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arXiv:1611.01483 · Physical Review A

Refined weak-coupling limit: Coherence, entanglement, and non-Markovianity

́Angel Rivas

Published Apr 6, 2017• 50 citations
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Abstract

We study the properties of a refined weak-coupling limit that preserves complete positivity in order to describe non-Markovian dynamics in the spin-boson model. With this tool, we show the system presents a rich non-Markovian phenomenology. This implies a dynamical difference between entanglement and coherence: the latter undergoes revivals, whereas the former not, despite the induced dynamics being fully incoherent. In addition, the evolution presents ``quasieternal'' non-Markovianity, becoming nondivisible at any time period where the system evolves qualitatively. Furthermore, the method allows for an exact derivation of a master equation that accounts for a reversible energy exchange between system and environment. Specifically, this is obtained in the form of a time-dependent Lamb shift term.

DOI
10.1103/physreva.95.042104

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We study the properties of a refined weak-coupling limit that preserves complete positivity in order to describe non-Markovian dynamics in the spin-boson model. With this tool, we show the system presents a rich non-Markovian phenomenology. This implies a dynamical difference between entanglement and coherence: the latter undergoes revivals, whereas the former not, despite the induced dynamics being fully incoherent. In addition, the evolution presents ``quasieternal'' non-Markovianity, becoming nondivisible at any time period where the system evolves qualitatively. Furthermore, the method allows for an exact derivation of a master equation that accounts for a reversible energy exchange between system and environment. Specifically, this is obtained in the form of a time-dependent Lamb shift term.
In recent years, there has been tremendous focus on identifying whether effective descriptions of open quantum systems such as master equations can accurately describe the dynamics of open quantum systems. One particular question is whether they provide the correct steady state in the long time limit. The transient regime is also of interest. Description of evolution by various master equations---some of them being not completely positive---is benchmarked against exact solutions [see, e.g., R. Hartmann and W. T. Strunz, Phys. Rev. A 101, 012103 (2020)]. An important property of true evolution is its non-Markovian features, which are not captured by the simplest completely positive master equations. In this paper we consider a non-Markovian yet completely positive evolution (known as refined weak coupling or cumulant equation) for the spin-boson model with an overdamped Drude-Lorentz spectral density and arbitrary coupling. We benchmark it against a numerically exact solution, as well as against other master equations, for different coupling strengths and temperatures. We find the cumulant to be a better description in the weak-coupling regime where it is supposed to be valid. For the examples considered it shows superiority at moderate and strong couplings in the low-temperature regime for all examples considered. In the high-temperature regime, however, its advantage vanishes. This indicates that the cumulant equation is a good candidate for simulations at weak to moderate coupling and low temperature. Our calculations are greatly facilitated due to our concise formulation of the cumulant equation by means of representation of the density matrix in the SU(N) basis.
The famous Davies-GKSL secular Markovian master equation is tremendously successful in approximating the evolution of open quantum systems in terms of just a few parameters. However, the fully secular Davies-GKSL equation fails to accurately describe timescales short enough, i.e., comparable to the inverse of differences of frequencies present in the system of interest. A complementary approach that works well for short times but is not suitable after this short interval is known as the quasisecular master equation. Still, both approaches fail to have any faithful dynamics in the intermediate-time interval. Simultaneously, descriptions of dynamics that apply to the aforementioned "gray zone" often are computationally much more complex than master equations or are mathematically not well-structured. The filtered approximation (FA) to the refined weak-coupling limit has the simplistic spirit of the Davies-GKSL equation and allows capturing the dynamics in the intermediate-time regime. At the same time, our non-Markovian equation yields completely positive dynamics. We exemplify the performance of the FA equation in the cases of the spin-boson system and qutrit-boson system in which two distant timescales appear.
We study the decoherence properties of an entangled bipartite qubit system, represented by two two-level atoms that are individually coupled to non-Markovian reservoirs. This coupling ensures that the dynamical equations of the atoms can be treated independently. The non-Markovian reservoirs are described by a model which leads to an exact non-Markovian master equation of the Nakajima-Zwanzig form [J. Salo, S. M. Barnett, and S. Stenholm, Optics Commun. 259, 772 (2006)]. We consider the evolution of the entanglement of a two-atom state that is initially completely entangled, quantified by its concurrence. Collapses and revivals in the concurrence, induced by the memory effects of the reservoir, govern the dynamics of the entangled quantum system. These collapses and revivals in the concurrence are a strong manifestation of the non-Markovian reservoir.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..
Understanding the behavior of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process of decoherence and the so-called quantum measurement problem. There have been many approaches to explore Markovian and non-Markovian dynamics within the framework of open quantum systems, but the richness of the ensuing dynamics is still not fully understood. In this paper we develop a non-Markovian extension of the standard Caldeira-Leggett model, based on expanding the dynamics of the reduced system at high temperature in inverse powers of the high-frequency cutoff of the Ohmic spectral density of the environment and derive a non-Markovian master equation for the reduced density matrix for the case of a general potential. We also obtain a fully analytical solution in the free particle case. While the short-time behavior of this solution does not diverge substantially from the Markovian behavior, at intermediate times we find a resurgence of coherence, which we name lateral coherence. We identify this with a corresponding transient negative entropy production rate, which is understood to be characteristic of non-Markovian dynamics. We also analyze the positivity of the reduced density matrix and derive the corresponding Fokker-Planck equation in the classical limit.
The spin-boson model, describing a two-level system coupled to a bosonic bath, is extensively studied as a paradigmatic dissipative quantum system, exhibiting rich dynamical behavior and even a localization transition in the strong coupling regime. Here, we additionally consider dephasing as a source of Markovian dissipation on top of the non-Markovian dynamics due to an Ohmic bath, and investigate the dynamics of the spin. We show that the characteristic frequency of the spin dynamics, while strongly renormalized by the bosonic bath, changes in a simple fashion (or does not change at all) with dephasing. To obtain these results, we develop an exact nonperturbative method known as the stochastic Schr\"odinger equation, mimicking the Ohmic bath via a stochastic magnetic field combined with the Lindblad quantum master equation due to dephasing, which allows us to numerically compute the dynamics. Furthermore, we derive weak-coupling analytic results utilizing the well-known noninteracting blip approximation. Our findings are relevant to quantum simulation of the spin-boson model in the regime of strong coupling in trapped ions and circuit QED architectures among others.