All clocks, classical or quantum, are open non equilibrium irreversible systems subject to the constraints of thermodynamics. Using examples I show that these constraints necessarily limit the performance of clocks and that good clocks require large energy dissipation. For periodic clocks, operating on a limit cycle, this is a consequence of phase diffusion. It is also true for non periodic clocks (for example, radio carbon dating) but due to telegraph noise not to phase diffusion. In this case a key role is played by accurate measurements that decrease entropy, thereby raising the free energy of the clock, and requires access to a low entropy reservoir. In the quantum case, for which thermal noise is replaced by quantum noise (spontaneous emission or tunnelling), measurement plays an essential role for both periodic and non periodic clocks. The paper concludes with a discussion of the Tolman relations and Rovelli's thermal time hypothesis in terms of clock thermodynamics.
All clocks, classical or quantum, are open non equilibrium irreversible systems subject to the constraints of thermodynamics. Using examples I show that these constraints necessarily limit the performance of clocks and that good clocks require large energy dissipation. For periodic clocks, operating on a limit cycle, this is a consequence of phase diffusion. It is also true for non periodic clocks (for example, radio carbon dating) but due to telegraph noise not to phase diffusion. In this case a key role is played by accurate measurements that decrease entropy, thereby raising the free energy of the clock, and requires access to a low entropy reservoir. In the quantum case, for which thermal noise is replaced by quantum noise (spontaneous emission or tunnelling), measurement plays an essential role for both periodic and non periodic clocks. The paper concludes with a discussion of the Tolman relations and Rovelli's thermal time hypothesis in terms of clock thermodynamics.
In classical physics, clocks are open dissipative systems driven from thermal equilibrium and necessarily subject to thermal noise. We describe a quantum clock driven by entropy reduction through measurement. The mechanism consists of a superconducting transmon qubit coupled to an open co-planar resonator. The cavity and qubit are driven by coherent fields and the cavity output is monitored with homodyne detection. We show that the measurement itself induces coherent oscillations, with fluctuating period, in the conditional moments. The clock signal can be extracted from the observed measurement currents and analysed to determine the noise performance. The model demonstrates a fundamental principle of clocks at zero temperature: good clocks require high rates of energy dissipation and consequently entropy generation.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
Driven quantum systems are systems in which a set of parameters obeys a time-dependent protocol, both periodic and non-periodic. The study of these systems bridges theoretical advances with experimental realizations in a variety of platforms—these range from quantum dot arrays to molecular junctions to trapped ions. The theoretical study is challenging due to the inherent non-equilibrium nature of the problem. These systems offer an interesting playground for quantum thermodynamics. They can be studied as quantum machines, such as refrigerators, heat pumps or engines. This poses the challenge of redefining the laws of thermodynamics in the quantum realm. This effort implies taking into account the presence of coherence, entanglement and strong correlations with the environment. In this conceptual framework, we attempt to shed new light on specific setups with applications in quantum metrology. In the first part of the Thesis, we present novel results on the thermodynamics and transport properties of quantum dots. After thoroughly introducing the main methods, namely non-equilibrium Green's functions and scattering matrix techniques, we apply these tools to adiabatic charge pumping. In this context, quantum dots, subjected to external periodic driving, act as nano-mechanical engines, transferring charge from a source to a drain. We investigate the conditions under which the pumped charge becomes quantized and how thermodynamic quantities behave in this regime. Next, we will focus on the charge shuttle mechanism in movable quantum dots as an example of a quantum clock. This physical model describes transport through a molecular state bound to two leads by van der Waals forces, with an electric field pushing the molecule from the source to the drain. The periodic oscillations arising from the system's dissipative limit cycle solution provide the basis for time measurement. We examine quantum noise primarily associated with the tunnelling process. In the second part, we propose a quantum clock that utilizes the free energy resources generated by coupling to a quantum battery, consisting of an integrable spin chain driven out of equilibrium by a quench in a chosen parameter. The operating conditions of the clock in the manifold of parameters are examined, leading to the requirement of the crossing of the critical point in the battery. The lifetime of the battery's resources is found to be extensive in its size, even when choosing a global coupling observable in the battery.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
Quantum measurement of a system can change its mean energy, as well as entropy. A selective measurement (classical or quantum) can be used as a "Maxwell's demon" to power a single-temperature heat engine, by decreasing the entropy. Quantum mechanically, so can a non-selective measurement, despite increasing the entropy of a thermal state. The maximal amount of work extractable following the measurement is given by the change in free energy: Wmax(non−)sel.=ΔEmeas−TBathΔSmeas(non−)sel.. This follows from the "generalized 2nd law for nonequilibrium initial state" [Hasegawa et. al, PLA (2010)], of which an elementary reduction to the standard law is given here. It is shown that Wmaxsel.−Wmaxnon−sel. equals the work required to reset the memory of the measuring device, and that no such resetting is needed in the non-selective case. Consequently, a single-bath engine powered by either kind of measurement works at a net loss of TBathΔSmeasnon−sel per cycle. By replacing the measurement by a reversible "premeasurement" and allowing a work source to couple to the system and memory, the cycle can be made completely reversible.