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arXiv:1911.01836 · Physical Review A

Symmetry and block structure of the Liouvillian superoperator in partial secular approximation

Marco Cattaneo, Gian Luca Giorgi, Sabrina Maniscalco, Roberta Zambrini

Published Apr 13, 2020• 39 citations
arXivHTMLPDF

Abstract

We address the structure of the Liouvillian superoperator for a broad class of bosonic and fermionic Markovian open systems interacting with stationary environments. We show that the accurate application of the partial secular approximation in the derivation of the Bloch-Redfield master equation naturally induces a symmetry on the superoperator level, which may greatly reduce the complexity of the master equation by decomposing the Liouvillian superoperator into independent blocks. Moreover, we prove that, if the steady state of the system is unique, one single block contains all the information about it, and that this imposes a constraint on the possible steady-state coherences of the unique state, ruling out some of them. To provide some examples, we show how the symmetry appears for two coupled spins interacting with separate baths, as well as for two harmonic oscillators immersed in a common environment. In both cases the standard derivation and solution of the master equation is simplified, as well as the search for the steady state. The block diagonalization does not appear when a local master equation is chosen.

DOI
10.1103/physreva.101.042108

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We address the structure of the Liouvillian superoperator for a broad class of bosonic and fermionic Markovian open systems interacting with stationary environments. We show that the accurate application of the partial secular approximation in the derivation of the Bloch-Redfield master equation naturally induces a symmetry on the superoperator level, which may greatly reduce the complexity of the master equation by decomposing the Liouvillian superoperator into independent blocks. Moreover, we prove that, if the steady state of the system is unique, one single block contains all the information about it, and that this imposes a constraint on the possible steady-state coherences of the unique state, ruling out some of them. To provide some examples, we show how the symmetry appears for two coupled spins interacting with separate baths, as well as for two harmonic oscillators immersed in a common environment. In both cases the standard derivation and solution of the master equation is simplified, as well as the search for the steady state. The block diagonalization does not appear when a local master equation is chosen.
The Markovian dynamics of open quantum systems is typically described through Lindblad equations, which are derived from the Redfield equation via the full secular approximation. The latter neglects the rotating terms in the master equation corresponding to pairs of jump operators with different Bohr frequencies. However, for many physical systems this approximation breaks down, and thus a more accurate treatment of the slowly rotating terms is required. Indeed, more precise physical results can be obtained by performing the partial secular approximation, which takes into account the relevant time scale associated with each pair of jump operators and compares it with the time scale arising from the system-environment coupling. In this work, we introduce a general code for performing the partial secular approximation in the Redfield equation for structured open quantum systems. The code can be applied to a generic Hamiltonian of any multipartite system coupled to bosonic baths. Moreover, it can also reproduce the unified master equation, which captures the same physical behavior as the Redfield equation under the partial secular approximation, but is mathematically guaranteed to generate a completely positive dynamical map. Finally, the code can compute both the local and global version of the master equation for the same physical problem. We illustrate the code by studying the steady-state heat flow in a structured open quantum system composed of two superconducting qubits, each coupled to a bosonic mode, which in turn interacts with a thermal bath. The results in this work can be employed for the numerical study of a wide range of complex open quantum systems.
We provide a rigorous construction of Markovian master equations for a wide class of quantum systems that encompass quadratic models of finite size, linearly coupled to an environment modeled by a set of independent thermal baths. Our theory can be applied for both fermionic and bosonic models in any number of physical dimensions and does not require any particular spatial symmetry of the global system. We show that, for nondegenerate systems under a full secular approximation, the effective Lindblad operators are the normal modes of the system, with coupling constants that explicitly depend on the transformation matrices that diagonalize the Hamiltonian. Both the dynamics and the steady-state (guaranteed to be unique) properties can be obtained with a polynomial amount of resources in the system size. We also address the particle and energy current flowing through the system in a minimal two-bath scheme and find that they hold the structure of Landauer's formula, being thermodynamically consistent.
