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arXiv:2001.04677 · Physical Review A

Quantum thermodynamics of two bosonic systems

Chiara Macchiavello, Alberto Riccardi, Massimiliano Federico Sacchi

Published Jun 19, 2020• 12 citations
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Abstract

We study the energy exchange between two bosonic systems that interact via bilinear transformations in the mode operators. The first mode is considered as the thermodynamic system, while the second is regarded as the bath. This work finds its roots in a very recent formulation of quantum thermodynamics [Bera et al., Quantum 3, 121 (2019)] which allows one to consider baths that are not described by the usual Boltzmann-Gibbs canonical form. Baths can possess quantum properties, such as squeezing or coherence, and can be initially correlated with the system, even through entanglement. We focus mainly on the case of Gaussian states, by quantifying the relation between their defining parameters, namely the mean values of the quadratures and the covariance matrix, and relevant thermodynamical quantities such as the heat exchanged and the work performed during the interaction process. We fully solve the case of initially uncorrelated Gaussian states and provide the most general form of the first law of thermodynamics in this case. We also discuss the case of initially correlated states by considering a number of relevant examples, studying how correlations can assist some phenomena, e.g., work extraction or anomalous heat flows. Finally, we present an information-theoretic approach based on the Renyi entropy of order two for clarifying more generally the role of correlations on heat exchanges.

DOI
10.1103/physreva.101.062326

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We study the energy exchange between two bosonic systems that interact via bilinear transformations in the mode operators. The first mode is considered as the thermodynamic system, while the second is regarded as the bath. This work finds its roots in a very recent formulation of quantum thermodynamics [Bera et al., Quantum 3, 121 (2019)] which allows one to consider baths that are not described by the usual Boltzmann-Gibbs canonical form. Baths can possess quantum properties, such as squeezing or coherence, and can be initially correlated with the system, even through entanglement. We focus mainly on the case of Gaussian states, by quantifying the relation between their defining parameters, namely the mean values of the quadratures and the covariance matrix, and relevant thermodynamical quantities such as the heat exchanged and the work performed during the interaction process. We fully solve the case of initially uncorrelated Gaussian states and provide the most general form of the first law of thermodynamics in this case. We also discuss the case of initially correlated states by considering a number of relevant examples, studying how correlations can assist some phenomena, e.g., work extraction or anomalous heat flows. Finally, we present an information-theoretic approach based on the Renyi entropy of order two for clarifying more generally the role of correlations on heat exchanges.
We provide a characterization of energy in the form of exchanged heat and work between two interacting constituents of a closed, bipartite, correlated quantum system. By defining a binding energy we derive a consistent quantum formulation of the first law of thermodynamics, in which the role of correlations becomes evident, and this formulation reduces to the standard classical picture in relevant systems. We next discuss the emergence of the second law of thermodynamics under certain-but fairly general-conditions such as the Markovian assumption. We illustrate the role of correlations and interactions in thermodynamics through two examples.
Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasonable resource theory of local activity for a multimode bosonic system, where we identify as free any state that is obtained from a product of thermal states (possibly at different temperatures) acted upon by any linear-optics (passive Gaussian) transformation. The associated free operations are then all linear-optics transformations supplemented with tensoring and partial tracing. We show that the local Gaussian extractable work (if each party applies a Gaussian unitary, assisted with linear optics) is zero if and only if the covariance matrix of the system is that of a free state. Further, we develop a resource theory of local Gaussian extractable work, defined as the difference between the trace and symplectic trace of the covariance matrix of the system. We prove that it is a resource monotone that cannot increase under free operations. We also provide examples illustrating the distillation of local activity and local Gaussian extractable work.
Abstract The treatment of quantum thermodynamic systems beyond weak coupling is of increasing relevance, yet extremely challenging. The evaluation of thermodynamic quantities in strong-coupling regimes requires a nonperturbative knowledge of the bath dynamics, which in turn relies on heavy numerical simulations. To tame these difficulties, considering thermal bosonic baths linearly coupled to the open system, we derive expressions for heat, work, and average system-bath interaction energy that only involve the autocorrelation function of the bath and two-time expectation values of system operators. We then exploit the pseudomode approach, which replaces the physical continuous bosonic bath with a small finite number of damped, possibly interacting, modes, to numerically evaluate these relevant thermodynamic quantities. We show in particular that this method allows for an efficient numerical evaluation of thermodynamic quantities in terms of one-time expectation values of the open system and the pseudomodes. We apply this framework to the investigation of two paradigmatic situations. In the first instance, we study the entropy production for a two-level system (TLS) coupled to an ohmic bath, simulated via interacting pseudomodes, allowing for the presence of time-dependent driving. Secondly, we consider a quantum thermal machine composed of a TLS interacting with two thermal baths at different temperatures, showing that an appropriate sinusoidal modulation of the coupling with the cold bath only is enough to obtain work extraction.
The study of thermal operations allows one to investigate the ultimate possibilities of quantum states and of nanoscale thermal machines. Whilst fairly general, these results typically do not apply to continuous variable systems and do not take into account that, in many practically relevant settings, system-environment interactions are effectively bilinear. Here we tackle these issues by focusing on Gaussian quantum states and channels. We provide a complete characterization of the most general Gaussian thermal operation acting on an arbitrary number of bosonic modes, which turn out to be all embeddable in a Markovian dynamics, and derive necessary and sufficient conditions for state transformations under such operations in the single-mode case, encompassing states with nonzero coherence in the energy eigenbasis (i.e., squeezed states). Our analysis leads to a no-go result for the technologically relevant task of algorithmic cooling: We show that it is impossible to reduce the entropy of a system coupled to a Gaussian environment below its own or the environmental temperature, by means of a sequence of Gaussian thermal operations interspersed by arbitrary (even non-Gaussian) unitaries. These findings establish fundamental constraints on the usefulness of Gaussian resources for quantum thermodynamic processes.
The question of with what we associate work and heat in a quantum thermodynamic process has been extensively discussed, mostly for systems with time-dependent Hamiltonians. In this paper, we aim to investigate the energy exchanged between two quantum systems through interaction where the Hamiltonian of the system is time-independent. An entropy-based re-definitions of heat and work are presented for these quantum thermodynamic systems therefore an entropy-based formalism of both the first and the second laws of thermodynamics are introduced. We will use the genuine reasoning based on which Clausius originally defined work and heat. The change in the energy which is accompanied by a change in the entropy is identified as heat, while any change in the energy which does not lead to a change in the entropy is known as work. It will be seen that quantum coherence does not allow all the energy exchanged between two quantum systems to be only of the heat form. Several examples will also be discussed. Finally, we will examine irreversibility from our entropy-based formalism of quantum thermodynamics.
The laws of thermodynamics strongly restrict the performance of thermal machines. Standard thermodynamics, initially developed for uncorrelated macroscopic systems, does not hold for microscopic systems correlated with their environments. We here derive an exact formula for the efficiency of any cyclically driven quantum engine by using generalized laws of quantum thermodynamics that account for all possible correlations between all involved parties, including initial correlations. Furthermore, we demonstrate the existence of two basic modes of engine operation: the usual thermal case, where heat is converted into work, and an athermal regime, where work is extracted from entropic resources, such as system-bath correlations. In the latter regime, the efficiency is not bounded by the usual Carnot formula. Our results provide a unified formalism to determine the efficiency of correlated microscopic quantum machines.