Abstract We investigate manipulations of pure quantum states under incoherent or strictly incoherent operations assisted by a coherence battery, that is, a storage device whose degree of coherence is allowed to fluctuate in the process. This leads to the derivation of fluctuation relations for quantum coherence, analogous to Jarzynski’s and Crooks’ relations for work in thermodynamics. Coherence is thus revealed as another instance of a physical resource, in addition to athermality and entanglement, for which a connection is established between the majorisation framework (regulating pure state transformations under suitable free operations) and the emergence of fluctuation theorems. Our study is hoped to provide further insight into the general structure of battery assisted quantum resource theories, and more specifically into the interplay between quantum coherence and quantum thermodynamics.
Abstract We investigate manipulations of pure quantum states under incoherent or strictly incoherent operations assisted by a coherence battery, that is, a storage device whose degree of coherence is allowed to fluctuate in the process. This leads to the derivation of fluctuation relations for quantum coherence, analogous to Jarzynski’s and Crooks’ relations for work in thermodynamics. Coherence is thus revealed as another instance of a physical resource, in addition to athermality and entanglement, for which a connection is established between the majorisation framework (regulating pure state transformations under suitable free operations) and the emergence of fluctuation theorems. Our study is hoped to provide further insight into the general structure of battery assisted quantum resource theories, and more specifically into the interplay between quantum coherence and quantum thermodynamics.
Fluctuation theorems provide universal constraints on nonequilibrium energy and entropy fluctuations, making them a natural framework to assess how and to what extent quantum resources become thermodynamically relevant. We develop a unified framework for incorporating a generic quantum resource, including athermality, quantum coherence, and entanglement, into fluctuation theorems. We work within the end point measurement scheme, which avoids an initial energy measurement and allows quantum resources in the initial state to affect nonequilibrium energy statistics. We derive a family of quantum fluctuation theorems, including generalized Jarzynski equalities and Crooks type fluctuation relations, in which corrections decompose into resource resolved contributions. For single systems, we introduce the concept of weight of athermality, and combine it with the weight of coherence to isolate distinct thermodynamic effects of these quantum resources. For bipartite systems, we furthermore obtain two families of entanglement-resolved fluctuation theorems using an appended correlation operator and the best separable approximation, respectively. Finally, we introduce the concepts of coherence and entanglement fluctuation distances, as Kullback Leibler divergences, which quantify the thermodynamic relevance of quantum resources in a process-dependent and operational manner.
Any quantum resource theory is based on free states and free operations, i.e., states and operations which can be created and performed at no cost. In the resource theory of coherence free states are diagonal in some fixed basis, and free operations are those which cannot create coherence for some particular experimental realization. Recently, some problems of this approach have been discussed, and new sets of operations have been proposed to resolve these problems. As an example for such a problem, a quantum operation can be incoherent in one particular experimental realization, but it still can create large amount of coherence in another. This problem is resolved by the framework of genuine quantum coherence. Here, we investigate this concept further and study other more general sets of operations which cannot create coherence in any experimental realization. We analyze in detail the mathematical structure of this class of maps and use this to study possible state transformations under these operations. We show that deterministic manipulation is severely limited, even in the asymptotic settings. In particular, this framework does not have a unique golden unit, i.e., there is no single state from which all other states can be created deterministically with the free operations. On the other hand, we show that these theories allow for a richer structure in what comes to stochastic manipulation of states. In particular, we determine the optimal probability of conversion among pure states with genuinely incoherent operations. Still, the aforementioned limitations suggest that any reasonably powerful resource theory of coherence must contain free operations which can potentially create coherence in some experimental realization.
