Abstract At the core of every frustrated system, one can identify the existence of frustrated rings that are usually interpreted in terms of single–particle physics. We check this point of view through a careful analysis of the entanglement entropy of both models that admit an exact single–particle decomposition of their Hilbert space due to integrability and those for which the latter is supposed to hold only as a low energy approximation. In particular, we study generic spin chains made by an odd number of sites with short-range antiferromagnetic interactions and periodic boundary conditions, thus characterized by a weak , i.e. nonextensive, frustration. While for distances of the order of the correlation length the phenomenology of these chains is similar to that of the non-frustrated cases, we find that correlation functions involving a number of sites scaling like the system size follow different rules. We quantify the long-range correlations through the von Neumann entanglement entropy, finding that indeed it violates the area law, while not diverging with the system size. This behavior is well fitted by a universal law that we derive from the conjectured single–particle picture.
Abstract At the core of every frustrated system, one can identify the existence of frustrated rings that are usually interpreted in terms of single–particle physics. We check this point of view through a careful analysis of the entanglement entropy of both models that admit an exact single–particle decomposition of their Hilbert space due to integrability and those for which the latter is supposed to hold only as a low energy approximation. In particular, we study generic spin chains made by an odd number of sites with short-range antiferromagnetic interactions and periodic boundary conditions, thus characterized by a weak , i.e. nonextensive, frustration. While for distances of the order of the correlation length the phenomenology of these chains is similar to that of the non-frustrated cases, we find that correlation functions involving a number of sites scaling like the system size follow different rules. We quantify the long-range correlations through the von Neumann entanglement entropy, finding that indeed it violates the area law, while not diverging with the system size. This behavior is well fitted by a universal law that we derive from the conjectured single–particle picture.
Defects in frustrated antiferromagnetic spin chains are universally present in geometrically frustrated systems. We consider the defects of the one-dimensional, spin-s XXZ chain with single-ion anisotropy on a periodic chain with N sites that was famously studied by Haldane. For N odd, the antiferromagnetic model is frustrated, and the ground state must include a soliton defect. We consider the Heisenberg interaction perturbatively and determine the corresponding perturbative solitonic ground state. Then we compute the entanglement spectrum, entanglement entropy (EE), capacity of entanglement (CE), and spin correlations in the solitonic ground state. For weak frustration, we find an algebraic violation of the area law for the EE consistent with recent results on weakly frustrated chains. Our analysis then moves beyond the weak frustration regime, and we obtain a novel extensive scaling law for the EE when strong frustration prevails, signaling large entanglement, and failure of the quasiparticle interpretation in this regime. Enhanced frustration results in less total correlations but relatively more nonlocal correlations.
Frustration in many-body spin systems is a situation where the spins cannot orient themselves to fully minimize the interactions with their neighbors. It is caused, in general, by competing interactions or by the lattice structure, as in the antiferromagnets on non-bipartite lattices. Over the years frustrated systems have been studied substantially, since frustration can destabilize the antiferromagnetic order, lead to different phases of matter and induce various exotic properties. Frustration can be caused also by a choice of boundary conditions, i.e. the lattice topology. For instance, a ring with an odd number of sites is non-bipartite, which makes antiferromagnets in this setting frustrated. The subject of this thesis are zero-temperature one-dimensional quantum systems exactly in this setting. The major content is discussing how such a simple setting can influence the antiferromagnetic order, by studying spin-1/2 chains with discrete symmetries, whose breaking is related to the onset of the order. After reviewing the known results on topological frustration, dealing with non-thermodynamic quantities, we develop an approach for studying symmetry breaking, that is both suitable for exact analytical computations and meaningful for discussing the order also in a finite system. It consists of the realization that many spin-1/2 chains without external magnetic fields, such as the quantum XY chain, possess anticommuting global symmetries when the number of lattice sites is an odd number, implying the ground-state degeneracy already in a finite system. In this framework, we discover that topological frustration, despite being induced only by the choice of boundary conditions and even/odd system size choice, can affect the magnetization in the thermodynamic limit and system's quantum phase transitions. We find that topological frustration can destroy local order, create a site-dependent magnetization that varies in space with an incommensurate pattern, induce a first-order quantum phase transition that is not present without frustration and modify the nature of a second-order transition, by destroying local order at both sides of the transition and preserving only non-local string order parameters. All these results indicate the incompleteness of the approach to quantum many-body systems, based on the Ginzburg-Landau theory, that tries to capture the properties of the system by taking the system size to infinity before computing the observables and neglects the influence of the chain length as a relevant scale. We find that topological frustration can affect also non-equilibrium properties, by considering a local quantum quench setup. Namely, we study the Loschmidt echo and find it displays qualitatively and quantitatively different behavior for antiferromagnetic rings with an even and odd number of sites. Most of all, the differences become clearer for large system sizes, thus allowing to distinguish in a simple out-of-equilibrium experiment a system made by a certain, large, number of spins from the one with a single additional spin. The thesis also contains a mathematical part. In studying order parameters of models mappable to free fermions, Toeplitz determinants with symbols that possess a part proportional to the delta function arise. We derive asymptotic formulas for this type of determinants.
