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arXiv:1103.2908 · Physical Review A

Isotope shift and hyperfine splitting of the 4s→5p transition in potassium

Alexandra Behrle, Marco Koschorreck, Michael Köhl

Published May 18, 2011• 12 citations
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Abstract

We have investigated the $4s {}^{2}{S}_{1/2}\ensuremath{\rightarrow}5p {}^{2}{P}_{1/2}$ transition (${D}_{1}$ line) of the potassium isotopes $^{39}\mathrm{K}$, $^{40}\mathrm{K}$, and $^{41}\mathrm{K}$ using Doppler-free laser saturation spectroscopy. Our measurements reveal the hyperfine splitting of the $5p {}^{2}{P}_{1/2}$ state of $^{40}\mathrm{K}$, and we have determined the specific mass shift and the nuclear field shift constants for the blue (405 nm) ${D}_{1}$ line.

DOI
10.1103/physreva.83.052507

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We have investigated the 4s2S1/2\ensuremath→5p2P1/24s {}^{2}{S}_{1/2}\ensuremath{\rightarrow}5p {}^{2}{P}_{1/2}4s2S1/2​\ensuremath→5p2P1/2​ transition (D1{D}_{1}D1​ line) of the potassium isotopes 39K^{39}\mathrm{K}39K, 40K^{40}\mathrm{K}40K, and 41K^{41}\mathrm{K}41K using Doppler-free laser saturation spectroscopy. Our measurements reveal the hyperfine splitting of the 5p2P1/25p {}^{2}{P}_{1/2}5p2P1/2​ state of 40K^{40}\mathrm{K}40K, and we have determined the specific mass shift and the nuclear field shift constants for the blue (405 nm) D1{D}_{1}D1​ line.
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Spectroscopy of the 411-nm transition in 171Yb+{}^{171}{\mathrm{Yb}}^{+}171Yb+ has been performed and the feasibility of its use as an optical frequency standard has been demonstrated. The 2S1/2(F=0,mF=0)−−2D5/2(F=2,mF=0){}^{2}{S}_{1/2}(F=0, {m}_{F}=0){--}^{2}{D}_{5/2}(F=2, {m}_{F}=0)2S1/2​(F=0,mF​=0)−−2D5/2​(F=2,mF​=0) frequency, at zero-magnetic field, has been measured to be 729 487 779 566(153) kHz. This transition is free from the first-order Zeeman shift and has a measured second-order shift of +0.38(8) Hz/(\ensuremath{\mu}T)2{\mathrm{T})}^{2}T)2. In addition, the hyperfine structure of the 2D5/2{}^{2}{D}_{5/2}2D5/2​ level has been deduced by driving the other hyperfine components of the 411-nm transition, showing it to be inverted. The 2D5/2{}^{2}{D}_{5/2}2D5/2​ hyperfine splitting, measured to be -191(2) MHz, implies an A factor of -63.6(7) MHz. These data taken in conjunction with previous work yield an isotope shift of ${\ensuremath{\nu}}_{171}\ensuremath{-}{\ensuremath{\nu}}_{172}=+1317.1(1.3)\mathrm{MHz}$ for this transition between the 171 and 172 isotopes.