Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2008.04742 · Physical Review Research

Quantum thermodynamically consistent local master equations

Adam Hewgill, Gabriele De Chiara, Alberto Imparato

Published Feb 19, 2021• 61 citations
arXivHTMLPDF

Abstract

Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems.These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of thermodynamics.In contrast, here we rigorously prove that local master equations are consistent with thermodynamics and its laws without resorting to a microscopic model, as done in previous works.In particular, we consider a quantum system in contact with multiple baths and identify the relevant contributions to the total energy, heat currents, and entropy production rate.We show that the second law of thermodynamics holds when one considers the proper expression we derive for the heat currents.We confirm the results for the quantum heat currents by using a heuristic argument that connects the quantum probability currents with the energy currents, using an analogous approach as in classical stochastic thermodynamics.We finally use our results to investigate the thermodynamic properties of a set of quantum rotors operating as thermal devices and show that a suitable design of three rotors can work as an absorption refrigerator or a thermal rectifier.For the machines considered here, we also perform an optimization of the system parameters using an algorithm of reinforcement learning.

DOI
10.1103/physrevresearch.3.013165

Related papers

Reconciliation of quantum local master equations with thermodynamics

Gabriele De Chiara, Gabriel Teixeira Landi, Adam Hewgill +4 more

The study of open quantum systems often relies on approximate master equations derived under the assumptions of weak coupling to the environment. However when the system is made of several interacting subsystems such a derivation is in many cases very hard. An alternative method, employed especially in the modeling of transport in mesoscopic systems, consists in using local master equations (LMEs) containing Lindblad operators acting locally only on the corresponding subsystem. It has been shown that this approach however generates inconsistencies with the laws of thermodynamics. In this paper we demonstrate that using a microscopic model of LMEs based on repeated collisions all thermodynamic inconsistencies can be resolved by correctly taking into account the breaking of global detailed balance related to the work cost of maintaining the collisions. We provide examples based on a chain of quantum harmonic oscillators whose ends are connected to thermal reservoirs at different temperatures. We prove that this system behaves precisely as a quantum heat engine or refrigerator, with properties that are fully consistent with basic thermodynamics.

arXiv:1808.10450•New Journal of Physics•Oct 31, 2018•250 citations

Thermodynamically consistent master equation based on subsystem eigenstates

Siying Wang, Qinghong Yang, Fulin Zhang

Master equations under appropriate assumptions are efficient tools for the study of open quantum systems. For many-body systems, subsystems of which locally couple to thermal baths and weakly interact with each other, the local approach provides a more convenient description than the global approach. However, these local master equations are believed to generate inconsistencies with the laws of thermodynamics when intersubsystem interactions exist. Here we develop an alternative local master equation by virtue of similar approximations used in deriving the traditional Gorini-Kossakowski-Lindblad-Sudarshan master equation. In particular, we stick to using eigenstates of each subsystem to construct quantum jump operators, and the secular approximation is also employed to modify the intersubsystem interactions. Our results show that violations of thermodynamic laws will be avoided after correcting intersubsystem interactions. Finally, we study a two-qubit heat transfer model and this further shows the validity of our modified master equation.

arXiv:2205.10212•Physical review. E•Jan 9, 2023•5 citations

Quantum correlations and thermal machines

Adam Hewgill

Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.

•Oct 1, 2026•0 citations

Heat currents in qubit systems

Hans C. Fogedby

Abstract There is a current interest in quantum thermodynamics in the context of open quantum systems. An important issue is the consistency of quantum thermodynamics, in particular the second law of thermodynamics, i.e. the flow of heat from a hot reservoir to a cold reservoir. Here recent emphasis has been on composite system and in particular the issue regarding the application of local or global master equations. In order to contribute to this discussion we discuss two cases, namely as an example a single qubit and as a simple composite system two coupled qubits driven by two heat reservoirs at different temperatures, respectively. Applying a global Lindblad master equation approach we present explicit expressions for the heat currents in agreement with the second law of thermodynamics. The analysis is carried out in the Born–Markov approximation. We also discuss issues regarding the possible presence of coherences in the steady state.

arXiv:2301.13544•Journal of Statistical Mechanics Theory and Experiment•Jul 23, 2024•0 citations

Exact Open System Approach to Strong Coupling Quantum Thermodynamics

Alessandra Colla, Heinz‐Peter Breuer

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.

