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arXiv:2007.11829 · Physical review. E

Stiffness of probability distributions of work and Jarzynski relation for initial microcanonical and energy eigenstates

Lars Knipschild, Andreas Engel, Jochen Gemmer B

Published Jun 23, 2021• 5 citations
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Abstract

We consider closed quantum systems which are driven such that only negligible heating occurs. If driving only affects small parts of the system, it may nonetheless be strong. Our analysis aims at clarifying under which conditions the Jarzynski relation (JR) holds in such setups, if the initial states are microcanonical or even energy eigenstates. We find that the validity of the JR for the microcanonical initial state hinges on an exponential density of states and on stiffness. The latter indicates an independence of the probability density functions (PDFs) of work of the energy of the respective microcanonical initial state. The validity of the JR for initial energy eigenstates is found to additionally require smoothness. The latter indicates an independence of the work PDFs of the specific energy eigenstates within a microcanonical energy shell. As the validity of the JR for pure initial energy eigenstates has no analog in classical systems, we consider it a genuine quantum phenomenon.

DOI
10.1103/physreve.103.062139

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We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4].We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4]. An interesting fact is that while the quantum version of the Jarzynski equality remains satisfied even in the presence of quantum correlations, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations [5]. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics.We intend to elucidate the subtle connection between Jarzynski’s relation and the “quantum arrow of time”. Finally we comment on the fact that our scheme for measuring the quantum work characteristic function belongs to the computational class known as DCQ1 [6], namely all computations that can be performed with only one pure qubit (and N maximally mixed ones).

The Rochester Conferences on Coherence and Quantum Optics and the Quantum Information and Measurement meeting•Jan 1, 2013•0 citations
We consider closed quantum systems which are driven such that only negligible heating occurs. If driving only affects small parts of the system, it may nonetheless be strong. Our analysis aims at clarifying under which conditions the Jarzynski relation (JR) holds in such setups, if the initial states are microcanonical or even energy eigenstates. We find that the validity of the JR for the microcanonical initial state hinges on an exponential density of states and on stiffness. The latter indicates an independence of the probability density functions (PDFs) of work of the energy of the respective microcanonical initial state. The validity of the JR for initial energy eigenstates is found to additionally require smoothness. The latter indicates an independence of the work PDFs of the specific energy eigenstates within a microcanonical energy shell. As the validity of the JR for pure initial energy eigenstates has no analog in classical systems, we consider it a genuine quantum phenomenon.
We consider closed quantum systems (into which baths may be integrated) that are driven, i.e., subject to time-dependent Hamiltonians. Our point of departure is the assumption that if systems start in non-Gibbsian states at some initial energies, the resulting probability distributions of work may be largely independent of the specific initial energies. It is demonstrated that this assumption has some far-reaching consequences, e.g., it implies the validity of the Jarzynski relation for a large class of non-Gibbsian initial states. By performing numerical analysis on integrable and nonintegrable spin systems, we find the above assumption fulfilled for all examples considered. Through an analysis based on Fermi's golden rule, we partially relate these findings to the applicability of the eigenstate thermalization ansatz to the respective driving operators.
Since the first suggestion of the Jarzynski equality many derivations of this equality have been presented in both the classical and the quantum context. While the approaches and settings differ greatly from one another, they all appear to rely on the condition that the initial state is a thermal Gibbs state. Here, we present an investigation of work distributions in driven isolated quantum systems, starting from pure states that are close to energy eigenstates of the initial Hamiltonian. We find that, for the nonintegrable quantum ladder studied, the Jarzynski equality is fulfilled to a good accuracy.
Work performed on a system in a microcanonical state by changes in a control parameter is characterized in terms of its statistics. The transition probabilities between eigenstates of the system Hamiltonians at the beginning and the end of the parameter change obey a detailed balance-like relation from which various forms of the microcanonical fluctuation theorem are obtained. As an example, sudden deformations of a two-dimensional harmonic oscillator potential are considered, and the validity of the microcanonical Jarzynski equality connecting the degrees of degeneracy of energy eigenvalues before and after the control parameter change is confirmed.
We study the quantum Jarzynski relation for driven quantum models embedded in various environments. We do so by generalizing a proof presented by Mukamel [Phys. Rev. Lett. 90, 170604 (2003)] for closed quantum systems. In this way, we are able to prove that the Jarzynski relation also holds for a bipartite system with microcanonical coupling. Furthermore, we show that, under the assumption that the interaction energy remains constant during the whole process, the relation is valid even for canonical coupling. The same follows for open quantum systems at high initial temperatures up to third order of the inverse temperature. Our analytical study is complemented by a numerical investigation of a special model system.
Fluctuation theorems are cornerstones of modern statistical mechanics and their standard derivations routinely rely on the crucial assumption of a canonical equilibrium state. Yet rigorous derivations of certain fluctuation theorems for microcanonical states and pure energy eigenstates in isolated quantum systems are still lacking and constitute a major challenge to theory. In this work we tackle this challenge and present such a derivation of an integral fluctuation theorem (IFT) by invoking two central and physically natural conditions, i.e., the so-called "stiffness" and "smoothness" of transition probabilities. Our analytical arguments are additionally substantiated by numerical simulations for archetypal many-body quantum systems, including integrable as well as nonintegrable models of interacting spins and hard-core bosons on a lattice. These simulations strongly suggest that "stiffness" and "smoothness" are indeed of vital importance for the validity of the IFT for microcanonical and pure states. Our work contrasts with recent approaches to the IFT based on Lieb-Robinson speeds and the eigenstate thermalization hypothesis.
We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4].We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4]. An interesting fact is that while the quantum version of the Jarzynski equality remains satisfied even in the presence of quantum correlations, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations [5]. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics.We intend to elucidate the subtle connection between Jarzynski’s relation and the “quantum arrow of time”. Finally we comment on the fact that our scheme for measuring the quantum work characteristic function belongs to the computational class known as DCQ1 [6], namely all computations that can be performed with only one pure qubit (and N maximally mixed ones).