Driven quantum systems are systems in which a set of parameters obeys a time-dependent protocol, both periodic and non-periodic. The study of these systems bridges theoretical advances with experimental realizations in a variety of platforms—these range from quantum dot arrays to molecular junctions to trapped ions. The theoretical study is challenging due to the inherent non-equilibrium nature of the problem. These systems offer an interesting playground for quantum thermodynamics. They can be studied as quantum machines, such as refrigerators, heat pumps or engines. This poses the challenge of redefining the laws of thermodynamics in the quantum realm. This effort implies taking into account the presence of coherence, entanglement and strong correlations with the environment. In this conceptual framework, we attempt to shed new light on specific setups with applications in quantum metrology. In the first part of the Thesis, we present novel results on the thermodynamics and transport properties of quantum dots. After thoroughly introducing the main methods, namely non-equilibrium Green's functions and scattering matrix techniques, we apply these tools to adiabatic charge pumping. In this context, quantum dots, subjected to external periodic driving, act as nano-mechanical engines, transferring charge from a source to a drain. We investigate the conditions under which the pumped charge becomes quantized and how thermodynamic quantities behave in this regime. Next, we will focus on the charge shuttle mechanism in movable quantum dots as an example of a quantum clock. This physical model describes transport through a molecular state bound to two leads by van der Waals forces, with an electric field pushing the molecule from the source to the drain. The periodic oscillations arising from the system's dissipative limit cycle solution provide the basis for time measurement. We examine quantum noise primarily associated with the tunnelling process. In the second part, we propose a quantum clock that utilizes the free energy resources generated by coupling to a quantum battery, consisting of an integrable spin chain driven out of equilibrium by a quench in a chosen parameter. The operating conditions of the clock in the manifold of parameters are examined, leading to the requirement of the crossing of the critical point in the battery. The lifetime of the battery's resources is found to be extensive in its size, even when choosing a global coupling observable in the battery.
Driven quantum systems are systems in which a set of parameters obeys a time-dependent protocol, both periodic and non-periodic. The study of these systems bridges theoretical advances with experimental realizations in a variety of platforms—these range from quantum dot arrays to molecular junctions to trapped ions. The theoretical study is challenging due to the inherent non-equilibrium nature of the problem. These systems offer an interesting playground for quantum thermodynamics. They can be studied as quantum machines, such as refrigerators, heat pumps or engines. This poses the challenge of redefining the laws of thermodynamics in the quantum realm. This effort implies taking into account the presence of coherence, entanglement and strong correlations with the environment. In this conceptual framework, we attempt to shed new light on specific setups with applications in quantum metrology. In the first part of the Thesis, we present novel results on the thermodynamics and transport properties of quantum dots. After thoroughly introducing the main methods, namely non-equilibrium Green's functions and scattering matrix techniques, we apply these tools to adiabatic charge pumping. In this context, quantum dots, subjected to external periodic driving, act as nano-mechanical engines, transferring charge from a source to a drain. We investigate the conditions under which the pumped charge becomes quantized and how thermodynamic quantities behave in this regime. Next, we will focus on the charge shuttle mechanism in movable quantum dots as an example of a quantum clock. This physical model describes transport through a molecular state bound to two leads by van der Waals forces, with an electric field pushing the molecule from the source to the drain. The periodic oscillations arising from the system's dissipative limit cycle solution provide the basis for time measurement. We examine quantum noise primarily associated with the tunnelling process. In the second part, we propose a quantum clock that utilizes the free energy resources generated by coupling to a quantum battery, consisting of an integrable spin chain driven out of equilibrium by a quench in a chosen parameter. The operating conditions of the clock in the manifold of parameters are examined, leading to the requirement of the crossing of the critical point in the battery. The lifetime of the battery's resources is found to be extensive in its size, even when choosing a global coupling observable in the battery.