Abstract We consider the effects of the competition between different sources of frustration in 1D spin chains through the analysis of the paradigmatic ANNNI model, which possesses an extensive amount of frustration of local origin due to the competition between nearest and next-to-nearest neighbor interactions. An additional, non-extensive amount of topological frustration can be added by applying suitable boundary conditions and we show that this seemingly subdominant contribution significantly affects the model. Choosing periodic boundary conditions with an even number of sites not divisible by 4 and using the entanglement entropy as a probe, we demonstrate that in one of the model’s phases the ground state can be characterized as hosting two (almost) independent excitations. Thus, not only we show an intriguing interplay between different types of frustration, but also manage to propose a non-trivial quasi-particle interpretation for it.
Abstract A central tenant in the classification of phases is that boundary conditions cannot affect the bulk properties of a system. In this work, we show striking, yet puzzling, evidence of a clear violation of this assumption. We use the prototypical example of an XYZ chain with no external field in a ring geometry with an odd number of sites and both ferromagnetic and antiferromagnetic interactions. In such a setting, even at finite sizes, we are able to calculate directly the spontaneous magnetizations that are traditionally used as order parameters to characterize the system’s phases. When ferromagnetic interactions dominate, we recover magnetizations that in the thermodynamic limit lose any knowledge about the boundary conditions and are in complete agreement with standard expectations. On the contrary, when the system is governed by antiferromagnetic interactions, the magnetizations decay algebraically to zero with the system size and are not staggered, despite the antiferromagnetic coupling. We term this behavior ferromagnetic mesoscopic magnetization . Hence, in the antiferromagnetic regime, our results show an unexpected dependence of a local, one-spin expectation values on the boundary conditions, which is in contrast with predictions from the general theory.
Generic quantum states in the Hilbert space of a many-body system are nearly maximally entangled whereas low-energy physical states are not; the so-called area laws for quantum entanglement are widespread. In this paper we introduce the novel concept of entanglement susceptibility by expanding the 2-Rényi entropy in the boundary couplings. We show how this concept leads to the emergence of area laws for bi-partite quantum entanglement in systems ruled by local gapped Hamiltonians. Entanglement susceptibility also captures quantitatively which violations one should expect when the system becomes gapless. We also discuss an exact series expansion of the 2-Rényi entanglement entropy in terms of connected correlation functions of a boundary term. This is obtained by identifying Rényi entropy with ground state fidelity in a doubled and twisted theory.
The von Neumann entanglement entropy of exact valence-bond ground states is studied in two frustrated one-dimensional spin chains: the spin-1/2 Majumdar-Ghosh (MG) model and the spin-3/2 J1-J2-J3 chain in its fully dimerized (FD) and partially dimerized (PD) phases. Using matrix-product-state representations, the entropy is computed as a function of system size for three complementary bipartitions - half-chain, single-site, and pairwise - under both open and periodic boundary conditions. In all cases, the entropy saturates to a finite constant in the thermodynamic limit, confirming area-law behavior. The saturation values, extracted via finite-size scaling, are directly related to the underlying virtual-spin bond structure. The MG model and FD phase exhibit similar entanglement behavior, differing primarily in saturation magnitude determined by spin value and bond multiplicity, and both display even-odd oscillations and exponential convergence with system size. In contrast, the PD phase shows qualitatively distinct signatures, including multiple half-chain saturation values depending on the bond type at the cut, asymmetric edge contributions in the single-site entropy, and a multi-band structure in the pairwise entropy reflecting the coexistence of single- and double-singlet bonds. These results establish entanglement entropy as a robust signature of frustrated bond architecture, enabling clear distinction among dimerized phases with different spin magnitude, bond multiplicity, and dimerization patterns.