While analyzing second order thermodynamical phase transitions, Lev Landau (the famous Russian physicist) introduced a very vital concept, the concept of an "order parameter". This not only amalgamated the previous fragmentary theoretical understanding of phase transitions (an arsenal of mean-field theories) but also it put forward the important theory of "spontaneous symmetry breaking". Today, order parameter concept is a paradigm both in condensed matter physics and in high energy physics, and Landau theory is a pinnacle of all mean-field theories. Mean field theories are good qualitative descriptors of the phase transition behavior. But all mean-field theories (including Landau's theory) fail at the critical point (the problem of large correlation length). The problems with large correlation length in quantum many-body systems are the hardest problems known in theoretical physics (both in condensed matter and in particle physics). It was Ken Wilson's physical insights and his powerful mathematical skills that opened a way to the solution of such hard problems. This manuscript is a perspective on these issues. Starting with simple examples of phase transitions (like ice/water; diamond/graphite etc.) we address the following important questions: Why does non-analyticity (sharp phase transitions) arise when thermodynamical functions (i.e., free energies etc) are good analytic functions? How does Landau's program unify all the previous mean-field theories? Why do all the mean-field theories fail near the critical point? How does Wilson's program go beyond all the mean-field theories? What is the origin emergence and universality?
While analyzing second order thermodynamical phase transitions, Lev Landau (the famous Russian physicist) introduced a very vital concept, the concept of an "order parameter". This not only amalgamated the previous fragmentary theoretical understanding of phase transitions (an arsenal of mean-field theories) but also it put forward the important theory of "spontaneous symmetry breaking". Today, order parameter concept is a paradigm both in condensed matter physics and in high energy physics, and Landau theory is a pinnacle of all mean-field theories. Mean field theories are good qualitative descriptors of the phase transition behavior. But all mean-field theories (including Landau's theory) fail at the critical point (the problem of large correlation length). The problems with large correlation length in quantum many-body systems are the hardest problems known in theoretical physics (both in condensed matter and in particle physics). It was Ken Wilson's physical insights and his powerful mathematical skills that opened a way to the solution of such hard problems. This manuscript is a perspective on these issues. Starting with simple examples of phase transitions (like ice/water; diamond/graphite etc.) we address the following important questions: Why does non-analyticity (sharp phase transitions) arise when thermodynamical functions (i.e., free energies etc) are good analytic functions? How does Landau's program unify all the previous mean-field theories? Why do all the mean-field theories fail near the critical point? How does Wilson's program go beyond all the mean-field theories? What is the origin emergence and universality?
This chapter addresses the fundamental role of order parameters and symmetry breaking in characterizing phases and understanding phase transitions and argues that the origin of non-analyticity is in fact the thermodynamic limit. It explores the Landau definition that a transition is first order if the order parameter is discontinuous at the transition point and second order if it is continuous. The chapter presents a general theory which in leading approximation embodies the physics of the Landau function of the order parameter. The mean field theory may be applied quite generally to any system for which the local order parameter has been identified. Once the order parameter for Bose condensation is recognized, the order parameter for superconducting or superfluid transitions follow naturally. For superconducting metals, pairs of electrons at the Fermi surface form bound states which behave effectively as Bosons and thus undergo Bose condensation.
The renormalization method is specifically aimed at connecting theories describing physical processes at different length scales and thereby connecting different theories in the physical sciences. The renormalization method used today is the outgrowth of one hundred and fifty years of scientific study of thermal physics and phase transitions. Different phases of matter show qualitatively different behavior separated by abrupt phase transitions. These qualitative differences seem to be present in experimentally observed condensed-matter systems. However, the "extended singularity theorem" in statistical mechanics shows that sharp changes can only occur in infinitely large systems. Abrupt changes from one phase to another are signaled by fluctuations that show correlation over infinitely long distances, and are measured by correlation functions that show algebraic decay as well as various kinds of singularities and infinities in thermodynamic derivatives and in measured system parameters. Renormalization methods were first developed in field theory to get around difficulties caused by apparent divergences at both small and large scales. The renormalization (semi-)group theory of phase transitions was put together by Kenneth G. Wilson in 1971 based upon ideas of scaling and universality developed earlier in the context of phase transitions and of couplings dependent upon spatial scale coming from field theory. Correlations among regions with fluctuations in their order underlie renormalization ideas. Wilson's theory is the first approach to phase transitions to agree with the extended singularity theorem. Some of the history of the study of these correlations and singularities is recounted, along with the history of renormalization and related concepts of scaling and universality. Applications are summarized.
