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arXiv:1610.05100 · Archives of Metallurgy and Materials

Modified Bohm’s theory for abstruse measurements: application to layer depth profiling using auger spectroscopy

E. Rówiński, Mariusz Pietruszka

Published Mar 14, 2019• 1 citation
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Abstract

Modified Bohm’s formalism was applied to solve the problem of abstruse layer depth profiles measured by the Auger electron spectroscopy technique in real physical systems. The desorbed carbon/passive layer on an NiTi substrate and the adsorbed oxygen/ surface of an NiTi alloy were studied. It was shown that the abstruse layer profiles can be converted to real layer structures using the modified Bohm’s theory, where the quantum potential is due to the Auger electron effect. It is also pointed out that the stationary probability density predicts the multilayer structures of the abstruse depth profiles that are caused by the carbon desorption and oxygen adsorption processes. The criterion for a kind of break or “cut” between the physical and unphysical multilayer systems was found. We conclude with the statement that the physics can also be characterised by the abstruse measurement and modified Bohm’s formalism.

DOI
10.24425/amm.2019.126234

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Modified Bohm’s formalism was applied to solve the problem of abstruse layer depth profiles measured by the Auger electron spectroscopy technique in real physical systems. The desorbed carbon/passive layer on an NiTi substrate and the adsorbed oxygen/ surface of an NiTi alloy were studied. It was shown that the abstruse layer profiles can be converted to real layer structures using the modified Bohm’s theory, where the quantum potential is due to the Auger electron effect. It is also pointed out that the stationary probability density predicts the multilayer structures of the abstruse depth profiles that are caused by the carbon desorption and oxygen adsorption processes. The criterion for a kind of break or “cut” between the physical and unphysical multilayer systems was found. We conclude with the statement that the physics can also be characterised by the abstruse measurement and modified Bohm’s formalism.
The usual interpretation of the quantum theory is self-consistent, but it involves an assumption that cannot be tested experimentally, viz., that the most complete possible specification of an individual system is in terms of a wave function that determines only probable results of actual measurement processes. The term ‘ontological interpretation’ is sometimes applied to Bohm’s approach, as he set out to tackle the ontological problems of conventional quantum theory. However, the ontological interpretations are strikingly different. In the many worlds view, the differing branches are simultaneously and equally real, whereas Bohm’s inactive channels remain as unmanifested potentialities, with steadily declining likelihoods as more and more irreversible process (like measurement) pile up along the manifest branch. Bohm’s theory serves to illuminate some of the more interesting aspects of quantum theory (its contextuality and nonlocal nature) and demonstrates what is at stake from an ontological point of view.
We analyse the track of an α-particle passing through a cloud chamber using the Bohm theory and show that the resulting classical track has its origins in the quantum Zeno effect. By assuming the ionised gas molecules reveal the positions of the α-particle on its trajectory and using these positions in a short time propagator technique developed by de Gosson, we show it is the failure of the quantum potential to develop quickly enough that leads to the appearance of the classical trajectory. Bohm and Hiley have already argued that it is this failure of the quantum potential to develop appropriately that prevents an Auger electron from undergoing a transition if continuously watched. This allows us to conclude that, in general, it is the suppression of the quantum potential that accounts for the quantum Zeno effect.
A tenet of time-resolved spectroscopy is "faster laser pulses for shorter timescales". Here, we suggest turning this paradigm around, and slowing down the system dynamics via repeated measurements, to do spectroscopy on longer timescales. This is the principle of the quantum Zeno effect. We exemplify our approach with the Auger process, and find that repeated measurements increase the core-hole lifetime, redistribute the kinetic energy of Auger electrons, and alter entanglement formation. We further provide an explicit experimental protocol for atomic Li, to make our proposal concrete.
We discuss a formal and physical connection between the Bohm quantum potential and the scalar mode of the Aharonov-Bohm extension of electrodynamics. The analysis is motivated by the effective non-relativistic bosonic model recently proposed by Minotti and Modanese, in which the electromagnetic field is coupled to a conserved current while the field equations contain an additional source term. In the Madelung representation ψ=Rexp⁡(iθ/ℏ)ψ=R\exp(iθ/\hbar)ψ=Rexp(iθ/ℏ), the Bohm quantum potential $ Q_B=-\frac{\hbar^2}{2m}\frac{\nabla^2 R}{R} $ is determined by the relative curvature ∇2R/R\nabla^2R/R∇2R/R of the amplitude profile RRR. In the same bosonic model, the scalar electromagnetic mode S=∂μAμS=\partial_μA^μS=∂μ​Aμ is sourced by the extra-current I=∂μjμI=\partial_μj^μI=∂μ​jμ, which contains the density-weighted electromagnetic combination ∇⋅(R2A)\nabla\cdot(R^2\mathbf A)∇⋅(R2A). Thus QBQ_BQB​ does not act as a direct source of SSS; rather, the two quantities probe different differential aspects of the same amplitude profile: QBQ_BQB​ is sensitive to the relative curvature of RRR, whereas the source of SSS is sensitive to its density and gradient content through R2R^2R2 and ∇R\nabla R∇R. We show that, once boundary and normalization data are fixed, this observation may be written as a mediated functional dependence of SSS on QBQ_BQB​ through RRR. We also clarify the physical status of QBQ_BQB​: although it is state-dependent and should not be interpreted as an autonomous external potential, its density-weighted integral gives the amplitude-gradient energy, equivalently a Fisher-information contribution. This makes QBQ_BQB​ a compact diagnostic of quantum pressure, rigidity, and inhomogeneity of a bosonic condensate. The resulting link with SSS is therefore best understood as a structural relation between the order-parameter amplitude profile of the condensate and the scalar sector of the extended electromagnetic theory.
In this work the Auger electron spectroscopy (AES) sputter depth profiling technique for binary solids has been discussed and exemplified by its application to reveal composition profiles generated in Ni(0.7)Mo(0.3) by pre-bombardment with Ar(+)-ions of 1 through 5 keV. Two element-specific. surface-sensitive Auger transitions are employed to monitor the surface composition. The Linear correlation between the Auger intensities provides the relative sensitivity factor for the quantification of AES data. A model proposed by Ho and co-workers is reformulated for the conversion of the measured temporal variation of surface concentration C(s)(t) into the original composition profile C(x). Radiation-enhanced diffusion caused by high-energy ion bombardment turns sputter depth profiling into an underdetermined inverse problem. On the other hand, experiments show that the strong preferential sputtering effect accompanying low-energy sputter may veil the detail of the composition profiles. An intermediate energy between about 100 and 300 eV is found to be optimum for the purpose of sputter depth profiling. (C) 2000 published by Elsevier Science B.V. All rights reserved.