We improve the Bardeen-Cooper-Schrieffer wave function with a fixed particle number so as to incorporate many-body correlations beyond the mean-field treatment. It is shown that the correlations lower the ground-state energy far more than Cooper-pair condensation in the weak-coupling region. Moreover, they naturally bring a superposition over the number of condensed particles. Thus, Cooper-pair condensation is special among the various bound-state formations of quantum mechanics in that number fluctuations are necessarily present in the condensate through the dynamical exchange of particles with the non-condensate reservoir. On the basis of this result, we propose $\varDelta N_{\rm con}\cdot \varDelta ϕ\gtrsim 1$ as the uncertainty relation relevant to the number-phase fluctuations in superconductors and superfluids, where the number of condensed particles $N_{\rm con}$ is used instead of the total particle number $N$. The formula implies that a macroscopic phase $ϕ$ can be established even in number-fixed superconductors and superfluids since $\varDelta N_{\rm con}\gg 1$.
We improve the Bardeen-Cooper-Schrieffer wave function with a fixed particle number so as to incorporate many-body correlations beyond the mean-field treatment. It is shown that the correlations lower the ground-state energy far more than Cooper-pair condensation in the weak-coupling region. Moreover, they naturally bring a superposition over the number of condensed particles. Thus, Cooper-pair condensation is special among the various bound-state formations of quantum mechanics in that number fluctuations are necessarily present in the condensate through the dynamical exchange of particles with the non-condensate reservoir. On the basis of this result, we propose ΔNcon⋅Δϕ≳1 as the uncertainty relation relevant to the number-phase fluctuations in superconductors and superfluids, where the number of condensed particles Ncon is used instead of the total particle number N. The formula implies that a macroscopic phase ϕ can be established even in number-fixed superconductors and superfluids since ΔNcon≫1.
the interaction.In other words, the correlations lower the ground-state energy relatively far more than Cooper-pair condensation for g ≪ 1.This fact implies that, formally speaking, Cooper-pair condensation should be studied only after the correlations effects have been incorporated.We incorporate the correlation effects to show explicitly that the correlations produce finite non-condensed particles in the ground-state, which work as a particle reservoir for the condensate to naturally yield the superposition, in exactly the same way as in the case of interacting Bose-Einstein condensates.[10] Thus, the superposition is a real physical entity that exists in any isolated superconductor or superfluid.Note in this context that the superposition and coherence have so far been discussed mostly in terms of condensed particles alone.[5,7,11,12] This thesis is organized as follows; We will discuss the improved ground-wave function with many-body correlations.Section 2 presents formulation.Section 3 gives numerical results.Section 4 presents concluding remarks.We also present details that deriving the formalism from Appendix.
Abstract Chapter 13 addresses Bose condensation in superfluids (and superconductors), which involves the field operator ψ having a c-number component (<ψ(x,t)>≠0), challenging number conservation. The nonlinear Gross-Pitaevskii equation is derived for this condensate wave function <ψ>=ψ−ψ˜, facilitating identification of the coherence length and the core region of vortex motion. The noncondensate Green’s function G˜1(1,1′)=−i<(ψ˜(1)ψ˜+(1′))+> and the nonvanishing anomalous correlation function F˜∗(2,1′)=−i<(ψ˜+(2)ψ˜+(1′))+> describe the dynamics and elementary excitations of the non-condensate states and are discussed in conjunction with Landau’s criterion for viscosity. Associated concepts of off-diagonal long-range order and the interpretation of <ψ> as a superfluid order parameter are also introduced. Anderson’s Bose-condensed state, as a phase-coherent wave packet superposition of number states, resolves issues of number conservation. Superconductivity involves bound Cooper pairs of electrons capable of Bose condensation and superfluid behavior. Correspondingly, the two-particle Green’s function has a term involving a product of anomalous bound-Cooper-pair condensate wave functions of the type F(1,2)=−i<(ψ(1)ψ(2))+>≠0, such that G2(1,2;1′,2′)=F(1,2)F+(1′,2′)+G˜2(1,2;1′,2′). Here, G˜2 describes the dynamics/excitations of the non-superfluid-condensate states, while nonvanishing F,F+ represent a phase-coherent wave packet superposition of Cooper-pair number states and off-diagonal long range order. Employing this form of G2 in the G1-equation couples the condensed state with the non-condensate excitations. Taken jointly with the dynamical equation for F(1,2), this leads to the Gorkov equations, encompassing the Bardeen–Cooper–Schrieffer (BCS) energy gap, critical temperature, and Bogoliubov-de Gennes eigenfunction Bogoliubons. Superconductor thermodynamics and critical magnetic field are discussed. For a weak magnetic field, the Gorkov-equations lead to Ginzburg–Landau theory and a nonlinear Schrödinger-like equation for the pair wave function and the associated supercurrent, along with identification of the Cooper pair density. Furthermore, Chapter 13 addresses the apparent lack of gauge invariance of London theory with an elegant variational analysis involving re-gauging the potentials, yielding a manifestly gauge invariant generalization of the London equation. Consistency with the equation of continuity implies the existence of Anderson’s acoustic normal mode, which is supplanted by the plasmon for Coulomb interaction. Type II superconductors and the penetration (and interaction) of quantized magnetic flux lines are also discussed. Finally, Chapter 13 addresses Josephson tunneling between superconductors.