This book provides an elementary introduction to the notions of continuum limit and universality in statistical systems with a large number of degrees of freedom. The existence of a continuum limit requires the appearance of correlations at large distance, a situation that is encountered in second order phase transitions, near the critical temperature. In this context, the book emphasizes the role of gaussian distributions and their relations with the mean field approximation and Landau′s theory of critical phenomena. The book shows that quasi-gaussian or mean-field approximations cannot describe correctly phase transitions in three space dimensions. The book assigns this difficulty to the coupling of very different physical length scales, even though the systems we will consider have only local, that is, short range, interactions. To analyze the unusual situation, a new concept is required: the renormalization group, whose fixed points allow understanding the universality of physical properties at large distance, beyond mean-field theory. In the continuum limit, critical phenomena can be described by quantum field theories. In this framework, the renormalization group is directly related to the renormalization process; that is, the necessity to cancel the infinities that arise in straightforward formulations of the theory. The book discusses the renormalization group in the context of various relevant field theories. This leads to proofs of universality and to efficient tools for calculating universal quantities in a perturbative framework. Finally, the book constructs a general functional renormalization group, which can be used when perturbative methods are inadequate.
To set the stage for our subsequent thorough discussion of dynamic critical phenomena, we first review the theoretical description of second-order equilibrium phase transitions. (Readers already well acquainted with this material may readily move on to Chapter 2.) To this end, we compare the critical exponents following from the van-der-Waals equation of state for weakly interacting gases with the results from the Curie–Weiss mean-field approximation for the ferromagnetic Ising model. We then provide a unifying description in terms of Landau–Ginzburg theory, i.e., a long-wavelength expansion of the effective free energy with respect to the order parameter. The Gaussian model is analyzed, and a quantitative criterion is established that defines the circumstances when non-linear fluctuations need to be taken into account properly. Thereby we identify d c = 4 as the upper critical dimension for generic continuous phase transitions in thermal equilibrium. The most characteristic feature of a critical point turns out to be the divergence of the correlation length that renders microscopic details oblivious. As a consequence, not only the correlation functions, but remarkably the thermodynamics as well of a critical system are governed by an emergent unusual symmetry: scale invariance. A simple scaling ansatz is capable of linking different critical exponents; as an application, we introduce the basic elements of finite-size scaling. Finally, a brief sketch of Wilson's momentum shell renormalization group method is presented, intended as a pedagogical preview of the fundamental RG ideas. Exploiting the scale invariance properties at the critical point, the scaling forms of the free energy and the order parameter correlation function are derived.
In the previous chapters, we discussed mean-field approaches such as the Curie–Weiss and Bragg–Williams theories, which provide a microscopic justification for macroscopic order parameters and spontaneous symmetry breaking. However, these approaches were based on specific microscopic Hamiltonians. Lev Davidovich Landau introduced a far more general and elegant framework: one that does not depend on microscopic details but on symmetry principles and analyticity of the free energy near the transition.
These lectures describe the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, these general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Then the Landau theory of phase transitions is presented. The form of free energy in the Landau theory is motivated by an explicit mean field calculation for the Ising model. This is followed by a discussion of spatial correlations and the breakdown of the mean field theory due to increase of spatial fluctuations near the critical point. This calculation also brings out the role of dimension of the system for the critical behaviour. The basic ideas of Renormalization Group (RG) are then introduced and illustrated by a simple RG calculation for the one-dimensional Ising model. Real-space RG calculations are then applied to the two-dimensional Ising model on the triangular lattice, which, in fact, brings forth several key features of the RG technique. A discussion of more general aspects of the RG formalism, such as scaling for spatial correlation functions, relevant and irrelevant couplings, universality, upper critical dimension, etc. are introduced.