Time-periodic quantum systems are present all over science and technology. They have been successfully studied using Floquet theory, and a broad diversity of interesting phenomena such as coherent destruction of tunnelling, dynamical localization and creation of new phases of matter have been discovered. Furthermore, periodic driving has also been introduced as a tool for engineering novel quantum systems that have no static analogue. Besides these remarkable achievements for isolated systems, in reality, systems always interact with their surroundings. Taking the effect of the environment into account, time-periodic quantum systems have been mainly described using the Floquet-Markov approach, which consists in deriving a weak coupling master equation in the Floquet basis. In this thesis, we focus on how to overcome these standard approximations in the description of driven open quantum systems. We start by providing a general review on the topics of isolated driven systems, open quantum systems and the Floquet-Markov approach, before presenting the main results of this work. Under the effect of high-frequency driving, we provide an analytic solution to a large class of open quantum systems. Our method relies on discrete symmetries of the system-bath Hamiltonian and grants access to the time evolution operator of the full system, including bath degrees of freedom. The solution can be interpreted as the stroboscopic evolution of a family of observables under the influence of an effective static Hamiltonian. This provides a flexible simulation procedure of nontrivial Hamiltonians. The results are exemplified with the driven spin-boson model, where a coherent control of dissipation is observed. By a novel combination of Floquet theory, full counting statistics and a Markovian embedding strategy (reaction coordinate mapping), more intricate scenarios with additional driven system-environment interactions are addressed. Hereby, we can access the dynamics and thermodynamics of a periodically driven thermal machine. For the particular case where the working medium is a two-level system, we identify four different operating regimes, including a heat engine and a refrigerator. As the coupling strength is increased, their efficiency and coefficient of performance decrease and the refrigerator regime disappears. Notably, our model reproduces the setup of laser cooling of trapped ions in a specific parameter limit. Following the same combination of methods, we investigate electron pumping through a single quantum dot with periodically modulated energy and tunnelling amplitudes. In the high-frequency regime, the direction of the current can be controlled with the driving phase and a rectification effect that is exclusive to the non-Markovian character of the model is observed. In the low-frequency regime, we apply an additional transformation to view the model as three independent transport channels and observe that the coupling strength also controls the current direction. Studying charge fluctuations we validate that our model behaves as a single-electron source.
This review presents a thermodynamic perspective on quantum coupled transport processes in nanoscale systems. Our analysis is formulated within the framework of entropy production rate, the central quantity governing non-equilibrium processes and expressed through conjugate force-flux pairs. Although thermodynamic laws are universal across classical and quantum domains, the discussion is developed within a microscopic open quantum system framework, focusing on quantum dots (QDs) coupled to electronic reservoirs. We first examine elementary single transport processes and highlight their strong thermodynamic constraints in the near-equilibrium regime. This motivates the study of coupled transport, where multiple force-flux pairs coexist and interact, leading to richer thermodynamic behaviour. Using entropy production as the guiding principle, we analyse coupled energy and particle transport in a minimal two-terminal single-QD setup and show how conventional thermoelectric phenomena, including Seebeck and Peltier effects as well as thermoelectric heat engines and refrigerators, naturally emerge as thermodynamic cross-effects. We then extend the framework to a three-terminal coupled quantum dot (CQD) geometry, which provides a versatile platform for studying coupled transport and reduces, under suitable constraints, to the well-known Sánchez-Büttiker configuration. Beyond standard cross-effects, we discuss the phenomenon of inverse currents in coupled transport (ICC), where a current flows against mutually parallel thermodynamic forces without violating the second law. We show that ICC requires breaking the symmetry between energy and particle transport and identify the conditions for its realization in coupled quantum-dot systems with attractive interdot interactions.
This paper explores topological thermodynamics in driven dissipative quantum materials, a field at the intersection of non-equilibrium statistical mechanics, quantum topology, and condensed matter physics. We review theoretical frameworks and experimental advancements, highlighting how driving forces and dissipative processes influence the formation, stability, and characterization of topological phases. A special focus is placed on Floquet engineering for open quantum systems, where periodic driving and environmental coupling lead to novel non-equilibrium steady states with exotic topological properties. We discuss challenges in defining thermodynamic quantities like temperature and entropy in these far-from-equilibrium settings and examine how topological invariants manifest in dissipative dynamics and transport. The paper uniquely synthesizes advancements in periodically driven, open quantum systems by critically examining how dissipation, often seen as detrimental, can be precisely engineered to reveal or even stabilize topological order. This offers a distinct perspective on designing next-generation quantum technologies. Key theoretical tools, including generalized Floquet theory, Keldysh formalism, and non-Hermitian descriptions, are discussed alongside experimental platforms like photonic quantum gases and cold atomic systems.
