Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasonable resource theory of local activity for a multimode bosonic system, where we identify as free any state that is obtained from a product of thermal states (possibly at different temperatures) acted upon by any linear-optics (passive Gaussian) transformation. The associated free operations are then all linear-optics transformations supplemented with tensoring and partial tracing. We show that the local Gaussian extractable work (if each party applies a Gaussian unitary, assisted with linear optics) is zero if and only if the covariance matrix of the system is that of a free state. Further, we develop a resource theory of local Gaussian extractable work, defined as the difference between the trace and symplectic trace of the covariance matrix of the system. We prove that it is a resource monotone that cannot increase under free operations. We also provide examples illustrating the distillation of local activity and local Gaussian extractable work.
Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasonable resource theory of local activity for a multimode bosonic system, where we identify as free any state that is obtained from a product of thermal states (possibly at different temperatures) acted upon by any linear-optics (passive Gaussian) transformation. The associated free operations are then all linear-optics transformations supplemented with tensoring and partial tracing. We show that the local Gaussian extractable work (if each party applies a Gaussian unitary, assisted with linear optics) is zero if and only if the covariance matrix of the system is that of a free state. Further, we develop a resource theory of local Gaussian extractable work, defined as the difference between the trace and symplectic trace of the covariance matrix of the system. We prove that it is a resource monotone that cannot increase under free operations. We also provide examples illustrating the distillation of local activity and local Gaussian extractable work.
We study the energy exchange between two bosonic systems that interact via bilinear transformations in the mode operators. The first mode is considered as the thermodynamic system, while the second is regarded as the bath. This work finds its roots in a very recent formulation of quantum thermodynamics [Bera et al., Quantum 3, 121 (2019)] which allows one to consider baths that are not described by the usual Boltzmann-Gibbs canonical form. Baths can possess quantum properties, such as squeezing or coherence, and can be initially correlated with the system, even through entanglement. We focus mainly on the case of Gaussian states, by quantifying the relation between their defining parameters, namely the mean values of the quadratures and the covariance matrix, and relevant thermodynamical quantities such as the heat exchanged and the work performed during the interaction process. We fully solve the case of initially uncorrelated Gaussian states and provide the most general form of the first law of thermodynamics in this case. We also discuss the case of initially correlated states by considering a number of relevant examples, studying how correlations can assist some phenomena, e.g., work extraction or anomalous heat flows. Finally, we present an information-theoretic approach based on the Renyi entropy of order two for clarifying more generally the role of correlations on heat exchanges.
The ideas of thermodynamics have proved fruitful in the setting of quantum information theory, in particular the notion that when the allowed transformations of a system are restricted, certain states of the system become useful resources with which one can prepare previously inaccessible states. The theory of entanglement is perhaps the best-known and most well-understood resource theory in this sense. Here, we return to the basic questions of thermodynamics using the formalism of resource theories developed in quantum information theory and show that the free energy of thermodynamics emerges naturally from the resource theory of energy-preserving transformations. Specifically, the free energy quantifies the amount of useful work which can be extracted from asymptotically many copies of a quantum system when using only reversible energy-preserving transformations and a thermal bath at fixed temperature. The free energy also quantifies the rate at which resource states can be reversibly interconverted asymptotically, provided that a sublinear amount of coherent superposition over energy levels is available, a situation analogous to the sublinear amount of classical communication required for entanglement dilution.
Active states, from which work can be extracted by time-dependent perturbations, are an important resource for quantum thermodynamics in the absence of heat baths. Here we characterize this resource, establishing a resource theory that captures the operational scenario where an experimenter manipulates a quantum system by means of energy-preserving operations and resets to non-active states. Our resource theory comes with simple conditions for state convertibility and an experimentally accessible resource quantifier that determines the maximum advantage of active states in the task of producing approximations of the maximally coherent state by means of energy-preserving quantum operations.
Resource theories are a set of tools, coming from the field of quantum information theory, that find applications in the study of several physical scenarios. These theories describe the physical world from the perspective of an agent, who acts over a system to modify its quantum state, while having at disposal a limited set of operations. A noticeable example of a physical theory which has recently been described with these tools is quantum thermodynamics, consisting in the study of thermodynamic phenomena at the nano-scale. In the standard approach to resource theories, it is usually the case that the constraints over the set of available operations single out a unique resource. In this thesis, we extend the resource theoretic framework to include situations where multiple resources can be identified, and we apply our findings to the study of quantum thermodynamics, to gain a better understanding of quantities like work and heat in the microscopic regime. We introduce a mathematical framework to study resource theories with multiple resources, and we explore under which conditions these multi-resource theories are reversible. Furthermore, we investigate the interconversion of resources, i.e., in which situations it is possible to exchange between two different kinds of resources. We then apply this formalism to quantum thermodynamics, where the two resources under consideration are energy and entropy. This multi-resource theory allows us to explore thermodynamics when the system under examination is closed or coupled with a thermal environment with a finite size. In addition to our work on multi-resource theories, we study the states of equilibrium of closed systems, known as passive states, and analyse under which circumstances it is possible to extract energy from these states. We show that passivity is energetically unstable, and that, even for closed systems, the only stable states are those with a well-defined temperature.
Work extractable from quantum systems can be viewed as a resource to perform some tasks. Here, we try to relate the work extractable to some resource theory. To do this, we consider completely passive states and passive states as free states and, by identifying the free operations, formulate resource theories where the maximum work extractable is a monotone. In particular, we study how the free operations act on the free states, showing how a sort of temperature plays a pivotal role in these resource theories.
The resource theory approach is a recently developed framework used in the study of thermodynamics for finite sized quantum systems. A simple way to describe how a quantum system evolves under energy-preserving unitaries while interacting with thermal reservoirs, has been formulated in the framework of thermal operations. Despite the conceptual simplicity of these operations, much is still unknown about their mathematical structures. In this work, we studied these mathematical structures, in an attempt to better understand how these operations, and some variants, describe quantum thermodynamics. One of the interesting phenomena that occurs in quantum thermodynamics, is something that we call super-activation. In this phenomenon, we make multiple forbidden transitions possible by combining them together. This phenomenon could, for example, be used to extract more work from two systems, while it is impossible to extract any work from the individual systems. We found conditions for when this phenomenon can occur. As a result of this, we found that qubits with trivial Hamiltonians cannot super-activate each other. On the other hand, we found a way to construct infinitely many examples of super-activation. We also investigated what happens if we combine multiples of the same forbidden transitions together. We found necessary conditions which each have to satisfy in order for this joint transition to be possible. In particular, these conditions show that this special case of super-activation can only occur in one direction. Another topic that we studied in this work is smoothed Rényi divergences. In an attempt to give an operational meaning to these quantities, we studied two special states that allow us to clarify the relation between the smoothed Rényi divergences with the possibility of a transition. These special states are the steepest state and the attest state. For a given state p, the steepest state is a state that is e-close to p in terms of trace distance and can be transformed, in the presence of a thermal bath and while conserving the total energy, to any other state that is also e-close to p. The attest state is a state that is also e-close to p in terms of trace distance, but all e-close states of p can be transformed to it. We found a way to construct this steepest state for limited values of e, and the attest state for any e.