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arXiv:1306.6040 · Journal of Statistical Mechanics Theory and Experiment

Thermodynamics of quantum spin chains with competing interactions

T S Tavares, G A P Ribeiro

Published Sep 13, 2013• 7 citations
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Abstract

We consider integrable quantum spin chains with competing interactions. We apply the quantum transfer matrix approach to these spin chains. This allows us to derive a set of nonlinear integral equations for the thermodynamics of these spin chains. We provide numerical solutions of these integral equations for the entropy as a function of magnetic field, temperature and the coupling constant. In addition we describe, at low but finite temperature, the possible scenarios for the ground state diagram for high-spin chain and longer range interchain interactions.

DOI
10.1088/1742-5468/2013/09/p09007

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We consider integrable quantum spin chains with competing interactions. We apply the quantum transfer matrix approach to these spin chains. This allows us to derive a set of nonlinear integral equations for the thermodynamics of these spin chains. We provide numerical solutions of these integral equations for the entropy as a function of magnetic field, temperature and the coupling constant. In addition we describe, at low but finite temperature, the possible scenarios for the ground state diagram for high-spin chain and longer range interchain interactions.
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The thermodynamics of coupled frustrated ferromagnetic chains is studied within a spin-rotation-invariant Green's-function approach. We consider an isotropic Heisenberg spin-half system with a ferromagnetic in-chain coupling J1<0{J}_{1}<0J1​<0 between nearest neighbors and a frustrating antiferromagnetic next-nearest-neighbor in-chain coupling J2>0{J}_{2}>0J2​>0. We focus on the moderate strength of frustration J2<∣J1∣/4{J}_{2}<|{J}_{1}|/4J2​<∣J1​∣/4 such that the in-chain spin-spin correlations are predominantly ferromagnetic. We consider two interchain couplings (ICs) ${J}_{\ensuremath{\perp},y}$ and ${J}_{\ensuremath{\perp},z}$, corresponding to the two axes perpendicular to the chain, where ferromagnetic as well as antiferromagnetic ICs are taken into account. We discuss the influence of frustration on the ground-state properties for antiferromagnetic ICs, where the ground state is of a quantum nature. The major part of our study is devoted to the finite-temperature properties. We calculate the critical temperature Tc{T}_{c}Tc​ as a function of the competing exchange couplings ${J}_{2},{J}_{\ensuremath{\perp},y},{J}_{\ensuremath{\perp},z}$. We find that for fixed ICs, Tc{T}_{c}Tc​ decreases monotonically with increasing frustration J2{J}_{2}J2​, where as ${J}_{2}\ensuremath{\rightarrow}|{J}_{1}|/4$ the Tc(J2){T}_{c}({J}_{2})Tc​(J2​) curve drops down rapidly. To characterize the magnetic ordering below and above Tc{T}_{c}Tc​, we calculate the spin-spin correlation functions $\ensuremath{\langle}{\mathbf{S}}_{0}{\mathbf{S}}_{\mathbf{R}}\ensuremath{\rangle}$, the magnetic order parameter MMM, the uniform static susceptibility ${\ensuremath{\chi}}_{0}$, as well as the correlation length $\ensuremath{\xi}$. Moreover, we discuss the specific heat CV{C}_{V}CV​ and the temperature dependence of the excitation spectrum ${\ensuremath{\omega}}_{\mathbf{q}}$. As ${J}_{2}\ensuremath{\rightarrow}|{J}_{1}|/4$, some unusual frustration-induced features were found, such as an increase of the in-chain spin stiffness (in the case of ferromagnetic ICs) or of the in-chain spin-wave velocity (in the case of antiferromagnetic ICs) with growing temperature.