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arXiv:0803.2439 · Physical Review Letters

Joule Expansion of a Pure Many-Body State

S. Camalet

Published May 5, 2008• 9 citations
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Abstract

We derive the Joule expansion of an isolated perfect gas from the principles of quantum mechanics. Contrary to most studies of irreversible processes which consider composite systems, the interesting and ignored degrees of freedom are here described by operators acting in the same many-body Hilbert space. Moreover, the expansion of the gas into the entire accessible volume is obtained for pure states. Still, the number particle density is characterized by a chemical potential and a temperature. We discuss the special case of a boson gas below the Bose condensation temperature.

DOI
10.1103/physrevlett.100.180401

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We derive the Joule expansion of an isolated perfect gas from the principles of quantum mechanics. Contrary to most studies of irreversible processes which consider composite systems, the interesting and ignored degrees of freedom are here described by operators acting in the same many-body Hilbert space. Moreover, the expansion of the gas into the entire accessible volume is obtained for pure states. Still, the number particle density is characterized by a chemical potential and a temperature. We discuss the special case of a boson gas below the Bose condensation temperature.
The low-density expansions for the energy, chemical potential, and condensate depletion of the homogeneous dilute dipolar Bose gas are obtained by regularizing the dipole-dipole interaction at long distances. It is shown that the leading term, proportional to the density, allows a simple physical interpretation and consistently describes the thermodynamic stability of the system. The long-range asymptotics are obtained analytically for the normal and anomalous one-particle correlation functions and the pair distribution function. We discuss the properties of the two-body scattering with zero relative momentum for the dipole-dipole interaction; in particular, we derive the asymptotics of the wave function and a correction to the scattering length for small values of the dipolar range. We show how the density expansions can be derived within the Bogoliubov model of weakly interacting particles without any divergence from the assumption of universality of the expansions at low densities.
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We investigate the Joule expansion of an interacting quantum gas in an energy eigenstate. The Joule expansion occurs when two subsystems of different particle density are allowed to exchange particles. We demonstrate numerically that the subsystems in their energy eigenstates evolves unitarily into the global equilibrium state in accordance with the eigenstate thermalization hypothesis. We find that the quantum gas changes its temperature after the Joule expansion with a characteristic inversion temperature T_{I}. The gas cools down (heats up) when the initial temperature is higher (lower) than T_{I}, implying that T_{I} is a stable fixed point, which is contrasted to the behavior of classical gases. Our work exemplifies that transport phenomena can be studied at the level of energy eigenstates.
The issue of the thermalization of an isolated quantum system is addressed by considering a perfect gas confined by gravity and initially trapped above a certain height. As we are interested in the behavior of truly isolated systems, we assume the gas is in a pure state of macroscopically well-defined energy. We show that, in general, for single-particle distributions, such a state is strictly equivalent to the microcanonical mixed state at the same energy. We derive an expression for the time-dependent gas density that depends on the initial gas state only via a few thermodynamic parameters. Though we consider noninteracting particles, the density relaxes into an asymptotic profile, but it is not the thermal equilibrium one determined by the gas energy and particle number.
This Letter provides the missing part of the newly constructed many-body formalism for composite quantum particles: the introduction of a finite temperature. The finite T formalism we propose deeply relies on the existence of a compact closure relation for the (overcomplete) set of N-composite-particle states. As a first application, we here calculate the energy mean value of the exciton gas outside the condensation regime. We show that carrier exchanges increase its temperature dependence compared to elementary bosons, a signature of the degree-of-freedom increase resulting from the particle composite nature.