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arXiv:1003.0756

X-probability and Irreversibility Paradox

Vladimir A. Skrebnev

Published Mar 3, 2010• 0 citations
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Abstract

Based on the general thought that mechanics cannot be absolutely exact, supported by pulsed nuclear magnetic resonance (NMR) experiments on the reversal of time in spin systems, we postulate existence of a probability which do not follow from the Schroudinger equation, or X-probability. It is shown that the X-probability allows explain irreversibility of evolution of macrosystems, and also creates a basis for using probabilistic methods in statistical mechanics and for deliverance from the mechanical determinism.

DOI
10.48550/arxiv.1003.0756

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Based on the general thought that mechanics cannot be absolutely exact, supported by pulsed nuclear magnetic resonance (NMR) experiments on the reversal of time in spin systems, we postulate existence of a probability which do not follow from the Schroudinger equation, or X-probability. It is shown that the X-probability allows explain irreversibility of evolution of macrosystems, and also creates a basis for using probabilistic methods in statistical mechanics and for deliverance from the mechanical determinism.
The problem of reconciling the irreversibility of thermodynamics with the completely reversible mechanics of the ultimate constituents of the thermodynamical system is examined from an operational viewpoint. The informational nature of entropy is demonstrated, and the famous paradoxes of statistical mechanics, due to Loschmidt and Zermelo, are resolved with its aid. Spin echo experiments are shown to realize the conditions of Loschmidt's reflection paradox, and used to illustrate how reversibility occurs only with perfect “memory” or information storage, while “forgetting” or loss of information implies irreversibility.
An experimental study of the applicability of mechanics equations to describing the process of equilibrium establishing in an isolated spin system was performed. The time-reversion effects were used at the experiments. It was demonstrated, that the equations of mechanics do not describe the spin macrosystem transition to the equilibrium. The experimental results correspond to the theory which is based on the non-equilibrium thermodynamics methods and takes into account the quick decay of cross-correlations in the systems.
Characteristic features of the probabilistic models used in classical mechanics, statistical physics, and quantum theory are discussed. The viewpoint according to which there is no room for probabilities in Nature, as such, is consistently substantiated; the researcher is forced to introduce probabilistic concepts and the corresponding models in conditions that provide only partial predictability of the phenomena being studied. This approach allows one to achieve a consistent interpretation of some important physical phenomena, in particular, the relationship between instability and irreversibility in time, the stochastic evolution of systems in the theory of deterministic chaos, Boltzmann’s H -theorem, and paradoxes of quantum mechanics.
Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this arrow of time is associated with a positive mean entropy production. Using a nuclear magnetic resonance setup, we measure the nonequilibrium entropy produced in an isolated spin-1/2 system following fast quenches of an external magnetic field. We experimentally demonstrate that it is equal to the entropic distance, expressed by the Kullback-Leibler divergence, between a microscopic process and its time reversal. Our result addresses the concept of irreversibility from a microscopic quantum standpoint.
Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the latter is understood as primarily concerned with the derivation of quantitative higher-level equations of motion, and only derivatively with underpinning the equilibrium concept in thermodynamics. I argue that at least in this wide class of examples, (i) irreversibility is introduced through a reasonably well-defined initial-state condition which does not precisely map onto those in the extant philosophical literature; (ii) probability is explicitly required both in the foundations and in the predictions of the theory. I then consider the same examples, as well as the more general context, in the light of quantum mechanics, and demonstrate that while the analysis of irreversibility is largely unaffected by quantum considerations, the notion of statistical-mechanical probability is entirely reduced to quantum-mechanical probability.