We combine the formalisms of Floquet theory and full counting statistics with a Markovian embedding strategy to access the dynamics and thermodynamics of a periodically driven thermal machine beyond the conventional Born–Markov approximation. The working medium is a two-level system and we drive the tunneling as well as the coupling to one bath with the same period. We identify four different operating regimes of our machine which include a heat engine and a refrigerator. As the coupling strength with one bath is increased, the refrigerator regime disappears, the heat engine regime narrows and their efficiency and coefficient of performance decrease. Furthermore, our model can reproduce the setup of laser cooling of trapped ions in a specific parameter limit.
We combine the formalisms of Floquet theory and full counting statistics with a Markovian embedding strategy to access the dynamics and thermodynamics of a periodically driven thermal machine beyond the conventional Born–Markov approximation. The working medium is a two-level system and we drive the tunneling as well as the coupling to one bath with the same period. We identify four different operating regimes of our machine which include a heat engine and a refrigerator. As the coupling strength with one bath is increased, the refrigerator regime disappears, the heat engine regime narrows and their efficiency and coefficient of performance decrease. Furthermore, our model can reproduce the setup of laser cooling of trapped ions in a specific parameter limit.
Time-periodic quantum systems are present all over science and technology. They have been successfully studied using Floquet theory, and a broad diversity of interesting phenomena such as coherent destruction of tunnelling, dynamical localization and creation of new phases of matter have been discovered. Furthermore, periodic driving has also been introduced as a tool for engineering novel quantum systems that have no static analogue. Besides these remarkable achievements for isolated systems, in reality, systems always interact with their surroundings. Taking the effect of the environment into account, time-periodic quantum systems have been mainly described using the Floquet-Markov approach, which consists in deriving a weak coupling master equation in the Floquet basis. In this thesis, we focus on how to overcome these standard approximations in the description of driven open quantum systems. We start by providing a general review on the topics of isolated driven systems, open quantum systems and the Floquet-Markov approach, before presenting the main results of this work. Under the effect of high-frequency driving, we provide an analytic solution to a large class of open quantum systems. Our method relies on discrete symmetries of the system-bath Hamiltonian and grants access to the time evolution operator of the full system, including bath degrees of freedom. The solution can be interpreted as the stroboscopic evolution of a family of observables under the influence of an effective static Hamiltonian. This provides a flexible simulation procedure of nontrivial Hamiltonians. The results are exemplified with the driven spin-boson model, where a coherent control of dissipation is observed. By a novel combination of Floquet theory, full counting statistics and a Markovian embedding strategy (reaction coordinate mapping), more intricate scenarios with additional driven system-environment interactions are addressed. Hereby, we can access the dynamics and thermodynamics of a periodically driven thermal machine. For the particular case where the working medium is a two-level system, we identify four different operating regimes, including a heat engine and a refrigerator. As the coupling strength is increased, their efficiency and coefficient of performance decrease and the refrigerator regime disappears. Notably, our model reproduces the setup of laser cooling of trapped ions in a specific parameter limit. Following the same combination of methods, we investigate electron pumping through a single quantum dot with periodically modulated energy and tunnelling amplitudes. In the high-frequency regime, the direction of the current can be controlled with the driving phase and a rectification effect that is exclusive to the non-Markovian character of the model is observed. In the low-frequency regime, we apply an additional transformation to view the model as three independent transport channels and observe that the coupling strength also controls the current direction. Studying charge fluctuations we validate that our model behaves as a single-electron source.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
Periodically-driven (Floquet) quantum systems are ubiquitous in science and technology. For example, when a laser illuminates a material or an AC voltage is applied to a device, the system is well-described by a time-periodic Hamiltonian. In recent years, periodic driving has been proposed, not just as a tool to excite and probe devices, but actually as a mechanism of engineering new phases of matter, some of which have no equilibrium analog. However, with this promise comes a serious problem. Intuitively, if energy is injected into and distributed throughout a system, it is no surprise that it tends to heat up indefinitely to infinite temperature. In this thesis, we study the mechanisms of heating, i.e. the process of thermalization, in Floquet systems and propose methods to control them. Specifically, for non-interacting Floquet systems that are coupled to external bosonic and fermionic baths (e.g. laser-driven electrons in a semiconductor that interact with phonons and an external lead), we classify the relevant scattering processes that contribute to cooling/heating in the Floquet bands and suggest methods to suppress heating via bandwidth-restrictions on the baths. We find that is possible, with appropriate dissipative engineering, to stabilize a controlled incompressible nonequilibrium steady-state resembling a ground state - a state we term the "Floquet insulator." We extend this analysis to include short-range interactions that contribute additional heating processes and show, under the same framework, that heating can be controlled with dissipation. In the process, we develop a simple effective model for the Floquet band densities that captures the essence of all the Floquet scattering processes and that is useful for ballparking experimentally-relevant estimates of heating. Next, we turn our attention to strongly-interacting closed Floquet systems and study how heating emerges through a proliferation of resonances. We find a novel integrable point governing the strong-interaction limit of the Floquet system and examine the breakdown of integrability via the proliferation of resonances. We observe two distinct scaling regimes, attributed to non-thermal and thermal behavior, and discover a power-law scaling of the crossover between them as a function of system size. The lingering ergodicity-breaking effects of the conserved quantities in the vicinity (in parameter space) of the integrable point at finite size is a phenomena we term "near-integrability." These results suggest that small quantum systems, which are accessible currently in many platforms (e.g. trapped ions, cold atoms, superconducting devices), intrinsically host non-thermal states that one may be able to utilize to avoid heating. Furthermore, our results suggest a "dual" interpretation, in the thermodynamic limit, that a periodically-driven system exhibits prethermalization as a power-law in interaction strength.
We discuss whether, and under which conditions, it is possible to realize a heat engine simply by dynamically modulating the couplings between the quantum working medium and thermal reservoirs. For that purpose, we consider the paradigmatic model of a quantum harmonic oscillator, exposed to a minimal modulation, that is, a monochromatic driving of the coupling to only one of the thermal baths. We demonstrate, at any order in the system/bath coupling strength, that in this setup non-Markovianity of the bath is a necessary condition to obtain a heat engine. In addition, we identify suitable structured environments for the engine to approach the ideal Carnot efficiency. Our results open up new possibilities for the use of non-Markovian open quantum systems for the construction and optimization of quantum thermal machines.
The study of quantum thermodynamics is key to the development of quantum thermal machines. Here we investigate a system of parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and work power of the working device which can operate as an engine or a refrigerator and analyse their instantaneous and averages efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to an accelerator or a heater. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.