The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles. Furthermore, optimizing the engine over multiple cycles leads to the identification of scenarios with a quantum enhancement. We demonstrate our findings with a quantum Otto engine based on a two-level system as the working substance that supplies power to an external oscillator.
The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles. Furthermore, optimizing the engine over multiple cycles leads to the identification of scenarios with a quantum enhancement. We demonstrate our findings with a quantum Otto engine based on a two-level system as the working substance that supplies power to an external oscillator.
The working substance fueling a quantum heat engine may contain prominent quantum properties such as coherence and nonclassical correlations. In particular, coherence has been somewhat related to quantum friction, whose origin has been mostly associated with the noncommutativity of a driven Hamiltonian at different times. Here, we consider a quantum Otto heat engine operated at finite time and undergoing incomplete thermalization with a heat source. We introduce analytical expressions relating the engine efficiency and extractable power to the coherence measured in the energy basis of the working substance during the engine cycle. We show that coherence, which has been related to an increase in entropy production and irreversibility, can in also be employed to improve the quantum engine performance, mitigating quantum friction. Such an improvement may be achieved by carefully tuning cycle parameters. To illustrate this coherent improvement we performed a numerical analysis in an experimentally feasible example.
This study presents a comparative analysis of three quantum thermal engines utilizing a two-qubit Heisenberg XXZ chain as the working substance. A novel generalized quantum Otto cycle (GQOC) is introduced, featuring two distinct coupling configurations to thermal reservoirs. The GQOC exhibits the potential for 100% efficiency, surpassing the efficiency of the conventional quantum Otto cycle. Essential conditions for positive work extraction and achieving maximum unity efficiency are derived. An experimental implementation using quantum electrodynamic circuits and Transmon qudit is proposed. This work contributes to the advancement of quantum heat engines, highlighting the benefits of nonequilibrium processes and asymmetric coupling for enhanced work extraction and efficiency.
To optimize the performance of a heat engine in a finite-time cycle, it is important to understand the finite-time effect of thermodynamic processes. Previously, we have shown that extra work is needed to complete a quantum adiabatic process in finite time, and proved that the extra work follows a C/τ^{2} scaling for long control time τ. There the oscillating part of the extra work is neglected due to the complex energy-level structure of the particular quantum system. However, such oscillation of the extra work cannot be neglected in some quantum systems with simple energy-level structure, e.g., the two-level system or the quantum harmonic oscillator. In this paper, we build the finite-time quantum Otto engine on these simple systems, and find that the oscillating extra work leads to a jagged edge in the constraint relation between the output power and the efficiency. By optimizing the control time of the adiabatic processes, the oscillation in the extra work is utilized to enhance the maximum power and the efficiency. We further design special control schemes with the zero extra work at the specific control time. Compared to the linear control scheme, these special control schemes of the finite-time adiabatic process improve the maximum power and the efficiency of the finite-time Otto engine.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance.
In this work we study the effect of quantum and thermal fluctuations on the statistics of quantum heat engine performance parameters, like efficiency and power. We begin by deriving an explicit solution for the characteristic function of the heat distribution of a thermal quantum harmonic oscillator. We then derive a general framework based on the standard two-point-measurement scheme to compute the efficiency distribution of a quantum Otto cycle. We analyze the generic properties of this distribution for scale-invariant driving Hamiltonians which describe a large class of single-particle, many-body, and nonlinear systems. We find that the efficiency is deterministic and that its mean is equal to the macroscopic efficiency for adiabatic driving. We continue our research by studying the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follow the ’universal’ theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We can relate this unusual property to the perfect anticorrelation between work output and heat input that suppresses thermal as well as quantum fluctuations. We then probe our findings in an experimental NMR setup using spin-1/2 systems and find them to agree rather well with our theoretical predictions. Afterward, we move on to the finite-time quantum Carnot cycle and investigate its power fluctuations. In particular, we consider how level degeneracy and level number, two commonly found properties in quantum systems, influence the relative work fluctuations. We find that their optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results highlight that these parameters can be employed to realize high-performance, high-stability cyclic quantum heat engines.
In this paper, we analyze the total work extracted and the efficiency of the magnetic Otto cycle in its classic and quantum versions. As a general result, we found that the work and efficiency of the classical engine is always greater than or equal to its quantum counterpart, independent of the working substance. In the classical case, this is due to the fact that the working substance is always in thermodynamic equilibrium at each point of the cycle, maximizing the energy extracted in the adiabatic paths. We apply this analysis to the case of a two-level system, finding that the work and efficiency in both the Otto's quantum and classical cycles are identical, regardless of the working substance, and we obtain similar results for a multilevel system where a linear relationship between the spectrum of energies of the working substance and the external magnetic field is fulfilled. Finally, we show an example of a three-level system in which we compare two zones in the entropy diagram as a function of temperature and magnetic field to find which is the most efficient region when performing a thermodynamic cycle. This work provides a practical way to look for temperature and magnetic field zones in the entropy diagram that can maximize the power extracted from an Otto magnetic engine.