Abstract The superfluid density ns(T) n s ( T ) of a superconductor is calculated based on the generalized Bose–Einstein condensation (GBEC) theory that addresses a fully-interacting ternary boson-fermion gas mixture of free electrons as fermions, plus two-electron Cooper pairs (2eCPs) and also, explicitly, two-hole Cooper pairs (2hCPs), both as bosons. Here we consider two special cases (i) 100%–0% (i.e., with no condensed 2hCPs) and (ii) 0%–100% (i.e., with no condensed 2eCPs). Subsumed in GBEC are the Bardeen–Cooper–Schrieffer (BCS) and Bose–Einstein condensation (BEC) theories along with the BCS-BEC crossover theory extended with 2hCPs. We find that in the weak-coupling regime ns(0) n s ( 0 ) agrees with data from the Uemura et al. (2004) graph for several elemental SCs by taking in 3D with a quadratic energy-dispersion relation while in 2D with a linear relation are much too far below the data. In the strong-coupling regime the linear behavior of critical temperature Tc T c vs ns(0) n s ( 0 ) obtained here is just as Božović et al. (2016) found. However, in 2D with a linear relation accounting for 0%–100%, ns(T)/ns(0) n s ( T ) / n s ( 0 ) compares well with some high- Tc T c -cuprate SC data between the two coupling regimes.
The condensation of Cooper pairs, originating from the Fermi-surface instability due to a weakly attractive interaction between two fermions, opened a new frontier for exploring many-body physics in interdisciplinary contexts. In this work, we discuss the possible condensation of Cooper triples, which are three-body counterparts of Cooper pairs for three-component fermions with a three-body attraction. Although each composite trimer-like state obeys the Fermi-Dirac statistics, its aggregate can form a condensate at zero center-of-mass momentum in the presence of the internal degrees of freedom associated with the relative momenta of constituent particles of momenta close to the Fermi surface. Such condensation can be regarded as bosonization in infinite-component fermions. We propose a variational wave function for the condensate of Cooper triples in analogy with the Bardeen-Cooper-Schrieffer ground state, and we obtain the ground-state energy.
Bosonization of Cooper pairs and novel Bose-liquid superconductivity and superfluidity in high-Tc cuprates and other systems
The criteria for bosonization of Cooper pairs and novel Bose-liquid superconductivity and superfluidity in high-Tc cuprates and other pseudogap matters are formulated by using the uncertainty principle and the boson mean field theory. We argue that the BCS-type s- or d-wave superconductivity occurring in the fermionic limit of Cooper pairs (which exist in ordinary metals and heavily overdoped cuprates with large Fermi energies) is not characteristic of underdoped to overdoped cuprates with low Fermi energies. The superconducting order parameter in high-Tc cuprates and other pseudogap matters cannot be determined as the BCS-like (s- or d-wave) gap. We show that the unconventional superconductivity/superfluidity occurring in the bosonic limit of Cooper pairs exists in low Fermi energy systems where the bosonic Cooper pairs are formed at a pseudogap temperature T* above the uperconducting/superfluid transition temperature Tc and then such bosons condenses into a Bose superfluid at Tc. The pair condensation of attracting bosons occurs at Tc and then their single particle condensation sets in at Tc∗ lower than Tc (in three dimensions (3D)) or at T=0 (in two dimensions (2D)). The coherent single particle and pair condensates of bosons exist as two distinct superfluid phases below Tc. By solving the mean field equations for high-Tc cuprates, the novel superconducting states (i.e., a vortex-like state existing below the temperature Tv=Tc2D lower than T* but higher than Tc=Tc3D and two superconducting phases below Tc) and their properties characterized by the boson superfluid stiffness are determined and compared with the key experimental findings. The novel Bose-liquid superconductivity and superfluidity exists also in other exotic superconductors/superfluids, including quantum liquids, atomic Fermi gases and low-density nuclear matter.