•Sep 24, 2021•1 citation

Markovian master equations for quantum thermal machines: local versus global approach

Patrick P. Potts, Martí Perarnau-Llobet, L David M Miranda +4 more

The study of quantum thermal machines, and more generally of open quantum systems, often relies on master equations. Two approaches are mainly followed. On the one hand, there is the widely used, but often criticized, local approach, where machine sub-systems locally couple to thermal baths. On the other hand, in the more established global approach, thermal baths couple to global degrees of freedom of the machine. There has been debate as to which of these two conceptually different approaches should be used in situations out of thermal equilibrium. Here we compare the local and global approaches against an exact solution for a particular class of thermal machines. We consider thermodynamically relevant observables, such as heat currents, as well as the quantum state of the machine. Our results show that the use of a local master equation is generally well justified. In particular, for weak inter-system coupling, the local approach agrees with the exact solution, whereas the global approach fails for non-equilibrium situations. For intermediate coupling, the local and the global approach both agree with the exact solution and for strong coupling, the global approach is preferable. These results are backed by detailed derivations of the regimes of validity for the respective approaches.

arXiv:1707.09211•New Journal of Physics•Oct 26, 2017•272 citations
Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems.These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of thermodynamics.In contrast, here we rigorously prove that local master equations are consistent with thermodynamics and its laws without resorting to a microscopic model, as done in previous works.In particular, we consider a quantum system in contact with multiple baths and identify the relevant contributions to the total energy, heat currents, and entropy production rate.We show that the second law of thermodynamics holds when one considers the proper expression we derive for the heat currents.We confirm the results for the quantum heat currents by using a heuristic argument that connects the quantum probability currents with the energy currents, using an analogous approach as in classical stochastic thermodynamics.We finally use our results to investigate the thermodynamic properties of a set of quantum rotors operating as thermal devices and show that a suitable design of three rotors can work as an absorption refrigerator or a thermal rectifier.For the machines considered here, we also perform an optimization of the system parameters using an algorithm of reinforcement learning.
The study of open quantum systems often relies on approximate master equations derived under the assumptions of weak coupling to the environment. However when the system is made of several interacting subsystems such a derivation is in many cases very hard. An alternative method, employed especially in the modeling of transport in mesoscopic systems, consists in using local master equations (LMEs) containing Lindblad operators acting locally only on the corresponding subsystem. It has been shown that this approach however generates inconsistencies with the laws of thermodynamics. In this paper we demonstrate that using a microscopic model of LMEs based on repeated collisions all thermodynamic inconsistencies can be resolved by correctly taking into account the breaking of global detailed balance related to the work cost of maintaining the collisions. We provide examples based on a chain of quantum harmonic oscillators whose ends are connected to thermal reservoirs at different temperatures. We prove that this system behaves precisely as a quantum heat engine or refrigerator, with properties that are fully consistent with basic thermodynamics.
Master equations under appropriate assumptions are efficient tools for the study of open quantum systems. For many-body systems, subsystems of which locally couple to thermal baths and weakly interact with each other, the local approach provides a more convenient description than the global approach. However, these local master equations are believed to generate inconsistencies with the laws of thermodynamics when intersubsystem interactions exist. Here we develop an alternative local master equation by virtue of similar approximations used in deriving the traditional Gorini-Kossakowski-Lindblad-Sudarshan master equation. In particular, we stick to using eigenstates of each subsystem to construct quantum jump operators, and the secular approximation is also employed to modify the intersubsystem interactions. Our results show that violations of thermodynamic laws will be avoided after correcting intersubsystem interactions. Finally, we study a two-qubit heat transfer model and this further shows the validity of our modified master equation.
Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.
Abstract There is a current interest in quantum thermodynamics in the context of open quantum systems. An important issue is the consistency of quantum thermodynamics, in particular the second law of thermodynamics, i.e. the flow of heat from a hot reservoir to a cold reservoir. Here recent emphasis has been on composite system and in particular the issue regarding the application of local or global master equations. In order to contribute to this discussion we discuss two cases, namely as an example a single qubit and as a simple composite system two coupled qubits driven by two heat reservoirs at different temperatures, respectively. Applying a global Lindblad master equation approach we present explicit expressions for the heat currents in agreement with the second law of thermodynamics. The analysis is carried out in the Born–Markov approximation. We also discuss issues regarding the possible presence of coherences in the steady state.
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.
The study of quantum thermal machines, and more generally of open quantum systems, often relies on master equations. Two approaches are mainly followed. On the one hand, there is the widely used, but often criticized, local approach, where machine sub-systems locally couple to thermal baths. On the other hand, in the more established global approach, thermal baths couple to global degrees of freedom of the machine. There has been debate as to which of these two conceptually different approaches should be used in situations out of thermal equilibrium. Here we compare the local and global approaches against an exact solution for a particular class of thermal machines. We consider thermodynamically relevant observables, such as heat currents, as well as the quantum state of the machine. Our results show that the use of a local master equation is generally well justified. In particular, for weak inter-system coupling, the local approach agrees with the exact solution, whereas the global approach fails for non-equilibrium situations. For intermediate coupling, the local and the global approach both agree with the exact solution and for strong coupling, the global approach is preferable. These results are backed by detailed derivations of the regimes of validity for the respective approaches.