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arXiv:1805.04254 · Physical review. B./Physical review. B

Equilibrium and real-time properties of the spin correlation function in the two-impurity Kondo model

Benedikt Lechtenberg, Frithjof B. Anders

Published Jul 6, 2018• 5 citations
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Abstract

We investigate the equilibrium and real-time properties of the spin-correlation function $\ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle}$ in the two-impurity Kondo model for different distances $R$ between the two-impurity spins. It is shown that the competition between the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction and the Kondo effect governs the amplitude of $\ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle}$. For distances $R$ exceeding the Kondo length scale, the Kondo effect also has a profound effect on the sign of the correlation function. For ferromagnetic Heisenberg couplings $J$ between the impurities and the conduction band, the Kondo effect is absent and the correlation function only decays for distances beyond a certain length scale introduced by finite temperature. The real-time dynamics after a sudden quench of the system reveals that correlations propagate through the conduction band with Fermi velocity. We identify two distinct timescales for the long-time behavior, which reflects that for small $J$ the system is driven by the RKKY interaction while for large $J$ the Kondo effect dominates. Interestingly, we find that at certain distances a one-dimensional dispersion obeying $\ensuremath{\epsilon}(k)=\ensuremath{\epsilon}(\ensuremath{-}k)$ may lead to a local parity conservation of the impurities such that $\ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle}$ becomes a conserved quantity for long times and does not decay to its equilibrium value.

