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arXiv:1811.10051 · Physical review. E

Heating and cooling of quantum gas by eigenstate Joule expansion

Jae Dong Noh, Eiki Iyoda, Takahiro Sagawa

Published Jul 31, 2019• 7 citations
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Abstract

We investigate the Joule expansion of an interacting quantum gas in an energy eigenstate. The Joule expansion occurs when two subsystems of different particle density are allowed to exchange particles. We demonstrate numerically that the subsystems in their energy eigenstates evolves unitarily into the global equilibrium state in accordance with the eigenstate thermalization hypothesis. We find that the quantum gas changes its temperature after the Joule expansion with a characteristic inversion temperature T_{I}. The gas cools down (heats up) when the initial temperature is higher (lower) than T_{I}, implying that T_{I} is a stable fixed point, which is contrasted to the behavior of classical gases. Our work exemplifies that transport phenomena can be studied at the level of energy eigenstates.

DOI
10.1103/physreve.100.010106

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We investigate the Joule expansion of an interacting quantum gas in an energy eigenstate. The Joule expansion occurs when two subsystems of different particle density are allowed to exchange particles. We demonstrate numerically that the subsystems in their energy eigenstates evolves unitarily into the global equilibrium state in accordance with the eigenstate thermalization hypothesis. We find that the quantum gas changes its temperature after the Joule expansion with a characteristic inversion temperature T_{I}. The gas cools down (heats up) when the initial temperature is higher (lower) than T_{I}, implying that T_{I} is a stable fixed point, which is contrasted to the behavior of classical gases. Our work exemplifies that transport phenomena can be studied at the level of energy eigenstates.
We investigate the Joule expansion of nonintegrable quantum systems that contain bosons or spinless fermions in one-dimensional lattices. A barrier initially confines the particles to be in half of the system in a thermal state described by the canonical ensemble and is removed at time t=0t=0t=0. We investigate the properties of the time-evolved density matrix, the diagonal ensemble density matrix, and the corresponding canonical ensemble density matrix with an effective temperature determined by the total energy conservation using exact diagonalization. The weights for the diagonal ensemble and the canonical ensemble match well for high initial temperatures that correspond to negative effective final temperatures after the expansion. At long times after the barrier is removed, the time-evolved R\'enyi entropy of subsystems bigger than half can equilibrate to the thermal entropy with exponentially small fluctuations. The time-evolved reduced density matrix at long times can be approximated by a thermal density matrix for small subsystems. Few-body observables, like the momentum distribution function, can be approximated by a thermal expectation of the canonical ensemble with strongly suppressed fluctuations. The negative effective temperatures for finite systems go to non-negative temperatures in the thermodynamic limit for bosons, but there is a true thermodynamic effect for fermions, which is confirmed by finite-temperature density matrix renormalization group calculations. We propose the Joule expansion as a way to dynamically create negative temperature states for fermion systems with repulsive interactions.
We report the first observation of the quantum Joule-Thomson (JT) effect in ideal and unitary Fermi gases. We study the temperature dynamics of these systems while they undergo an energy-per-particle conserving rarefaction. For scale-invariant systems, whose equations of state satisfy the relation U∝PV, this rarefaction conserves the specific enthalpy, which makes it thermodynamically equivalent to a JT throttling process. We observe JT heating in an ideal Fermi gas, a direct consequence of Pauli blocking. In a unitary Fermi gas, we observe that the JT heating is marginal in the temperature range 0.2≲T/T_{F}≲0.8 as the repulsive quantum-statistical effect is lessened by the attractive interparticle interactions.
How does an isolated quantum system evolve toward thermal equilibrium from a far-from-equilibrium initial state-for instance, one prepared by a global quantum quench? This question has attracted significant interest in recent years. The Eigenstate Thermalization Hypothesis (ETH) provides a compelling framework for addressing it, with far-reaching implications from high-energy physics to condensed matter. This primer offers a pedagogical introduction to quantum equilibrium and ETH for a broad physics audience, particularly high-energy physicists seeking a comprehensive understanding of these topics. We assume only basic knowledge of quantum mechanics and statistical mechanics.
Understanding how out-of-equilibrium states thermalize under quantum unitary dynamics is an important problem in many-body physics. In this work, we propose a statistical Ansatz for the matrix elements of non-equilibrium initial states in the energy eigenbasis, in order to describe such evolution. The approach is inspired by the Eigenstate Thermalisation Hypothesis (ETH) but the proposed Ansatz exhibits different scaling. Importantly, we point out the exponentially small cross-correlations between the observable and the initial state matrix elements that determine relaxation dynamics toward equilibrium. We numerically verify scaling and cross-correlation, point out the emergent universality of the high-frequency behavior, and outline possible generalizations.
We derive the Joule expansion of an isolated perfect gas from the principles of quantum mechanics. Contrary to most studies of irreversible processes which consider composite systems, the interesting and ignored degrees of freedom are here described by operators acting in the same many-body Hilbert space. Moreover, the expansion of the gas into the entire accessible volume is obtained for pure states. Still, the number particle density is characterized by a chemical potential and a temperature. We discuss the special case of a boson gas below the Bose condensation temperature.