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arXiv:1710.10871 · Physical review. E

Stiffness of probability distributions of work and Jarzynski relation for non-Gibbsian initial states

Daniel Schmidtke, Lars Knipschild, Michele Campisi, Robin Steinigeweg, Jochen Gemmer B

Published Jul 19, 2018• 15 citations
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Abstract

We consider closed quantum systems (into which baths may be integrated) that are driven, i.e., subject to time-dependent Hamiltonians. Our point of departure is the assumption that if systems start in non-Gibbsian states at some initial energies, the resulting probability distributions of work may be largely independent of the specific initial energies. It is demonstrated that this assumption has some far-reaching consequences, e.g., it implies the validity of the Jarzynski relation for a large class of non-Gibbsian initial states. By performing numerical analysis on integrable and nonintegrable spin systems, we find the above assumption fulfilled for all examples considered. Through an analysis based on Fermi's golden rule, we partially relate these findings to the applicability of the eigenstate thermalization ansatz to the respective driving operators.

DOI
10.1103/physreve.98.012123

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We consider closed quantum systems (into which baths may be integrated) that are driven, i.e., subject to time-dependent Hamiltonians. Our point of departure is the assumption that if systems start in non-Gibbsian states at some initial energies, the resulting probability distributions of work may be largely independent of the specific initial energies. It is demonstrated that this assumption has some far-reaching consequences, e.g., it implies the validity of the Jarzynski relation for a large class of non-Gibbsian initial states. By performing numerical analysis on integrable and nonintegrable spin systems, we find the above assumption fulfilled for all examples considered. Through an analysis based on Fermi's golden rule, we partially relate these findings to the applicability of the eigenstate thermalization ansatz to the respective driving operators.
We consider closed quantum systems which are driven such that only negligible heating occurs. If driving only affects small parts of the system, it may nonetheless be strong. Our analysis aims at clarifying under which conditions the Jarzynski relation (JR) holds in such setups, if the initial states are microcanonical or even energy eigenstates. We find that the validity of the JR for the microcanonical initial state hinges on an exponential density of states and on stiffness. The latter indicates an independence of the probability density functions (PDFs) of work of the energy of the respective microcanonical initial state. The validity of the JR for initial energy eigenstates is found to additionally require smoothness. The latter indicates an independence of the work PDFs of the specific energy eigenstates within a microcanonical energy shell. As the validity of the JR for pure initial energy eigenstates has no analog in classical systems, we consider it a genuine quantum phenomenon.
Since the first suggestion of the Jarzynski equality many derivations of this equality have been presented in both the classical and the quantum context. While the approaches and settings differ greatly from one another, they all appear to rely on the condition that the initial state is a thermal Gibbs state. Here, we present an investigation of work distributions in driven isolated quantum systems, starting from pure states that are close to energy eigenstates of the initial Hamiltonian. We find that, for the nonintegrable quantum ladder studied, the Jarzynski equality is fulfilled to a good accuracy.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρS(t) approaches an equilibrium state ρ(eq)(S), the latter depending only on macroscopic characteristics of the bath (e.g., temperature) but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present paper we concentrate on one aspect of thermalization, namely, on the system initial state independence (ISI) of ρ(eq)(S). A necessary condition for the system ISI is derived in the quantum framework. We use the derived condition to prove the absence of the system ISI in a specific class of models. Namely, we consider a single spin coupled to a large bath, the interaction term commuting with the bath self-Hamiltonian (but not with the system self-Hamiltonian). Although the model under consideration is nontrivial enough to exhibit the decoherence and the approach to equilibrium, the derived necessary condition is not fulfilled and thus ρ(eq)(S) depends on the initial state of the spin.
We study the validity of the eigenstate thermalization hypothesis (ETH) and its role for the occurrence of initial-state independent (ISI) equilibration in closed quantum many-body systems. Using the concept of dynamical typicality, we present an extensive numerical analysis of energy exchange in integrable and nonintegrable spin-1/2 systems of large size outside the range of exact diagonalization. In the case of nonintegrable systems, our finite-size scaling shows that the ETH becomes valid in the thermodynamic limit and can serve as the underlying mechanism for ISI equilibration. In the case of integrable systems, however, indication of ISI equilibration has been observed despite the violation of the ETH. We establish a connection between this observation and the need of choosing a proper parameter within the ETH.
We study the quantum Jarzynski relation for driven quantum models embedded in various environments. We do so by generalizing a proof presented by Mukamel [Phys. Rev. Lett. 90, 170604 (2003)] for closed quantum systems. In this way, we are able to prove that the Jarzynski relation also holds for a bipartite system with microcanonical coupling. Furthermore, we show that, under the assumption that the interaction energy remains constant during the whole process, the relation is valid even for canonical coupling. The same follows for open quantum systems at high initial temperatures up to third order of the inverse temperature. Our analytical study is complemented by a numerical investigation of a special model system.
We study heating rates in strongly interacting quantum lattice systems in the thermodynamic limit. Using a numerical linked cluster expansion, we calculate the energy as a function of the driving time and find a robust exponential regime. The heating rates are shown to be in excellent agreement with Fermi's golden rule. We discuss the relationship between heating rates and, within the eigenstate thermalization hypothesis, the smooth function that characterizes the off-diagonal matrix elements of the drive operator in the eigenbasis of the static Hamiltonian. We show that such a function, in nonintegrable and (remarkably) integrable Hamiltonians, can be probed experimentally by studying heating rates as functions of the drive frequency.