Continuing our inquiry into the conditions when fluctuation-dissipation relations (FDR) may appear in the context of nonequilibrium dynamics of open quantum systems (over and beyond the conventional FDR from linear response theory) we turn to non-Gaussian systems and consider this issue for an anharmonic quantum oscillator interacting with a scalar quantum field bath. We present the general nonperturbative expressions for the rate of energy (power) exchange between the anharmonic oscillator and its thermal bath. For the cases that a stable final equilibrium state exists, and the nonstationary components of the two-point functions of the anharmonic oscillator have negligible contributions to the power balance, we can show nonperturbatively that equilibration implies an FDR for the anharmonic oscillator. We then use a weakly anharmonic oscillator as an example to illustrate the validity of those two assumptions and show that in the weak anhamonicity limit, they are satisfied according to our first-order perturbative results..
We introduce a response theory for open quantum systems within nonequilibrium steady states subject to a Hamiltonian perturbation.Working in the weak system-bath coupling regime, our results are derived within the Lindblad-Gorini-Kossakowski-Sudarshan formalism.We find that the response of the system to a small perturbation is not simply related to a correlation function within the system, unlike traditional linear response theory in closed systems or expectations from the fluctuation-dissipation theorem.In limiting cases, when the perturbation is small relative to the coupling to the surroundings or when it does not lead to a change of the eigenstructure of the system, a perturbative expansion exists where the response function is related to a sum of a system correlation functions and additional forces induced by the surroundings.Away from these limiting regimes, however, the secular approximation results in a singular response that cannot be captured within the traditional approach but can be described by reverting to a microscopic Hamiltonian description.These findings are illustrated by explicit calculations in coupled qubits and anharmonic oscillators in contact with bosonic baths at different temperatures.
Continuing our work on the nature and existence of fluctuation-dissipation relations (FDR) in linear and nonlinear open quantum systems [J.-T. Hsiang, B. L. Hu, and S.-Y. Lin, Phys. Rev. D 100, 025019 (2019); J.-T. Hsiang, B. L. Hu, S.-Y. Lin, and K. Yamamoto, Phys. Lett. B 795, 694 (2019); J.-T. Hsiang and B. L. Hu, Physics (Utrecht) 1, 430 (2019); J.-T. Hsiang and B. L. Hu, Phys. Rev. D 101, 125003 (2020)], here we consider such relations when a linear system is in a nonequilibrium steady state (NESS). With the model of two-oscillators (considered as a short harmonic chain with the two ends) each connected to a thermal bath of different temperatures we find that when the chain is fully relaxed due to interaction with the baths, the relation that connects the noise kernel and the imaginary part of the dissipation kernel of the chain in one bath does not assume the conventional form for the FDR in equilibrium cases. There exists an additional term we call the ``bias current'' that depends on the difference of the bath's initial temperatures and the interoscillator coupling strength. We further show that this term is related to the steady heat flow between the two baths when the system is in an NESS. The ability to know the real-time development of the interheat exchange (between the baths and the end-oscillators) and the intraheat transfer (within the chain) and their dependence on the parameters in the system offers possibilities for quantifiable control, and in the design of quantum heat engines, or thermal devices.
We develop an exact analytical framework for studying the nonequilibrium dynamics of interacting quantum harmonic oscillators coupled to a modelled thermal reservoir and driven by external classical fields. The total Hamiltonian is diagonalized via successive Bogoliubov transformations, enabling a nonperturbative treatment of dissipation and driving. For two coupled oscillators with an external source applied to the first, we derive explicit energy expressions and analyze their dependence on coupling and bath parameters. The phase-space structure is characterized through Husimi
Q-functions for initial separable coherent and number states. We obtain the reduced density matrix elements in the number-state basis and demonstrate that, in the absence of driving and at zero temperature, the reduced density matrix of the main system satisfies the Lindblad master equation. A generating function for the Husimi function is introduced to facilitate computation of higher-order correlations. The analysis is then generalized to
n interacting oscillators, with analytical energy expressions provided and the case
n=3 examined in detail. Our results establish a versatile and exact framework for driven-dissipative quantum systems, with potential applications in quantum thermodynamics, open quantum systems, and many-body physics.
A definition of nonequilibrium free energy
Fs is proposed for dynamical Gaussian quantum open systems strongly coupled to a heat bath and the formal relation with the generating functional, the coarse-grained effective action and the influence action is indicated. For Gaussian open quantum systems exemplified by the quantum Brownian motion model studied here, a time-varying effective temperature can be introduced in a natural way, and, with it, the nonequilibrium free energy
Fs, von Neumann entropy
SvN and internal energy
Us of the reduced system (
S) can be defined accordingly. In contrast to the nonequilibrium free energy found in the literature which references the bath temperature, the nonequilibrium thermodynamic functions we find here obey the familiar relation ${\mathcal{F}}_{\mathrm{s}}(t)={\mathcal{U}}_{\mathrm{s}}(t)\ensuremath{-}{T}_{\mathrm{EFF}}(t){\mathcal{S}}_{vN}(t)$ at any and all moments of time in the system's fully nonequilibrium evolution history. After the system equilibrates they coincide, in the weak coupling limit, with their counterparts in conventional equilibrium thermodynamics. Since the effective temperature captures both the state of the system and its interaction with the bath, upon the system's equilibration, it approaches a value slightly higher than the initial bath temperature. Notably, it remains nonzero for a zero-temperature bath, signaling the existence of system-bath entanglement. Reasonably, at high bath temperatures and under ultraweak couplings, it becomes indistinguishable from the bath temperature. The nonequilibrium thermodynamic functions and relations discovered here for dynamical Gaussian quantum systems should open up useful pathways toward establishing meaningful theories of nonequilibrium quantum thermodynamics.
Building upon the work of Hu, Paz, and Zhang [1,2] on open quantum systems we consider the quantum Brownian motion (QBM) model with one oscillator (position variable
x) as the system, {\it nonlinearly} coupled to an environment of
N harmonic oscillators (with mass
mn, natural frequency
ωn, position
qn and momentum
pn variables) in the form
∑n(vn1(x)qnk+vn2(x)pnl) where
k,l are integers (the present work only considers the
k=l=2 cases). The vertex functions $v_{n1}, v_{n2} $ are of the form
vn1=λCn1f(x),vn2(x)=−λCn2mn−2ωn−2f(x) where
Cn1,2 are the coupling constants with the
nth oscillator,
f(x) is any arbitrary function of
x, and
λ is a dimensionless constant. Employing the closed-time-path formalism the influence action
SIF is calculated using a perturbative expansion in
λ. It is possible to identify the terms in
SIF quadratic or higher in
Δ(s)≡f(x+(s))−f(x−(s)) to constitute the noise kernel, while terms linear in
Δ to that of the dissipation kernel. The non-Gaussian noise kernel gives rise to non-zero three-point correlation function of the corresponding stochastic force. The pathway presented here should be useful for the exploration of \textit{non-Gaussian properties of systems nonlinearly coupled with their environments}; examples in early universe cosmology and in quantum optomechanics (QOM) are mentioned. A modified fluctuation-dissipation relation (FDR) is also established, which ensures the consistency of the model and the accuracy of results even at higher perturbative orders. Another result of significance is the derivation of a nonlinear Langevin equation which is expected to be useful for many open quantum system applications.