Abstract Open quantum systems that interact with a Markovian environment can be described by a Lindblad master equation. The generator of time-translation is given by a Liouvillian superoperator acting on the density matrix of the system. As the Fock space for a single bosonic mode is already infinite-dimensional, the diagonalization of the Liouvillian has to be done on the creation- and annihilation-superoperators, a process called ‘third quantization’. We propose a method to solve the Liouvillian for quadratic systems using a single symplectic transformation. We show that the non-Hermitian effective Hamiltonian of the system, next to incorporating the dynamics of the system, is a tool to analyze its symmetries. As an example, we use the effective Hamiltonian to formulate a -‘symmetry’ of an open system. We describe how the inclusion of source terms allows us to obtain the cumulant generating function for observables such as the photon current.
In the thermodynamic limit, the steady states of open quantum many-body systems can undergo nonequilibrium phase transitions due to a competition between coherent and driven-dissipative dynamics. Here, we consider Markovian systems and elucidate structures of the Liouville superoperator that generates the time evolution. In many cases of interest, an operator-basis transformation can bring the Liouvillian into a block-triangular form, making it possible to assess its spectrum. The spectral gap sets the asymptotic decay rate. The superoperator structure can be used to bound gaps from below, showing that, in a large class of systems, dissipative phase transitions are actually impossible and that the convergence to steady states follows an exponential temporal decay. Furthermore, when the blocks on the diagonal are Hermitian, the Liouvillian spectra obey Weyl ordering relations. The results apply, for example, to Davies generators and quadratic systems and are also demonstrated for various spin models.
We perform a systematic symmetry classification of many-body Lindblad superoperators describing general (interacting) open quantum systems coupled to a Markovian environment. Our classification is based on the behavior of the many-body Lindbladian under antiunitary symmetries and unitary involutions. We find that Hermiticity preservation reduces the number of symmetry classes, while trace preservation and complete positivity do not, and that the set of admissible classes depends on the presence of additional unitary symmetries: in their absence or in symmetry sectors containing steady states, many-body Lindbladians belong to one of ten non-Hermitian symmetry classes; if however, there are additional symmetries and we consider non-steady-state sectors, they belong to a different set of 19 classes. In both cases, it does not include classes with Kramer's degeneracy. Remarkably, our classification admits a straightforward generalization to the case of non-Markovian, and even non-trace-preserving, open quantum dynamics. While the abstract classification is completely general, we then apply it to general (long-range, interacting, spatially inhomogeneous) spin-1/21/21/2 chains. We explicitly build examples in all ten classes of Lindbladians in steady-state sectors, describing standard physical processes such as dephasing, spin injection and absorption, and incoherent hopping, thus illustrating the relevance of our classification for practical physics applications. Finally, we show that the examples in each class display unique random-matrix correlations. To fully resolve all symmetries, we employ the combined analysis of bulk complex spacing ratios and the overlap of eigenvector pairs related by symmetry operations. We further find that statistics of levels constrained onto the real and imaginary axes or close to the origin are not universal due to spontaneous breaking of Lindbladian PT symmetry.
Abstract Relaxation processes in quantum systems coupled to external environments represent one of the most fundamental nonequilibrium phenomena in condensed matter physics. The Lindblad master equation provides a powerful framework for characterizing such open quantum dynamics. In this work, we systematically investigate how different types of quantum jump operators and system geometries influence the Liouvillian gap and the properties of the nonequilibrium steady state (NESS) in finite-size systems. We demonstrate that, due to the intricate structure of the Liouvillian superoperator, multiple NESSs with unphysical characteristics can emerge. The physically meaningful steady state must instead be understood as a superposition of these NESSs that collectively satisfy the required physical constraints. Furthermore, we find that the Liouvillian gap does not necessarily increase monotonically with the system–environment coupling strength. Instead, it can exhibit a nontrivial peak structure, corresponding to a minimum in the relaxation time. The magnitude of this peak is closely related to the symmetry properties of the system. Our results provide a deeper understanding of nonequilibrium behavior in finite quantum systems and offer new insights into the design and control of open quantum dynamics.