DOI
10.1103/physrevb.98.035109

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We investigate the equilibrium and real-time properties of the spin-correlation function \ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle} in the two-impurity Kondo model for different distances RRR between the two-impurity spins. It is shown that the competition between the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction and the Kondo effect governs the amplitude of \ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle}. For distances RRR exceeding the Kondo length scale, the Kondo effect also has a profound effect on the sign of the correlation function. For ferromagnetic Heisenberg couplings JJJ between the impurities and the conduction band, the Kondo effect is absent and the correlation function only decays for distances beyond a certain length scale introduced by finite temperature. The real-time dynamics after a sudden quench of the system reveals that correlations propagate through the conduction band with Fermi velocity. We identify two distinct timescales for the long-time behavior, which reflects that for small JJJ the system is driven by the RKKY interaction while for large JJJ the Kondo effect dominates. Interestingly, we find that at certain distances a one-dimensional dispersion obeying \ensuremathϵ(k)=\ensuremathϵ(\ensuremath−k)\ensuremath{\epsilon}(k)=\ensuremath{\epsilon}(\ensuremath{-}k)\ensuremathϵ(k)=\ensuremathϵ(\ensuremath−k) may lead to a local parity conservation of the impurities such that \ensuremath{\langle}{\stackrel{P\vec}{S}}_{1}{\stackrel{P\vec}{S}}_{2}\ensuremath{\rangle} becomes a conserved quantity for long times and does not decay to its equilibrium value.
We propose that real-space properties of the two-impurity Kondo model can be obtained from an effective spin model where two single-impurity Kondo spin chains are joined via an Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction between the two impurity spins. We then use a density matrix renormalization group approach, valid in all ranges of parameters, to study its features using two complementary quantum-entanglement measures, the negativity and the von Neumann entropy. This nonperturbative approach enables us to uncover the precise dependence of the spatial extent ξ(K) of the Kondo screening cloud with the Kondo and RKKY couplings. Our results reveal an exponential suppression of the Kondo temperature T(K)~1/ξ(K) with the size of the effective impurity spin in the limit of large ferromagnetic RKKY coupling, a striking display of "Kondo resonance narrowing" in the two-impurity Kondo model. We also show how the antiferromagnetic RKKY interaction produces an effective decoupling of the impurities from the bulk already for intermediate strengths of this interaction, and, furthermore, exhibit how the non-Fermi liquid quantum critical point is signaled in the quantum entanglement between various parts of the system.
In order to study the interplay between Kondo and Ruderman-Kittel-Kasuya-Yosida interaction, we calculate the spin-spin correlation functions between two Kondo impurities coupled to different sites of a half-filled open Hubbard chain. Using the density-matrix renormalization group (DMRG), we reexamine the exponents for the power-law decay of the correlation function between the two impurity spins as a function of the antiferromagnetic coupling JJJ, the Hubbard interaction UUU, and the distance RRR between the impurities. The exponents for finite systems obtained in this work deviate from previously published DMRG calculations. We furthermore show that the long-distance behavior of the exponents is the same for impurities coupled to the bulk or to both ends of the chain. We note that a universal exponent for the asymptotic behavior can not be extracted from these finite-size systems with open boundary conditions.
In order to quantify quantum entanglement in two-impurity Kondo systems, we calculate the concurrence, negativity, and von Neumann entropy. The entanglement of the two Kondo impurities is shown to be determined by two competing many-body effects, namely the Kondo effect and the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction, III. Due to the spin-rotational invariance of the ground state, the concurrence and negativity are uniquely determined by the spin-spin correlation between the impurities. It is found that there exists a critical minimum value of the antiferromagnetic correlation between the impurity spins which is necessary for entanglement of the two impurity spins. The critical value is discussed in relation with the unstable fixed point in the two-impurity Kondo problem. Specifically, at the fixed point there is no entanglement between the impurity spins. Entanglement will only be created [and quantum information processing (QIP) will only be possible] if the RKKY interaction exchange energy, III, is at least several times larger than the Kondo temperature, TK{T}_{K}TK​. Quantitative criteria for QIP are given in terms of the impurity spin-spin correlation.
We study the ground-state entanglement properties of nanostructured Kondo systems consisting of a pair of impurity spins coupled to a background of confined electrons. The competition between the Ruderman-Kittel-Kasuya-Yosida-like coupling and the Kondo effect determines the development of quantum correlations between the different parts of the system. A key element is the electronic filling due to confinement. An even electronic filling leads to results similar to those found previously for extended systems, where the properties of the reduced impurity spin subsystem are uniquely determined by the spin-correlation function defining a one-dimensional phase space. An odd filling, instead, breaks spin rotation symmetry unfolding a two-dimensional phase space showing rich entanglement characteristics as, e.g., the requirement of a larger amount of entanglement for the development of nonlocal correlations between impurity spins. We illustrate these results by numerical simulations of elliptic quantum corrals with magnetic impurities at the foci as a case study.
We address the fundamental question how the spatial Kondo correlations are building up in time assuming an initially decoupled impurity spin ${\stackrel{P\vec}{S}}_{\mathrm{imp}}$. We investigate the time-dependent spin-correlation function $\ensuremath{\chi}(\stackrel{P\vec}{r},t)=\ensuremath{\langle}{\stackrel{P\vec}{S}}_{\mathrm{imp}}\stackrel{P\vec}{s}(\stackrel{P\vec}{r})\ensuremath{\rangle}(t)$ in the Kondo model with antiferromagnetic and ferromagnetic couplings, where $\stackrel{P\vec}{s}(\stackrel{P\vec}{r})$ denotes the spin density of the conduction electrons after switching on the Kondo coupling at time t=0t=0t=0. We present data obtained from a time-dependent numerical renormalisation group (TD-NRG) calculation. We gauge the accuracy of our two-band NRG by the spatial sum rules of the equilibrium correlation functions and the reproduction of the analytically exactly known spin-correlation function of the decoupled Fermi sea. We find a remarkable building up of Kondo correlation outside of the light cone defined by the Fermi velocity of the host metal. By employing a perturbative approach exact in second-order of the Kondo coupling, we connect these surprising correlations to the intrinsic spin-density entanglement of the Fermi sea. The thermal wavelength supplies a cutoff scale at finite temperatures beyond which correlations are exponentially suppressed. We present data for the frequency dependent retarded spin-spin susceptibility and use the results to calculate the real-time response of a weak perturbation in linear response: within the spatial resolution no response outside of the light cone is found.
Competition between the Kondo effect and Ruderman-Kittel-Kasuya-Yosida interaction in the two-impurity Kondo problem can be phenomenologically described by the Rasul-Schlottmann spin model. We revisit this model from the quantum entanglement perspective by calculating both the inter-impurity entanglement and the local Kondo entanglement, the latter being the entanglement between a local magnetic impurity and its spatially nearby conduction electron. A groundstate phase diagram is derived and a discontinuous breakdown of the local Kondo entanglement is found at the singular point, associated concomitantly with a jump in the inter-impurity entanglement. An entanglement monogamy holds in the whole phase diagram. Our results identify the important role of the frustrated cross-coupling and demonstrate the local characteristic of the quantum phase transition in the two-impurity Kondo problem. The implications of these results for Kondo lattices and quantum information processing are also briefly discussed.