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arXiv:1308.0078 · Physical Review Letters

Controlling Magnetic Feshbach Resonances in Polar Open-Shell Molecules with Nonresonant Light

Michał Tomza, Rosario González‐Férez, Christiane P. Koch, Robert Moszyński

Published Mar 20, 2014• 30 citations
arXivHTMLPDF

Abstract

Magnetically tunable Feshbach resonances for polar paramagnetic ground-state diatomics are too narrow to allow for magnetoassociation starting from trapped, ultracold atoms. We show that nonresonant light can be used to engineer the Feshbach resonances in their position and width. For nonresonant field intensities of the order of 10(9) W/cm(2), we find the width to be increased by 3 orders of magnitude, reaching a few Gauss. This opens the way for producing ultracold molecules with sizable electric and magnetic dipole moments and thus for many-body quantum simulations with such particles.

DOI
10.1103/physrevlett.112.113201

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We investigate the possibility of forming Li+Yb ultracold molecules by magnetoassociation in mixtures of ultracold atoms. We find that magnetically tunable Feshbach resonances exist, but are extremely narrow for even-mass ytterbium isotopes, which all have zero spin. For odd-mass Yb isotopes, however, there is a new mechanism due to hyperfine coupling between the electron spin and the Yb nuclear magnetic moment. This mechanism produces Feshbach resonances for fermionic Yb isotopes that can be more than 2 orders of magnitude larger than for the bosonic counterparts.
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We explore the feasibility of producing ultracold diatomic molecules with nonzero electric and magnetic dipole moments by magnetically associating two atoms, one with zero electron spin and one with nonzero spin. Feshbach resonances arise through the dependence of the hyperfine coupling on internuclear distance. We survey the Feshbach resonances in diatomic systems combining the nine stable alkali-metal isotopes with those of Yb, focusing on the illustrative examples of RbYb and CsYb. We show that the resonance widths may expressed as a product of physically comprehensible terms in the framework of Fermi's golden rule. The resonance widths depend strongly on the background scattering length, which may be adjusted by selecting the Yb isotope, and on the hyperfine coupling constant and the magnetic field. In favorable cases the resonances may be over 100 mG wide.