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arXiv:1905.05432 · Physical review. E

Quantum mechanical bound for efficiency of quantum Otto heat engine

Jong-Min Park, Sangyun Lee, Hyun-Myung Chun, Jae Dong Noh

Published Jul 30, 2019• 15 citations
arXivHTMLPDF

Abstract

The second law of thermodynamics holds that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasiprobability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the ℏ-dependent quantum mechanical bound for the efficiency. It turns out that the bound is tighter than the Carnot efficiency. The engine achieves the bound in the low-temperature limit where quantum effects dominate. Our work demonstrates that quantum nature could suppress the performance of heat engines in terms of efficiency bound, work, and power output.

DOI
10.1103/physreve.100.012148

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•Jan 1, 2020•1 citation
The second law of thermodynamics holds that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasiprobability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the ℏ-dependent quantum mechanical bound for the efficiency. It turns out that the bound is tighter than the Carnot efficiency. The engine achieves the bound in the low-temperature limit where quantum effects dominate. Our work demonstrates that quantum nature could suppress the performance of heat engines in terms of efficiency bound, work, and power output.
Thermodynamic constraints impose a trade-off between power and efficiency in heat engines, preventing the simultaneous achievement of high power and high efficiency. For classical microscopic engines, explicit inequalities have been discovered, demonstrating the inherent inevitability of this power-efficiency trade-off. However, extensions of these results to quantum engines have so far been limited to cases of slow operation. In this study, we derive a power-efficiency trade-off relation for a paradigmatic quantum engine operating within a finite time, specifically the Otto cycle of a quantum harmonic oscillator. By utilizing a phase-space approach based on quasiprobability representations, we establish a universal trade-off relation applicable to arbitrary time-dependent protocols during the adiabatic processes. Our results reveal that the power of the quantum engine vanishes as the efficiency approaches the quantum-mechanical efficiency bound, which is stricter than the Carnot bound. Furthermore, we identify the conditions under which the upper bound is attained, which indicate maximum power is achieved when the generation of quantum coherence is reduced, and the difference in time durations of the isochoric processes increases. These findings are validated through numerical calculations, which confirm their applicability across various types of protocols for heat engine cycles.
From an entropy-based formulation of the first law of thermodynamics in the quantum regime, we investigate the performance of Otto-like and Carnot-like engines for a single-qubit working medium. Within this framework, the first law includes an additional contribution-coherence work-that quantifies the energetic cost of deviating the quantum trajectory from its natural unitary evolution. We focus on the efficiency of the heat-to-coherence work conversion and show that the Carnot cycle achieves the classical Carnot efficiency, while the performance of the Otto cycle is upper-bounded by the Carnot efficiency corresponding to the extreme temperatures of the cycle. We identify entropy generation during the isochoric stages as the key source of irreversibility limiting the Otto cycle's efficiency.
The quantum heat engines have drawn much attention due to miniaturization of devices recently. We study the dynamics of the quantum Otto heat engine using the driven-dissipative Schrödinger equation. Starting from different initial states, we simulate the time evolutions of the internal energy, power and heat-work conversion efficiency. The initial state impacts on these thermodynamic quantities before the Otto cycle reaches stable. In the transition period, the efficiency and power may be higher or lower than the corresponding values in the cyclostationary state. Remarkably, the efficiency could surpass the Otto limit and even the Carnot limit and the power could be much higher than the rated power. The efficiency anomaly is due to the energy in the initial state. Thus, we suggest that periodically pumping could take the similar role of a hot bath but could be manipulated flexibly. Furthermore, we propose a new quantum engine working in a single reservoir to convert the pump energy into mechanical work. This manipulative engine could potentially be applied to working in the microenvironments without a large temperature difference, such as the biological tissues in vivo. Our protocol is expected to model a new quantum engine with the advantage of applicability and controllability.
We investigate the performance of a quantum thermal machine operating in finite time based on shortcut-to-adiabaticity techniques. We compute efficiency and power for a paradigmatic harmonic quantum Otto engine by taking the energetic cost of the shortcut driving explicitly into account. We demonstrate that shortcut-to-adiabaticity machines outperform conventional ones for fast cycles. We further derive generic upper bounds on both quantities, valid for any heat engine cycle, using the notion of quantum speed limit for driven systems. We establish that these quantum bounds are tighter than those stemming from the second law of thermodynamics.
This paper establishes an entangled otto quantum heat engine(EQHE) working with the two-qubit anisotropic Heisenberg XXZ model.Based on the first law of quantum thermodynamics,we derive the expressions for the net work and the efficiency of EQHE.By numerical calculation we plot three dimensional graphics between the efficiency and the concurrence.It is found that the efficiency of the EQHE is smaller than the Carnot efficiency and the validity of the second law of thermodynamics is confirmed;The region of non-zero efficiency is mainly distributed in C1C2 and the value of efficiency and region of non-zero efficiency increase with the increase of the ratio of the temperature γ.The efficiency of the EQHE is discussed in two special cases Δ=0 and Δ=1.
In this work we study the effect of quantum and thermal fluctuations on the statistics of quantum heat engine performance parameters, like efficiency and power. We begin by deriving an explicit solution for the characteristic function of the heat distribution of a thermal quantum harmonic oscillator. We then derive a general framework based on the standard two-point-measurement scheme to compute the efficiency distribution of a quantum Otto cycle. We analyze the generic properties of this distribution for scale-invariant driving Hamiltonians which describe a large class of single-particle, many-body, and nonlinear systems. We find that the efficiency is deterministic and that its mean is equal to the macroscopic efficiency for adiabatic driving. We continue our research by studying the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follow the ’universal’ theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We can relate this unusual property to the perfect anticorrelation between work output and heat input that suppresses thermal as well as quantum fluctuations. We then probe our findings in an experimental NMR setup using spin-1/2 systems and find them to agree rather well with our theoretical predictions. Afterward, we move on to the finite-time quantum Carnot cycle and investigate its power fluctuations. In particular, we consider how level degeneracy and level number, two commonly found properties in quantum systems, influence the relative work fluctuations. We find that their optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results highlight that these parameters can be employed to realize high-performance, high-stability cyclic quantum heat engines.