In Newtonian mechanics, any closed-system dynamics of a composite system in a microstate will leave all its individual subsystems in distinct microstates, however this fails dramatically in quantum mechanics due to the existence of quantum entanglement. Here we introduce the notion of a `coherent work process', and show that it is the direct extension of a work process in classical mechanics into quantum theory. This leads to the notion of `decomposable' and `non-decomposable' quantum coherence and gives a new perspective on recent results in the theory of asymmetry as well as early analysis in the theory of classical random variables. Within the context of recent fluctuation relations, originally framed in terms of quantum channels, we show that coherent work processes play the same role as their classical counterparts, and so provide a simple physical primitive for quantum coherence in such systems. We also introduce a pure state effective potential as a tool with which to analyze the coherent component of these fluctuation relations, and which leads to a notion of temperature-dependent mean coherence, provides connections with multi-partite entanglement, and gives a hierarchy of quantum corrections to the classical Crooks relation in powers of inverse temperature.
In Newtonian mechanics, any closed-system dynamics of a composite system in a microstate will leave all its individual subsystems in distinct microstates, however this fails dramatically in quantum mechanics due to the existence of quantum entanglement. Here we introduce the notion of a coherent work process', and show that it is the direct extension of a work process in classical mechanics into quantum theory. This leads to the notion of decomposable' and `non-decomposable' quantum coherence and gives a new perspective on recent results in the theory of asymmetry as well as early analysis in the theory of classical random variables. Within the context of recent fluctuation relations, originally framed in terms of quantum channels, we show that coherent work processes play the same role as their classical counterparts, and so provide a simple physical primitive for quantum coherence in such systems. We also introduce a pure state effective potential as a tool with which to analyze the coherent component of these fluctuation relations, and which leads to a notion of temperature-dependent mean coherence, provides connections with multi-partite entanglement, and gives a hierarchy of quantum corrections to the classical Crooks relation in powers of inverse temperature.
Of indisputable relevance for nonequilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists of treating work as a stochastic variable and the acting system as an eminently classical device with a deterministic dynamics. Inspired by technological advances in the field of quantum machines, here we look for corrections to work fluctuations theorems when the acting system is allowed to enter the quantum domain. This entails including the acting system in the dynamics and letting it share a nonclassical state with the system acted upon. Moreover, favoring a mechanical perspective to this program, we employ a concept of work observable. For simplicity, we choose as theoretical platform the autonomous dynamics of a two-particle system with an elastic coupling. For some specific processes, we derive several fluctuation theorems within both the quantum and classical statistical arenas. In the quantum results, we find that, along with entanglement and quantum coherence, aspects of inertia also play a significant role since they regulate the route to mechanical equilibrium.
The notion of coherence, intimately related to the notion of wave-particle duality, plays a central role in quantum mechanics. When quantum coherence extends over several particles inside a system, the description in terms of individual objects becomes impossible, due to the development of quantum correlations (or entanglement). In this manuscript, we focus on equilibrium systems, for which we show that coherent fluctuations add up to the fluctuations predicted by thermodynamic identities, valid for classical systems only. In the ground state, coherent fluctuations are the only ones to subsist, an in this case we study their relationship with entanglement entropy. We show in particular that an hypothesis of effective temperature, spatially modulated, captures the structure of entanglement in a many-body system, and we show how this temperature can be reconstructed from usual correlation functions. Our results also enable for a refined understanding of quantum phase transitions. We show in particular that the phase transition between a bosonic Mott insulator and a superfluid gives rise to a singularity of entanglement entropy induced by amplitude fluctuations of the phase of the condensate. We finally identify a coherence length governing the scaling behaviour of coherent fluctuations inside the quantum critical region in the finite-temperature vicinity of a quantum critical point, and open novel perspectives for the metrological advantage offered by the exceptional coherence which develops close to quantum critical points, based on the example of the quantum Ising model.
Based on the superposition principle, any two states of a quantum system may be coherently superposed to yield a novel state. Such a simple construction is at the heart of genuinely quantum phenomena such as interference of massive particles or quantum entanglement. Yet, these superpositions are susceptible to environmental influences, eventually leading to a complete disappearance of the system's quantum character. In principle, two distinct mechanisms responsible for this process of decoherence may be identified. In a classical decoherence setting, on the one hand, stochastic fluctuations of classical, ambient fields are the relevant source. This approach leads to a formulation in terms of stochastic Hamiltonians; the dynamics is unitary, yet stochastic. In a quantum decoherence scenario, on the other hand, the system is described in the language of open quantum systems. Here, the environmental degrees of freedom are to be treated quantum mechanically, too. The loss of coherence is then a direct consequence of growing correlations between system and environment. The purpose of the present thesis is to clarify the distinction between classical and quantum decoherence. It is known that there exist decoherence processes that are not reconcilable with the classical approach. We deem it desirable to have a simple, feasible model at hand of which it is known that it cannot be understood in terms of fluctuating fields. Indeed, we find such an example of true quantum decoherence. The calculation of the norm distance to the convex set of classical dynamics allows for a quantitative assessment of the results. In order to incorporate genuine irreversibility, we extend the original toy model by an additional bath. Here, the fragility of the true quantum nature of the dynamics under increasing coupling strength is evident. The geometric character of our findings offers remarkable insights into the geometry of the set of non-classical decoherence maps. We give a very intuitive geometrical measure---a volume---for the quantumness of dynamics. This enables us to identify the decoherence process of maximum quantumness, that is, having maximal distance to the convex set of dynamics consistent with the stochastic, classical approach. In addition, we observe a distinct correlation between the decoherence potential of a given dynamics and its achievable quantumness. In a last step, we study the notion of quantum decoherence in the context of a bipartite system which couples locally to the subsystems' respective environments. A simple argument shows that in the case of a separable environment the resulting dynamics is of classical nature. Based on a realistic experiment, we analyze the impact of entanglement between the local environments on the nature of the dynamics. Interestingly, despite the variety of entangled environmental states scrutinized, no single instance of true quantum decoherence is encountered. In part, the identification of the classical nature relies on numerical schemes. However, for a large class of dynamics, we are able to exclude analytically the true quantum nature.
