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arXiv:1708.01495 · New Journal of Physics

Verification of the quantum nonequilibrium work relation in the presence of decoherence

Andrew Maven Smith, Yao Lu, Shuoming An, Xiang Zhang, Jing-Ning Zhang, Zongping Gong, H. T. Quan, Christopher Jarzynski, Kihwan Kim

Published Nov 27, 2017• 71 citations
arXivHTMLPDF

Abstract

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult.For systems that undergo decoherence but not dissipation, we argue that it is natural to define quantum work exactly as for isolated quantum systems, using the two-point measurement protocol.Complementing previous theoretical analysis using quantum channels, we show that the nonequilibrium work relation remains valid in this situation, and we test this assertion experimentally using a system engineered from a trapped ion, adding external noise to produce the effects of decoherence.Our experimental results reveal the work relationʼs validity over a variety of driving speeds, decoherence rates, and effective temperatures and represent the first confirmation of the work relation for evolution described by a non-unitary master equation.

DOI
10.1088/1367-2630/aa9cd6

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Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult.For systems that undergo decoherence but not dissipation, we argue that it is natural to define quantum work exactly as for isolated quantum systems, using the two-point measurement protocol.Complementing previous theoretical analysis using quantum channels, we show that the nonequilibrium work relation remains valid in this situation, and we test this assertion experimentally using a system engineered from a trapped ion, adding external noise to produce the effects of decoherence.Our experimental results reveal the work relationʼs validity over a variety of driving speeds, decoherence rates, and effective temperatures and represent the first confirmation of the work relation for evolution described by a non-unitary master equation.
The first part of this thesis focuses on verifying the quantum nonequilibrium work relation in the presence of decoherence. The nonequilibrium work relation is a generalization of the second law of thermodynamics that links nonequilibrium work measurements to equilibrium free energies via an equality. Despite being well established for classical systems, a quantum work relation is conceptually difficult to construct for systems that interact with their environment. We argue that for a quantum system which undergoes decoherence but not dissipation, these conceptual difficulties do not arise and the work relation can be proven similarly to the case of an isolated system. This result is accompanied by an experimental demonstration using trapped ions. The second part of this thesis examines the relationship between quantum work and coherence by constructing analogous quantities in classical physics. It has recently been shown that quantum coherence can function as a resource for work extraction. Furthermore, it has been suggested that this property could be a truly quantum aspect of thermodynamics with no classical analog. We examine this assertion within the framework of classical Hamiltonian mechanics and canonical quantization. For classical states we define a so called non-uniformity measure and show that it is a resource for work extraction similar to quantum coherence. Additionally, we show that work extracted from non-uniformity and coherence agree in the classical limit. This calls into question the idea that coherence qualitatively separates classical and quantum thermodynamics. The final part of this thesis explores the connection between decoherence and adiabatic (quasistatic) driving. This topic is inspired by an experiment where it was seen that strong dephasing suppressed energy level transitions. Using a perturbative method we investigate this mechanism in the regime of small to moderate decoherence rate and ask if decoherence can help suppress energy transitions when compared with an adiabatic process without decoherence. We find that strategies that include decoherence are inferior to those where decoherence is absent.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
Abstract The experimental verification of quantum fluctuation relations for driven open quantum system is currently a challenge, due to the conceptual and operative difficulty of distinguishing work and heat. The nitrogen-vacancy (NV) center in diamond has been recently proposed as a controlled test bed to study fluctuation relations in the presence of an engineered dissipative channel, in absence of work (Hernández-Gómez et al 2020 Phys. Rev. Res. 2 023327). Here, we extend those studies to exploring the validity of quantum fluctuation relations in a driven-dissipative scenario, where the spin exchanges energy both with its surroundings because of a thermal gradient, and with an external work source. We experimentally prove the validity of the quantum fluctuation relations in the presence of cyclic driving in two cases, when the spin exchanges energy with an effective infinite-temperature reservoir, and when the total work vanishes at stroboscopic times—although the power delivered to the NV center is non-null. Our results represent the first experimental study of quantum fluctuation relation in driven open quantum systems.
Rapid progress in the fabrication and manipulation of micro and nanoscale devices has made it necessary to extend the concepts of thermodynamics to small systems and finally to quantum systems. In such systems the extensive thermodynamic quantities, such as entropy, heat, and work, are not described by their average values alone but by distributions. \n \nRemarkably, it has been shown that the stochastic thermodynamic variables often obey fluctuation relations which usually appear in the form of relations between exponential averages. While the two-measurement protocol of thermodynamic variables, especially work, is now well studied in closed quantum systems, there have been conceptual and experimental problems in open quantum systems. \n \nIn this thesis, we theoretically study work statistics and fluctuation relations in open quantum systems. To calculate the work statistics, we use the quantum jump method and direct master equation calculations. We show that work definitions equivalent in closed systems can lead to mutually different results in the case of open quantum systems due to a different order of approximations. Moreover, we show that the fluctuation relations can be extended to nearly adiabatically driven systems by using the adiabatic renormalization procedure. \n \nLast, we focus on how a finite size of the environment affects the dynamics and work statistics of open quantum systems. This is important from the experimental point of view because a finite-size environment allows the detection of heat exchange between the system and the environment. We derive a master equation that takes into account these effects and develop a stochastic model that unravels the master equation. We explicitly show that the finite size of the environment influences the dynamics and the work statistics. We also show that the common fluctuation relations are still valid.
We consider a quantum harmonic oscillator coupled to a general nonequilibrium environment. We show that the decoherence factor can be expressed in terms of a measurable effective temperature, defined via a generalized fluctuation-dissipation relation. We further propose a simple experimental scheme to determine the time-dependent effective temperature in a linear Paul trap with engineered reservoirs. Our formalism allows quantitative description of nonequilibrium decoherence in the presence of an arbitrary number of non-Markovian noise sources in a unified manner.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.