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arXiv:1905.11422 · Physical review. B./Physical review. B

Coherent backaction between spins and an electronic bath: Non-Markovian dynamics and low-temperature quantum thermodynamic electron cooling

Stephanie Matern, Daniel Loss, Jelena Klinovaja, Bernd Braunecker

Published Oct 16, 2019• 5 citations
arXivHTMLPDF

Abstract

We provide a versatile analytical framework for calculating the dynamics of a spin system in contact with a fermionic bath beyond the Markov approximation. The approach is based on a second-order expansion of the Nakajima-Zwanzig master equation but systematically includes all quantum coherent memory effects leading to non-Markovian dynamics. Our results describe, for the free induction decay, the full time range from the non-Markovian dynamics at short times, to the well-known exponential thermal decay at long times. We provide full analytic results for the entire time range using a bath of itinerant electrons as an archetype for universal quantum fluctuations. Furthermore, we propose a quantum thermodynamic scheme to employ the temperature insensitivity of the non-Markovian decay to transport heat out of the electron system and thus, by repeated reinitialization of a cluster of spins, to efficiently cool the electrons at very low temperatures.

DOI
10.1103/physrevb.100.134308

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We provide a versatile analytical framework for calculating the dynamics of a spin system in contact with a fermionic bath beyond the Markov approximation. The approach is based on a second-order expansion of the Nakajima-Zwanzig master equation but systematically includes all quantum coherent memory effects leading to non-Markovian dynamics. Our results describe, for the free induction decay, the full time range from the non-Markovian dynamics at short times, to the well-known exponential thermal decay at long times. We provide full analytic results for the entire time range using a bath of itinerant electrons as an archetype for universal quantum fluctuations. Furthermore, we propose a quantum thermodynamic scheme to employ the temperature insensitivity of the non-Markovian decay to transport heat out of the electron system and thus, by repeated reinitialization of a cluster of spins, to efficiently cool the electrons at very low temperatures.
In this thesis we present an investigation of the influence of quantum correlations on a quantum system’s dynamical behaviour. Our focus is specifically on the time dependence of quantum spins in an environment of itinerant electrons. This is an archetype for strong correlation physics, whose dynamical onset is the central correlation effect investigated in this work. We derive an analytic result for the time evolution of a single localised quantum spin in weak contact with conduction electrons. This result is obtained from a detailed analysis of the pole structure of the Nakajima-Zwanzig equation for the reduced density matrix in Laplace space. We provide a description of the full time range, from very short times in which a novel result for non-Markovian behaviour is obtained, to long times in which we recover the well-known exponential decay expressions. For the short times we show how the non-Markovian memory effects of the spin’s dynamics arise from the backaction of coherent electronic particle-hole fluctuations. As an application of the fast dynamics we propose a cooling protocol going beyond the paradigm of thermodynamic cycles. The protocol relies on a rapid pump scheme with a repeated reinitialisation of the fast quantum coherent dynamics, with each repetition carrying away a small amount of heat from the electronic environment. This protocol is temperature independent and designed to circumvent a natural bottleneck in standard demagnetisation cooling due to long relaxation times at low temperatures. Finally we extend the dynamics to a pair of localised spins coupled through the same electronic environment, using a self-consistent projection operator framework. In contrast to the conventional RKKY coupling we derive a set of coupled equations including the temporal and spatial correlations. This set becomes finite through a meticulous identification of the electronic fluctuations responsible for the coupled dynamics, allowing for a numerical solution.
Quantum two-state systems, known as quantum bits (qubits), are unavoidably in contact with their uncontrolled thermal environment, also known as a macroscopic 'bath'. The higher the temperature of the qubits, the more impure their quantum state and the less useful they are for coherent control or quantum logic operations, hence the desirability of cooling down the qubits as much and as fast as possible, so as to purify their state prior to the desired operation. Yet, the limit on the speed of existing cooling schemes, which are all based on Markovian principles, is either the duration of the qubit equilibration with its bath or the decay time of an auxiliary state to one of the qubit states. Here we pose the conceptual question: can one bypass this existing Markovian limit? We show that highly frequent phase shifts or measurements of the state of thermalized qubits can lead to their ultrafast cooling, within the non-Markov time domain, well before they re-equilibrate with the bath and without resorting to auxiliary states. Alternatively, such operations may lead to the cooling down of the qubit to arbitrarily low temperatures at longer times. These anomalous non-Markov cooling processes stem from the hitherto unfamiliar coherent quantum dynamics of the qubit–bath interaction well within the bath memory time.
Molecular spins are promising candidates for quantum information science, leveraging coherent electronic spin states for quantum sensing and computation. However, the practical application of these systems is hindered by electronic spin decoherence, driven by interactions with nuclear spins in the molecule and the surrounding environment at low temperatures. Predicting dephasing dynamics remains a formidable challenge due to the complexity of the spin bath. In this work, we develop a non-Markovian time-convolutionless master equation to treat an electronic spin coupled to a nuclear-spin bath. By relating ab initio electronic structure parameters directly to the decoherence dynamics, we provide a framework that accounts for pure dephasing in the low-temperature limit. We apply this method to a series of molecular qubit candidates and demonstrate good agreement with experimental relaxation trends. This approach offers a computationally efficient path for the prediction of low-temperature decoherence trends in molecular spin systems.
We study the analytically solvable Ising model of a single qubit system coupled to a spin bath. The purpose of this study is to analyze and elucidate the performance of Markovian and non-Markovian master equations describing the dynamics of the system qubit, in comparison to the exact solution. We find that the time-convolutionless master equation performs particularly well up to fourth order in the system-bath coupling constant, in comparison to the Nakajima-Zwanzig master equation. Markovian approaches fare poorly due to the infinite bath correlation time in this model. A recently proposed post-Markovian master equation performs comparably to the time-convolutionless master equation for a properly chosen memory kernel, and outperforms all the approximation methods considered here at long times. Our findings shed light on the applicability of master equations to the description of reduced system dynamics in the presence of spin baths.
We introduce a systematic framework to derive the effective Hamiltonian governing the coherent dynamics of non-Markovian open quantum systems. By applying the minimal dissipation principle, we uniquely isolate the coherent contribution to the time-local generator of the reduced dynamics. We derive a general expression for the effective Hamiltonian and develop a recursive perturbative expansion that expresses it in terms of system-bath interaction terms and bath correlation functions. This expansion provides a systematic tool for analyzing energy renormalization effects across different coupling regimes. Applying our framework to paradigmatic spin systems, we reveal how environmental correlations influence energy shifts and eigenbasis rotations, offering insights into strong-coupling effects and non-Markovian quantum thermodynamics.
An exact reduced dynamical map along with its operator sum representation is derived for a central spin interacting with a thermal spin environment. The dynamics of the central spin shows high sustainability of quantum traits such as coherence and entanglement in the low-temperature regime. However, for sufficiently high temperature and when the number of bath particles approaches the thermodynamic limit, this feature vanishes and the dynamics closely mimics Markovian evolution. The properties of the long-time-averaged state and the trapped information of the initial state for the central qubit are also investigated in detail, confirming that the nonergodicity of the dynamics can be attributed to the finite temperature and finite size of the bath. It is shown that if a certain stringent resonance condition is satisfied, the long-time-averaged state retains quantum coherence, which can have far reaching technological implications in engineering quantum devices. An exact time-local master equation of the canonical form is derived. With the help of this master equation, the nonequilibrium properties of the central spin system are studied by investigating the detailed balance condition and irreversible entropy production rate. The result reveals that the central qubit thermalizes only in the limit of very high temperature and large number of bath spins.