Abstract We investigate manipulations of pure quantum states under incoherent or strictly incoherent operations assisted by a coherence battery, that is, a storage device whose degree of coherence is allowed to fluctuate in the process. This leads to the derivation of fluctuation relations for quantum coherence, analogous to Jarzynski’s and Crooks’ relations for work in thermodynamics. Coherence is thus revealed as another instance of a physical resource, in addition to athermality and entanglement, for which a connection is established between the majorisation framework (regulating pure state transformations under suitable free operations) and the emergence of fluctuation theorems. Our study is hoped to provide further insight into the general structure of battery assisted quantum resource theories, and more specifically into the interplay between quantum coherence and quantum thermodynamics.
We establish the general framework of quantum fluctuation theorems by finding the symmetry between the forward and backward transitions of any given quantum channel. The Petz recovery map is adopted as the reverse quantum channel, and the notion of entropy production in thermodynamics is extended to the quantum regime. Our result shows that the fluctuation theorems, which are normally considered for thermodynamic processes, can be a powerful tool to study the detailed statistics of quantum systems as well as the effect of coherence transfer in an arbitrary non-equilibrium quantum process. We introduce a complex-valued entropy production to fully understand the relation between the forward and backward processes through the quantum channel. We find the physical meaning of the imaginary part of entropy production to witness the broken symmetry of the quantum channel. We also show that the imaginary part plays a crucial role in deriving the second law from the quantum fluctuation theorem. The dissipation and fluctuation of various quantum resources including quantum free energy, asymmetry and entanglement can be coherently understood in our unified framework. Our fluctuation theorem can be applied to a wide range of physical systems and dynamics to query the reversibility of a quantum state for the given quantum processing channel involving coherence and entanglement.
In this work our aim is to study several aspects related to quantum coherence as understood to correspond with the non-classical behaviour that can be observed for certain particular states of a physical system. In particular we are interested in the possible mechanisms that result in dynamically induced transitions between quantum and classical regimes. The thesis is organized as follows: The first chapter dubs as an introduction and serves to set out the basic philosophy underlying the questions addressed in this thesis. It also presents some elementary properties of states and state spaces in Quantum Theory including what we have chosen to define as classical and quantum behaviour. In chapter 2 we study some of the aspects related to observing quantum behaviour and of the properties of our main definition of classicality (and quantumness). Here we also study some of the restrictions imposed on measurements by the existence of globally conserved quantities (Wigner-Araki-Yanase theorem) and their relationship to weak measurements coupled to postselection. In the following chapter we review some of the basic tools used in the description of open quantum system dynamics that will be applied in other chapters. In chapter 4 we review the basics of decoherence and analyse the importance of the choice of initial conditions when trying to study the dynamical emergence of classical behaviour within Quantum Theory. Next we study the other direction of the transition and focus on how to obtain pure quantum states from states that originally were classically mixed. Along the same lines, in chapter 6 we cover some topics related to the production of pure quantum states from measurements. We pay special attention to a model of the non-selective continuous monitoring of a system coupled to another unmonitored system. Lastly we explore some of the possible similarities between the theory of phase transitions and the quantum-classical transition. We must emphasize that all the work done in this thesis assumes that Quantum Theory is generally valid (at least within a broad enough range of energies). Thus, when we say that a state is “classical” we will mainly be referring to one of all the possible states contained in Quantum Theory, but that is susceptible to being interpreted as corresponding to “classical” behaviour. Similarly when we speak of creating a “quantum”, or “quantum coherent”, state we mean that the system has evolved to this state from one of the “classical” ones, but all of these still correspond to valid states within Quantum Theory. In the opinion of the author the main original contributions that can be found in this thesis are the following: - The recognition of the relationship between the Wigner-Araki-Yanase theorem and weak measurements coupled to postselection (sections 2.2 and 2.4); - A mathematical proof of the possible ambiguities arising when two observers try to decide if a state corresponds to quantum or classical behaviour (section 2.6); - The implications of initial correlations in decoherence models. In particular how the choice of certain (correlated) initial conditions can result in residual coherence and the production of pure quantum states in a model that otherwise results in ideal decoherence when (locally equivalent) uncorrelated initial conditions are used (section 4.2); - Various results related to the production of quantum states from initially classical states (sections 5.2 to 5.4); - The analysis of the inverse of a generalized depolarizing channel (section 5.7); - The study of a model of the non-selective continuous monitoring, in the quantum Zeno limit, of a subsystem A interacting with an unmonitored subsystem B. In particular the absence of the purification of B, which has been previously predicted in the selective case, but the possibility of coherent dynamics for B (section 6.4); - The identification of the loose equivalent of a broken symmetry and order parameter in the quantum-classical transition (section 7.2).