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arXiv:1701.05024 · Physical Review A

Dissipation in the Caldeira-Leggett model

Luca Ferialdi

Published May 11, 2017• 36 citations
arXivHTMLPDF

Abstract

Caldeira and Leggett (CL), in a seminal paper, derived a master equation describing Markovian quantum Brownian motion. Such an equation suffered from not being completely positive, and many efforts have been made to solve this issue. We show that when a careful mathematical analysis is performed, the model considered by CL leads to a nondissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of quantum Brownian motion with the CL model, one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.

DOI
10.1103/physreva.95.052109

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Caldeira and Leggett (CL), in a seminal paper, derived a master equation describing Markovian quantum Brownian motion. Such an equation suffered from not being completely positive, and many efforts have been made to solve this issue. We show that when a careful mathematical analysis is performed, the model considered by CL leads to a nondissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of quantum Brownian motion with the CL model, one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.
Caldeira and Leggett (CL) in a seminal paper derived a master equation describing Markovian Quantum Brownian motion. Such an equation suffered of not being completely positive, and many efforts have been made to solve this issue. We show that, when a careful mathematical analysis is performed, the model considered by CL leads to a non dissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of Quantum Brownian motion one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.
We develop a non-Markovian extension to the caldeira-leggett master equation for quantum Brownian motion by using the timescale of the bath as a small parameter around which to perform a perturbative expansion. This framework allows us to deal directly with the time non-locality of the non-Markovian regime. We derive an exact description of the evolution of the reduced density matrix and obtain a new quantum master equa- tion with non-Markovian corrections added perturbatively to the standard Lindblad form. The resulting simulations show new dynamics and a strong deviation from Markovian behaviour. We observe that quantum coherences survive far longer than in the Marko- vian limit. In particular, when the system is fully non-Markovian, quantum phenomena experience a form of decoherence that behaves functionally like an inverse-power law. These results may have important implications in quantum technologies and biology as they suggest environments can be engineered to support long-lived quantum coherence.
This article presents a brief account of Amir O. Caldeira's contributions to the theory of quantum Brownian motion. Motivated by its importance, we outline the description of Brownian motion in the quantum regime following Caldeira's first works. In this context, we particularly highlight the effect of dissipation on the tunneling rate out of a metastable state. We then journey along the alternative ways to approach quantum Brownian motion developed by Caldeira during his career, which go beyond the so-called Caldeira-Leggett model. We conclude by summarizing some of Caldeira's contributions to contemporary fields such as the theory of quantum decoherence and quantum thermodynamics, that were strongly inspired by his eponymous approach to quantum Brownian motion.
Understanding the behavior of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process of decoherence and the so-called quantum measurement problem. There have been many approaches to explore Markovian and non-Markovian dynamics within the framework of open quantum systems, but the richness of the ensuing dynamics is still not fully understood. In this paper we develop a non-Markovian extension of the standard Caldeira-Leggett model, based on expanding the dynamics of the reduced system at high temperature in inverse powers of the high-frequency cutoff of the Ohmic spectral density of the environment and derive a non-Markovian master equation for the reduced density matrix for the case of a general potential. We also obtain a fully analytical solution in the free particle case. While the short-time behavior of this solution does not diverge substantially from the Markovian behavior, at intermediate times we find a resurgence of coherence, which we name lateral coherence. We identify this with a corresponding transient negative entropy production rate, which is understood to be characteristic of non-Markovian dynamics. We also analyze the positivity of the reduced density matrix and derive the corresponding Fokker-Planck equation in the classical limit.
Non-Markovian master equations describe general open quantum systems when no approximation is made. We provide the exact closed master equation for the class of Gaussian, completely positive, trace preserving, non-Markovian dynamics. This very general result allows us to investigate a vast variety of physical systems. We show that the master equation for non-Markovian quantum Brownian motion is a particular case of our general result. Furthermore, we derive the master equation unraveled by a non-Markovian, dissipative stochastic Schrödinger equation, paving the way for the analysis of dissipative non-Markovian collapse models.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.