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arXiv:1907.05874 · Physical Review A

Master equation for non-Markovian quantum Brownian motion: The emergence of lateral coherences

Sapphire Lally, Nicholas Werren, Jim Al-Khalili, Andrea Rocco

Published Jan 18, 2022• 6 citations
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Abstract

Understanding the behavior of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process of decoherence and the so-called quantum measurement problem. There have been many approaches to explore Markovian and non-Markovian dynamics within the framework of open quantum systems, but the richness of the ensuing dynamics is still not fully understood. In this paper we develop a non-Markovian extension of the standard Caldeira-Leggett model, based on expanding the dynamics of the reduced system at high temperature in inverse powers of the high-frequency cutoff of the Ohmic spectral density of the environment and derive a non-Markovian master equation for the reduced density matrix for the case of a general potential. We also obtain a fully analytical solution in the free particle case. While the short-time behavior of this solution does not diverge substantially from the Markovian behavior, at intermediate times we find a resurgence of coherence, which we name lateral coherence. We identify this with a corresponding transient negative entropy production rate, which is understood to be characteristic of non-Markovian dynamics. We also analyze the positivity of the reduced density matrix and derive the corresponding Fokker-Planck equation in the classical limit.

DOI
10.1103/physreva.105.012209

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Understanding the behavior of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process of decoherence and the so-called quantum measurement problem. There have been many approaches to explore Markovian and non-Markovian dynamics within the framework of open quantum systems, but the richness of the ensuing dynamics is still not fully understood. In this paper we develop a non-Markovian extension of the standard Caldeira-Leggett model, based on expanding the dynamics of the reduced system at high temperature in inverse powers of the high-frequency cutoff of the Ohmic spectral density of the environment and derive a non-Markovian master equation for the reduced density matrix for the case of a general potential. We also obtain a fully analytical solution in the free particle case. While the short-time behavior of this solution does not diverge substantially from the Markovian behavior, at intermediate times we find a resurgence of coherence, which we name lateral coherence. We identify this with a corresponding transient negative entropy production rate, which is understood to be characteristic of non-Markovian dynamics. We also analyze the positivity of the reduced density matrix and derive the corresponding Fokker-Planck equation in the classical limit.
We develop a non-Markovian extension to the caldeira-leggett master equation for quantum Brownian motion by using the timescale of the bath as a small parameter around which to perform a perturbative expansion. This framework allows us to deal directly with the time non-locality of the non-Markovian regime. We derive an exact description of the evolution of the reduced density matrix and obtain a new quantum master equa- tion with non-Markovian corrections added perturbatively to the standard Lindblad form. The resulting simulations show new dynamics and a strong deviation from Markovian behaviour. We observe that quantum coherences survive far longer than in the Marko- vian limit. In particular, when the system is fully non-Markovian, quantum phenomena experience a form of decoherence that behaves functionally like an inverse-power law. These results may have important implications in quantum technologies and biology as they suggest environments can be engineered to support long-lived quantum coherence.
We revisit the Caldeira-Leggett model of quantum Brownian motion with Ohmic spectral density, and derive an additional contribution to the decoherence kernel in a new high-temperature limit at arbitrarily large cutoff frequency. This contribution reveals a novel mechanism for the classicalization of high-frequency quantum fluctuations. We further demonstrate that it leads to a Markovian master equation that is in guaranteed Lindblad form, and argue that this master equation describes the correct Markovian limit of quantum Brownian motion. Our approach considers in detail the behavior of the decoherence kernel at both the initial and final times of the process on the timescale of the bath memory.
Caldeira and Leggett (CL) in a seminal paper derived a master equation describing Markovian Quantum Brownian motion. Such an equation suffered of not being completely positive, and many efforts have been made to solve this issue. We show that, when a careful mathematical analysis is performed, the model considered by CL leads to a non dissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of Quantum Brownian motion one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
We study quantum non-Markovian dynamics of the Caldeira-Leggett model, a prototypical model for quantum Brownian motion describing a harmonic oscillator linearly coupled to a reservoir of harmonic oscillators. Employing the exact analytical solution of this model one can determine the size of memory effects for arbitrary couplings, temperatures, and frequency cutoffs. Here, quantum non-Markovianity is defined in terms of the flow of information between the open system and its environment, which is quantified through the Bures metric as distance measure for quantum states. This approach allows us to discuss quantum memory effects in the whole range from weak to strong dissipation for arbitrary Gaussian initial states. A comparison of our results with the corresponding results for the spin-boson problem show a remarkable similarity in the structure of non-Markovian behavior of the two paradigmatic models.
Caldeira and Leggett (CL), in a seminal paper, derived a master equation describing Markovian quantum Brownian motion. Such an equation suffered from not being completely positive, and many efforts have been made to solve this issue. We show that when a careful mathematical analysis is performed, the model considered by CL leads to a nondissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of quantum Brownian motion with the CL model, one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.