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Mathematical Notes

Decoherence and Coherence Preservation in the Solutions of the GKSL Equation in the Theory of Open Quantum Systems

Anton Sergeevich Trushechkin

Published Nov 1, 2019• 4 citations
Publisher

Abstract

The properties of solutions of the Gorini–Kossakowski-Sudarshan–Lindblad (GKSL) equation for the density operator (matrix) of a system that has nondegenerate energy spectrum and weakly interacts with a reservoir are considered. Conditions for the existence of solutions for which the density matrix has off-diagonal entries (“coherences”) not tending to zero at large times are derived.

DOI
10.1134/s000143461911035x

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The properties of solutions of the Gorini–Kossakowski-Sudarshan–Lindblad (GKSL) equation for the density operator (matrix) of a system that has nondegenerate energy spectrum and weakly interacts with a reservoir are considered. Conditions for the existence of solutions for which the density matrix has off-diagonal entries (“coherences”) not tending to zero at large times are derived.
Open quantum systems are, in general, described by a density matrix that is evolving under transformations belonging to a dynamical semigroup. They can obey the Franke–Gorini–Kossakowski–Lindblad–Sudarshan (FGKLS) equation. We exhaustively study the case of a Hilbert space of dimension 2. First, we find final fixed states (called pointers) of an evolution of an open system, and we then obtain a general solution to the FGKLS equation and confirm that it converges to a pointer. After this, we check that the solution has physical meaning, i.e., it is Hermitian, positive and has trace equal to 1, and find a moment of time starting from which the FGKLS equation can be used—the range of applicability of the semigroup symmetry. Next, we study the behavior of a solution for a weak interaction with an environment and make a distinction between interacting and non-interacting cases. Finally, we prove that there cannot exist oscillating solutions to the FGKLS equation, which would resemble the behavior of a closed quantum system.
Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account non-secular effects, but, nevertheless, has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) form (in particular, preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The non-secular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.
These notes are a short introduction to the mathematical theory of open quantum systems. They are meant to serve as an entry point into a broad research area which has applications across the quantum sciences dealing with systems subjected to external noise. The guiding idea is to let the key structures of the theory emerge from a concrete model. By working through the dissipative Jaynes-Cummings model the reader will dis- cover explicitly how irreversible dynamics arises from a unitary system-reservoir evolution. The notions of the continuous mode limit, correlation functions, spectral density appear in a natural manner and lead to the evolution equation of the open system in form of a master equation. This sets the stage for the more general analysis of completely positive, trace preserving (CPTP) maps and the study of quantum dynamical semigroups. We motivate and prove the Kraus representation theorem, the dilation theorem and the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) theorem. Working through the exercises (for which full solutions are supplied) will reinforce the ideas introduced in the main text.
Derivation of a quantum master equation for a system weakly coupled to a bath which takes into account nonsecular effects, but nevertheless has the mathematically correct Gorini-Kossakowski-Lindblad-Sudarshan form (in particular, it preserves positivity of the density operator) and also satisfies the standard thermodynamic properties is a known long-standing problem in theory of open quantum systems. The nonsecular terms are important when some energy levels of the system or their differences (Bohr frequencies) are nearly degenerate. We provide a fully rigorous derivation of such equation based on a formalization of the weak-coupling limit for the general case.
An open quantum system can be described by a master equation, of which one of the most popular is the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) equation. We revisit description of driven-dissipative quantum systems focusing on the appropriate choice of the system's basis and the respective transformations. We consider the GKSL equation in different bases and calculate the dynamics for a qubit and for a qudit. An appropriate choice of the basis is a fundamental problem for theoretical consideration of open quantum systems and provides an opportunity to obtain the desired evolution in practice.
A longstanding tool to characterize the evolution of open Markovian quantum systems is the GKSL (Gorini-Kossakowski-Sudarshan-Lindblad) master equation. However, in some cases, open quantum systems can be effectively described with non-Hermitian Hamiltonians, which have attracted great interest in the last twenty years due to a number of unconventional properties, such as the appearance of exceptional points. Here, we present a short review of these two different approaches aiming in particular to highlight their relation and illustrate different ways of connecting non-Hermitian Hamiltonian to a GKSL master equation for the full density matrix.