In this research, we develop a many-body Green's function approach for interacting composite bosons in the Bose–Einstein condensed phase. The resummation scheme dealing with the carrier–carrier exchange between many-body composite bosons in cold condensation is manifested as a diagrammatic technique through the introduction of a set of Dyson equations for composite bosons. We diagrammatically calculate the specific heat capacity of neutral composite bosons, made of mass-imbalanced fermions with opposite charges, up to the first orders of the Pauli exchange and Coulomb interaction. Condensate phenomena due to the effect of the carrier–carrier exchange are discussed. In comparison with the approximation that composite bosons behave like interacting fundamental bosons, our result shows that the energy reduction from the carrier–carrier exchange stabilizes composite-boson condensates.
We present a canonical ensemble approach for weakly interacting composite boson systems, which is confined with a finite number of particles. Composite bosons, made of fermion pairs, correlate to each other through the Coulomb interaction associated with the fermion exchange, and are treated perturbatively. We study Bose–Einstein condensation of composite bosons according to the specific heat capacity, the composite-boson distribution function, and the condensate fraction up to the first-order perturbations. As an example, we investigate two-dimensional confined excitons. The study shows that the fermion exchange tends to assist the exciton condensation by raising the temperature. This stabilization of the exciton condensation owing to the fermion exchange is characterized by a small trough in the specific heat capacity profile. As the temperature becomes higher than the transition temperature, the effective Coulomb interaction reduces the thermal fluctuation of excitons, leading to a negative correction to the specific heat capacity in the normal phase. Weakly interacting excitons stay in a more stable thermodynamic state in comparison with ideal exciton gases.
Chapter 16 introduces the last part that addresses the bosonic condensation of composite bosons. To bridge the gap between elementary bosons and composite bosons, elementary fermion systems like semiconductor electrons and holes are also studied. Whereas the previous chapters provided a fairly precise knowledge of bosonic particles relevant for condensed matter physics, namely, Wannier excitons, Frenkel excitons, Cooper pairs, biexcitons, and polaritons, this chapter addresses an important question of current interest: what is the ground state of N composite bosons from the perspective of Bose-Einstein condensation? Or rather, how does the genuine Bose-Einstein condensation for elementary bosons persist in composite boson systems? This chapter lists important results with respect to condensate momentum fragmentation or spin fragmentation, correlation energy, and the dark nature of exciton condensate, to emphasize the connection between elementary bosons, elementary fermions, elementary fermion pairs, and composite bosons, from the composite boson perspective of their condensation.
Chapter 19 addresses bosonic condensation in composite bosons. It first considers the coboson ground-state energy, which is analytically known by now in the case of N Cooper pairs interacting via the reduced BCS potential but not yet known for N Wannier or Frenkel excitons, owing to the complexity of the Coulomb potential. Still, the chapter provides hints on how to derive the density linear term of the N-exciton ground-state energy in the case of Wannier excitons. It also discusses the role of the exciton composite nature in condensate momentum fragmentation, spin fragmentation, and condensate brightness. Indeed, the excitons that have the lowest energy and thus are the ones expected to condense are not coupled to light; so, the exciton condensate must be dark. However, a bright exciton condensate can appear, coherent with the dark exciton condensate, above a density threshold, owing to coupling induced by carrier exchange between dark excitons and bright excitons.
This paper shows the necessity of introducing a quantum object, the ``coboson,'' to properly describe, through a fermion scheme, any composite particle, such as the exciton, which is made of two fermions. Although commonly dealt with as elementary bosons, these composite bosons---cobosons in short---differ from them due to their composite nature which makes the handling of their many-body effects quite different from the existing treatments valid for elementary bosons. As a direct consequence of this composite nature, there is no correct way to describe the interaction between cobosons as a potential
V. This is rather dramatic because, with the Hamiltonian not written as
H=H0+V, all the usual approaches to many-body effects fail. In particular, the standard form of the Fermi golden rule, written in terms of
V, cannot be used to obtain the transition rates of two cobosons. To get them, we have had to construct an unconventional expression for this Fermi golden rule in which
H only appears. Making use of this expression, we give here a detailed calculation of the time evolution of two excitons. We compare the results of this exact approach with the ones obtained by using an effective bosonic Hamiltonian in which the excitons are considered as elementary bosons with effective scatterings between them, these scatterings resulting from an elaborate mapping between the two-fermion space and the ideal boson space. We show that the relation between the inverse lifetime and the sum of the transition rates for elementary bosons differs from the one of the composite bosons by a factor of
1∕2, so that it is impossible to find effective scatterings between bosonic excitons giving these two physical quantities correctly, whatever the mapping from composite bosons to elementary bosons is. The present paper thus constitutes a strong mathematical proof that, in spite of a widely spread belief, we cannot forget the composite nature of these cobosons, even in the extremely low-density limit of just two excitons. This paper also shows the (unexpected) cancellation in the Born approximation of the two-exciton transition rate for a finite value of the momentum transfer.