different temperatures. We compare the statistics of steady-state heat currents through this system as predicted by the unified equation to those given by the Redfield equation, which is less approximate but, in general, not thermodynamically consistent. We also compare results to the secular equation, where coherences are entirely abandoned. We find that maintaining coherences between nearly degenerate levels is essential to properly capture the current and its cumulants. On the other hand, the relative fluctuations of the heat current, which embody the thermodynamic uncertainty relation, display inconsequential dependence on quantum coherences.
An open quantum system can be described by a master equation, of which one of the most popular is the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) equation. We revisit description of driven-dissipative quantum systems focusing on the appropriate choice of the system's basis and the respective transformations. We consider the GKSL equation in different bases and calculate the dynamics for a qubit and for a qudit. An appropriate choice of the basis is a fundamental problem for theoretical consideration of open quantum systems and provides an opportunity to obtain the desired evolution in practice.
Time-local quantum master equations that describe open quantum systems beyond the limit of ultraweak system-bath coupling are often not of Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) form. Prominent examples are the Redfield equation approximating general open quantum systems and the Hu-Paz-Zhang equation precisely describing a damped harmonic oscillator. In this study, we demonstrate that not only the former but also the latter can be brought to pseudo-Lindblad form. This form features a dissipator resembling that of a GKSL equation, with the distinction that some of the terms have negative weights. Moreover, we systematically investigate transformations that leave the dissipator of pseudo-Lindblad equations unchanged, while changing the relative weight between its positive and negative terms. These can be used to minimize the weights of the negative terms, which is optimal both for the convergence of a recently developed quantum-trajectory unraveling of pseudo-Lindblad equations and the truncation of the negative terms to obtain a GKSL equation.