Abstract Any quantum resource theory is based on free states and free operations, i.e. states and operations which can be created and performed at no cost. In the resource theory of coherence free states are diagonal in some fixed basis, and free operations are those which cannot create coherence for some particular experimental realization. Recently, some problems of this approach have been discussed, and new sets of operations have been proposed to resolve these problems. We propose here the framework of genuine quantum coherence. This approach is based on a simple principle: we demand that a genuinely incoherent operation preserves all incoherent states. This framework captures coherence under additional constrains such as energy preservation and all genuinely incoherent operations are incoherent regardless of their particular experimental realization. We also introduce the full class of operations with this property, which we call fully incoherent. We analyze in detail the mathematical structure of these classes and also study possible state transformations. We show that deterministic manipulation is severely limited, even in the asymptotic settings. In particular, this framework does not have a unique golden unit, i.e. there is no single state from which all other states can be created deterministically with the free operations. This suggests that any reasonably powerful resource theory of coherence must contain free operations which can potentially create coherence in some experimental realization.
Pure-state entanglement transformations have been thought of as irreversible, with reversible transformations generally only possible in the limit of many copies. Here, we show that reversible entanglement transformations do not require processing on the many-copy level but can instead be undertaken on individual systems, provided the amount of entanglement which is produced or consumed is allowed to fluctuate. We derive necessary and sufficient conditions for entanglement manipulations in this case. As a corollary, we derive an equation which quantifies the fluctuations of entanglement, which is formally identical to the Jarzynski fluctuation equality found in thermodynamics. One can also relate a forward entanglement transformation to its reverse process in terms of the entanglement cost of such a transformation, in a manner equivalent to the Crooks relation. We show that a strong converse theorem for entanglement transformations is formally related to the second law of thermodynamics, while the fact that the Schmidt rank of an entangled state cannot increase is related to the third law of thermodynamics. Achievability of the protocols is done by introducing an entanglement battery, a device which stores entanglement and uses an amount of entanglement that is allowed to fluctuate but with an average cost which is still optimal. This allows us to also solve the problem of partial entanglement recovery, and in fact, we show that entanglement is fully recovered. Allowing the amount of consumed entanglement to fluctuate also leads to improved and optimal entanglement dilution protocols.
In Newtonian mechanics, any closed-system dynamics of a composite system in a microstate will leave all its individual subsystems in distinct microstates, however this fails dramatically in quantum mechanics due to the existence of quantum entanglement. Here we introduce the notion of a `coherent work process', and show that it is the direct extension of a work process in classical mechanics into quantum theory. This leads to the notion of `decomposable' and `non-decomposable' quantum coherence and gives a new perspective on recent results in the theory of asymmetry as well as early analysis in the theory of classical random variables. Within the context of recent fluctuation relations, originally framed in terms of quantum channels, we show that coherent work processes play the same role as their classical counterparts, and so provide a simple physical primitive for quantum coherence in such systems. We also introduce a pure state effective potential as a tool with which to analyze the coherent component of these fluctuation relations, and which leads to a notion of temperature-dependent mean coherence, provides connections with multi-partite entanglement, and gives a hierarchy of quantum corrections to the classical Crooks relation in powers of inverse temperature.
This paper presents a comprehensive exposition of quantum thermodynamics, aiming to bridge the foundational concepts of classical thermodynamics and quantum mechanics.Beginning with a rigorous overview of classical thermodynamic laws and statistical ensembles, the work transitions into the quantum domain by introducing quantum states, density operators, and von Neumann entropy.Core thermodynamic quantities such as work, heat, energy, and entropy are redefined in the quantum regime, with emphasis on operational frameworks like the twopoint measurement scheme.The study explores the role of quantum resource theories in formulating generalizations of the second law and delves into the intricacies of nonequilibrium thermodynamics through fluctuation theorems, such as the Jarzynski equality and Crooks theorem.Special attention is given to the influence of coherence, entanglement, and measurement backaction, which contribute uniquely to quantum thermodynamic behavior.The treatise concludes with a discussion on quantum heat engines, thermodynamic consistency of quantum master equations, and information-theoretic approaches, establishing quantum thermodynamics as a vital framework for understanding energy and information flow at the quantum scale.