The first part of this thesis focuses on verifying the quantum nonequilibrium work relation in the presence of decoherence. The nonequilibrium work relation is a generalization of the second law of thermodynamics that links nonequilibrium work measurements to equilibrium free energies via an equality. Despite being well established for classical systems, a quantum work relation is conceptually difficult to construct for systems that interact with their environment. We argue that for a quantum system which undergoes decoherence but not dissipation, these conceptual difficulties do not arise and the work relation can be proven similarly to the case of an isolated system. This result is accompanied by an experimental demonstration using trapped ions. The second part of this thesis examines the relationship between quantum work and coherence by constructing analogous quantities in classical physics. It has recently been shown that quantum coherence can function as a resource for work extraction. Furthermore, it has been suggested that this property could be a truly quantum aspect of thermodynamics with no classical analog. We examine this assertion within the framework of classical Hamiltonian mechanics and canonical quantization. For classical states we define a so called non-uniformity measure and show that it is a resource for work extraction similar to quantum coherence. Additionally, we show that work extracted from non-uniformity and coherence agree in the classical limit. This calls into question the idea that coherence qualitatively separates classical and quantum thermodynamics. The final part of this thesis explores the connection between decoherence and adiabatic (quasistatic) driving. This topic is inspired by an experiment where it was seen that strong dephasing suppressed energy level transitions. Using a perturbative method we investigate this mechanism in the regime of small to moderate decoherence rate and ask if decoherence can help suppress energy transitions when compared with an adiabatic process without decoherence. We find that strategies that include decoherence are inferior to those where decoherence is absent.
Although the idea of combining thermodynamics with quantum mechanics is more than a century old, quantum thermodynamics has seen significant development over the past few decades. Understanding work, heat, and entropy in the quantum regime has become increasingly important, particularly in light of advances in quantum technologies. This thesis investigates work processes in quantum spin chains. Quantum work processes can involve genuinely quantum features such as entanglement, coherence, and measurement back-action, which are absent in classical thermodynamic descriptions, making their characterization an area of ongoing interest in quantum thermodynamics. Focusing first on a single work step, we show that the frictional work due to finite-time driving for a non-integrable quantum spin chain can be well quantified by the diagonal entropy production. We further demonstrate that integrability breaking enhances work extraction in the adiabatic limit, while suppressing it in the non-adiabatic regime. We then study a quantum Otto cycle using the transverse-field Ising model as the working substance. We determine how different types of operation (engine, refrigerator, accelerator, heater) can emerge for different parameter regimes. We show that with infinitesimal work strokes, a thermal machine behaves either as an engine or an accelerator, and that these regimes can be characterized by equilibrium transverse magnetization. At low temperatures, these regimes are governed by low-energy excitations, while at high temperatures they follow from a free-energy expansion in inverse temperature. Frictional effects can emerge and suppress the engine performance during non-adiabatic driving. We show that these effects can be mitigated using an optimised drive protocol based on a geometric formulation of the path of the system through parameter space. Overall, this thesis provides a comprehensive understanding of how integrability, coherence, finite-time driving, and non-adiabatic transitions govern work extraction and thermal machine operation in quantum spin chains, and paves the way for understanding these processes in other quantum many-body systems.
We present an overview of recent advances in the study of energy dynamics and mechanisms for energy conversion in qubit systems with special focus on realizations in superconducting quantum circuits. We briefly introduce the relevant theoretical framework to analyze heat generation, energy transport and energy conversion in these systems with and without time-dependent driving considering the effect of equilibrium and non-equilibrium environments. We analyze specific problems and mechanisms under current investigation in the context of qubit systems. These include the problem of energy dissipation and possible routes for its control, energy pumping between driving sources and heat pumping between reservoirs, implementation of thermal machines and mechanisms for energy storage. We highlight the underlying fundamental phenomena related to geometrical and topological properties, as well as many-body correlations. We also present an overview of recent experimental activity in this field.