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arXiv:2009.02801 · Entropy

Quantum Finite-Time Thermodynamics: Insight from a Single Qubit Engine

Roie Dann, Ronnie Kosloff, Peter Salamon

Published Nov 4, 2020• 53 citations
arXivHTMLPDF

Abstract

Incorporating time into thermodynamics allows for addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model in order to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction, and thermalization in the presence of external driving. We construct various finite-time engine cycles that are based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.

DOI
10.3390/e22111255

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Incorporating time into thermodynamics allows for addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model in order to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction, and thermalization in the presence of external driving. We construct various finite-time engine cycles that are based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.
From an entropy-based formulation of the first law of thermodynamics in the quantum regime, we investigate the performance of Otto-like and Carnot-like engines for a single-qubit working medium. Within this framework, the first law includes an additional contribution-coherence work-that quantifies the energetic cost of deviating the quantum trajectory from its natural unitary evolution. We focus on the efficiency of the heat-to-coherence work conversion and show that the Carnot cycle achieves the classical Carnot efficiency, while the performance of the Otto cycle is upper-bounded by the Carnot efficiency corresponding to the extreme temperatures of the cycle. We identify entropy generation during the isochoric stages as the key source of irreversibility limiting the Otto cycle's efficiency.
We investigate a finite-time quantum Otto engine within the framework of gauge-invariant quantum thermodynamics, using the Lipkin-Meshkov-Glick model as the working medium. In this formulation, thermodynamic quantities are defined on equivalence classes of thermodynamically indistinguishable states, leading naturally to gauge-invariant notions of work, heat, entropy, and efficiency. We derive explicit expressions for these quantities and show that the usual work performed during the unitary strokes decomposes into an invariant contribution, associated with changes in the instantaneous energy spectrum and populations, and a coherent contribution arising from finite-time quantum coherences. This decomposition induces the corresponding splittings of engine efficiency and entropy production, providing a geometric interpretation of finite-time irreversibility and clarifying the role of coherence in work extraction. By analyzing the cycle's dependence on driving speed and system size, we identify the engine's operating region and investigate the influence of criticality. We show that crossing the critical region substantially reduces the parameter space in which the cycle operates as a heat engine. At the same time, whenever the engine condition remains satisfied, the discrepancy between the conventional and gauge-invariant descriptions becomes strongly suppressed, indicating that the gauge-invariant sector predominantly carries the extracted work. These results establish a direct connection between gauge-invariant thermodynamics, finite-time irreversibility, and work extraction in many-body quantum thermal machines.
The working substance fueling a quantum heat engine may contain prominent quantum properties such as coherence and nonclassical correlations. In particular, coherence has been somewhat related to quantum friction, whose origin has been mostly associated with the noncommutativity of a driven Hamiltonian at different times. Here, we consider a quantum Otto heat engine operated at finite time and undergoing incomplete thermalization with a heat source. We introduce analytical expressions relating the engine efficiency and extractable power to the coherence measured in the energy basis of the working substance during the engine cycle. We show that coherence, which has been related to an increase in entropy production and irreversibility, can in also be employed to improve the quantum engine performance, mitigating quantum friction. Such an improvement may be achieved by carefully tuning cycle parameters. To illustrate this coherent improvement we performed a numerical analysis in an experimentally feasible example.
After a brief historical perspective, we introduce the key notions of work and heat for quantum systems, to then apply them to quantum engines operating on quantum Otto and Carnot cycles. The irreversible and dissipative character of the quantum Otto cycle is briefly analyzed, contrasting with the energetic optimality of the quantum Carnot cycle. The central question of quantum effects is also addressed and illustrated with several examples. Finally, the last part strives to explain the role that quantum thermodynamics plays for quantum applications and quantum technologies, particularly in relation to energy optimization and the trade-off between performances and energy costs.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero.
Developments in the thermodynamics of small quantum systems envisage nonclassical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum heat engine based on a spin-1/2 system and nuclear magnetic resonance techniques. Irreversibility at a microscope scale is fully characterized by the assessment of energy fluctuations associated with the work and heat flows. We also investigate the efficiency lag related to the entropy production at finite time. The implemented heat engine operates in a regime where both thermal and quantum fluctuations (associated with transitions among the instantaneous energy eigenstates) are relevant to its description. Performing a quantum Otto cycle at maximum power, the proof-of-concept quantum heat engine is able to reach an efficiency for work extraction (η≈42%) very close to its thermodynamic limit (η=44%).