Active states, from which work can be extracted by time-dependent perturbations, are an important resource for quantum thermodynamics in the absence of heat baths. Here we characterize this resource, establishing a resource theory that captures the operational scenario where an experimenter manipulates a quantum system by means of energy-preserving operations and resets to non-active states. Our resource theory comes with simple conditions for state convertibility and an experimentally accessible resource quantifier that determines the maximum advantage of active states in the task of producing approximations of the maximally coherent state by means of energy-preserving quantum operations.
Active states, from which work can be extracted by time-dependent perturbations, are an important resource for quantum thermodynamics in the absence of heat baths. Here we characterize this resource, establishing a resource theory that captures the operational scenario where an experimenter manipulates a quantum system by means of energy-preserving operations and resets to non-active states. Our resource theory comes with simple conditions for state convertibility and an experimentally accessible resource quantifier that determines the maximum advantage of active states in the task of producing approximations of the maximally coherent state by means of energy-preserving quantum operations.
Abstract Thermodynamics plays an important role both in the foundations of physics and in technological applications. An operational perspective adopted in recent years is to formulate it as a quantum resource theory. At the core of this theory is the interconversion between athermality states, i.e. states out of thermal equilibrium. Here, we solve the question of how athermality can be used to heat and cool other quantum systems that are initially at thermal equilibrium. We then show that the convertibility between quasi-classical resources (resources that do not exhibit coherence between different energy eigenstates) is fully characterized by their ability to cool and heat qubits, i.e. by two of the most fundamental thermodynamical tasks on the simplest quantum systems.
Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasonable resource theory of local activity for a multimode bosonic system, where we identify as free any state that is obtained from a product of thermal states (possibly at different temperatures) acted upon by any linear-optics (passive Gaussian) transformation. The associated free operations are then all linear-optics transformations supplemented with tensoring and partial tracing. We show that the local Gaussian extractable work (if each party applies a Gaussian unitary, assisted with linear optics) is zero if and only if the covariance matrix of the system is that of a free state. Further, we develop a resource theory of local Gaussian extractable work, defined as the difference between the trace and symplectic trace of the covariance matrix of the system. We prove that it is a resource monotone that cannot increase under free operations. We also provide examples illustrating the distillation of local activity and local Gaussian extractable work.
Resource theories are a set of tools, coming from the field of quantum information theory, that find applications in the study of several physical scenarios. These theories describe the physical world from the perspective of an agent, who acts over a system to modify its quantum state, while having at disposal a limited set of operations. A noticeable example of a physical theory which has recently been described with these tools is quantum thermodynamics, consisting in the study of thermodynamic phenomena at the nano-scale. In the standard approach to resource theories, it is usually the case that the constraints over the set of available operations single out a unique resource. In this thesis, we extend the resource theoretic framework to include situations where multiple resources can be identified, and we apply our findings to the study of quantum thermodynamics, to gain a better understanding of quantities like work and heat in the microscopic regime. We introduce a mathematical framework to study resource theories with multiple resources, and we explore under which conditions these multi-resource theories are reversible. Furthermore, we investigate the interconversion of resources, i.e., in which situations it is possible to exchange between two different kinds of resources. We then apply this formalism to quantum thermodynamics, where the two resources under consideration are energy and entropy. This multi-resource theory allows us to explore thermodynamics when the system under examination is closed or coupled with a thermal environment with a finite size. In addition to our work on multi-resource theories, we study the states of equilibrium of closed systems, known as passive states, and analyse under which circumstances it is possible to extract energy from these states. We show that passivity is energetically unstable, and that, even for closed systems, the only stable states are those with a well-defined temperature.
We introduce the resource-theoretic free energy of a quantum channel as the maximal work extractable from the channel as its output equilibrates to a thermal state and its reference system remains locally intact. It is proportional to the relative entropy between the given channel and the absolutely thermal channel. It attains a clear operational meaning as twice the asymptotic rates of athermality distillation and formation under Gibbs-preserving superchannels, which map one absolutely thermal channel to another for a given bath, thereby revealing the asymptotic reversibility of the resource theory of athermality for quantum channels. Consequently, we establish that the optimal extractable work in converting one channel to another through the asymptotic athermality distillation and formation tasks equals the difference in their free energies. We call this optimal work the thermodynamic work capacity of channel conversion. Quantum information processing and computing fundamentally concern the manipulation and transformation of quantum channels, which encompass quantum states, their transformations, and measurements. A quantitative characterization of the optimal thermodynamic work gain or expenditure in quantum information processing constitutes a key step toward formulating thermodynamics of quantum processes.
In this paper we aim to push the analogy between thermodynamics and quantum resource theories one step further. Previous inspirations were based predominantly on thermodynamic considerations concerning scenarios with a single heat bath, neglecting an important part of thermodynamics that studies heat engines operating between two baths at different temperatures. Here, we investigate the performance of resource engines, which replace the access to two heat baths at different temperatures with two arbitrary constraints on state transformations. The idea is to imitate the action of a two–stroke heat engine, where the system is sent to two agents (Alice and Bob) in turns, and they can transform it using their constrained sets of free operations. We raise and address several questions, including whether or not a resource engine can generate a full set of quantum operations or all possible state transformations, and how many strokes are needed for that. We also explain how the resource engine picture provides a natural way to fuse two or more resource theories, and we discuss in detail the fusion of two resource theories of thermodynamics with two different temperatures, and two resource theories of coherence with respect to two different bases.
Understanding whether uniquely quantum features can provide concrete advantages in thermodynamic processes is a central objective of quantum thermodynamics. A key challenge is quantifying how different forms of non-classicality can be systematically harnessed to enhance thermodynamic tasks. In light of this, we prove that any form of non-classicality can serve as a thermodynamic resource. In particular, any system that possesses quantum magic, coherence, or non-classical correlations can be leveraged to extract higher amounts of work than if the system does not possess such resources. The quantum thermodynamic advantages--quantified by the ratio between work extractable from a resource state and work extractable in its absence--increase with the resource robustness. We show that for any convex quantum resource theory, any resourceful state can yield a work-extraction advantage over all free states via a cyclic quench/thermalization protocol whose Hamiltonian is engineered from an optimal robustness witness. We illustrate concrete examples in which the robustness measures increase with the system's dimension, yielding quantum thermodynamic advantages that scale with it. In contrast, we also show that preparing a resource state (e.g., one with magic, coherence, or non-classical correlations) can be significantly more thermodynamically costly than preparing any state without such a resource. Concretely, there always exists a protocol that can prepare any non-resourceful state at significantly less work than it takes to prepare a resourceful state. Overall, our results provide operational meaning to robustness measures of quantum resources in terms of their thermodynamic costs and advantages.