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arXiv:0705.3278 · Physical Review A

Thermal symmetry of the Markovian master equation

Buang Ann Tay, Tomio Yamakoshi Petrosky

Published Oct 2, 2007• 15 citations
arXivHTMLPDF

Abstract

The quantum Markovian master equation of the reduced dynamics of a harmonic oscillator coupled to a thermal reservoir is shown to possess thermal symmetry. This symmetry is revealed by a Bogoliubov transformation that can be represented by a hyperbolic rotation acting on the Liouville space of the reduced dynamics. The Liouville space is obtained as an extension of the Hilbert space through the introduction of tilde variables used in the thermofield dynamics formalism. The angle of rotation depends on the temperature of the reservoir, as well as the value of Planck's constant. This symmetry relates the thermal states of the system at any two temperatures. This includes absolute zero, at which purely quantum effects are revealed. The Caldeira-Leggett equation and the classical Fokker-Planck equation also possess thermal symmetry. We compare the thermal symmetry obtained from the Bogoliubov transformation in related fields and discuss the effects of the symmetry on the shape of a Gaussian wave packet.

DOI
10.1103/physreva.76.042102

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The quantum Markovian master equation of the reduced dynamics of a harmonic oscillator coupled to a thermal reservoir is shown to possess thermal symmetry. This symmetry is revealed by a Bogoliubov transformation that can be represented by a hyperbolic rotation acting on the Liouville space of the reduced dynamics. The Liouville space is obtained as an extension of the Hilbert space through the introduction of tilde variables used in the thermofield dynamics formalism. The angle of rotation depends on the temperature of the reservoir, as well as the value of Planck's constant. This symmetry relates the thermal states of the system at any two temperatures. This includes absolute zero, at which purely quantum effects are revealed. The Caldeira-Leggett equation and the classical Fokker-Planck equation also possess thermal symmetry. We compare the thermal symmetry obtained from the Bogoliubov transformation in related fields and discuss the effects of the symmetry on the shape of a Gaussian wave packet.
The theory of Brownian motion of a quantum oscillator is developed. The Brownian motion is described by a model Hamiltonian which is taken to be the one describing the interaction between this oscillator and a reservoir. Use is made of the master equation recently derived by the author, to obtain the equation of motion for the various reduced phase-space distribution functions that are obtained by mapping the density operator onto ccc-number functions. The equations of motion for the reduced phase-space distribution functions are found to be of the Fokker-Planck type. On transforming the Fokker-Planck equation to real variables, it is found to have the same form as the Fokker-Planck equation obtained by Wang and Uhlenbeck to describe the Brownian motion of a classical oscillator. The Fokker-Planck equation is solved for the conditional probability (Green's function) which is found to be in the form of a two-dimensional Gaussian distribution. This solution is then used to obtain various time-dependent quantum statistical properties of the oscillator. Next, the entropy for a quantum oscillator undergoing Brownian motion is calculated and we show that this system approaches equilibrium as $t\ensuremath{\rightarrow}\ensuremath{\infty}$. Finally we show that in the weak-coupling limit the Fokker-Planck equation reduces to the one obtained by making the usual rotating-wave approximation.
We study the behavior of two weakly coupled quantum systems, described by a separable density operator. One of them is a single oscillator, representing a microscopic system, while the other is a set of oscillators, which perform the role of a reservoir in thermal equilibrium. From the Liouville-Von Neumann equation for the reduced density operator, we devise the master equation that governs the evolution of the microscopic system, incorporating the effects of temperature via Thermofield Dynamics formalism and suitably redefining the vacuum of the macroscopic system. As applications, we study an oscillator interacting with a set of boson oscillators at finite temperature, usually employed in quantum mechanics to describe a Brownian particle; and investigate the behavior of an oscillator in the presence of a heat bath consisting of a set of fermion oscillators.
We develop an exact analytical framework for studying the nonequilibrium dynamics of interacting quantum harmonic oscillators coupled to a modelled thermal reservoir and driven by external classical fields. The total Hamiltonian is diagonalized via successive Bogoliubov transformations, enabling a nonperturbative treatment of dissipation and driving. For two coupled oscillators with an external source applied to the first, we derive explicit energy expressions and analyze their dependence on coupling and bath parameters. The phase-space structure is characterized through Husimi QQQ-functions for initial separable coherent and number states. We obtain the reduced density matrix elements in the number-state basis and demonstrate that, in the absence of driving and at zero temperature, the reduced density matrix of the main system satisfies the Lindblad master equation. A generating function for the Husimi function is introduced to facilitate computation of higher-order correlations. The analysis is then generalized to nnn interacting oscillators, with analytical energy expressions provided and the case n=3n=3n=3 examined in detail. Our results establish a versatile and exact framework for driven-dissipative quantum systems, with potential applications in quantum thermodynamics, open quantum systems, and many-body physics.
Abstract After replacing the reduced density matrix of a quantum harmonic oscillator linearly coupled to a thermal bath by its ‘characteristic function’ (a non-negative definite function defined on the Heisenberg-Weyl group), the master equation of the reduced density matrix can be transformed into a first-order linear partial differential equation of the characteristic function. We derive stationary solutions for the Caldeira–Leggett (CL) master equation as well as for the late-time Hu–Paz–Zhang master equation, and examine the positivity problem for these solutions. In order to illustrate to what extent classical properties of quantum states of the damping oscillator emerge dynamically due to coupling to the environment, we discuss the problem of how and under what conditions a steady state predicted by the CL master equation could be expressed as a statistical mixture of Gaussian packets having a uniform position variance. Similar studies are carried out for the solutions of a Lindblad-form generalization of the CL master equation, where the positivity problem is certainly absent. Our results show that in the low-temperature regime the steady states predicted by the Lindblad-type master equation may depend on the damping strength of the bath and there are cases which may not show Gaussian-packet decomposition.
We use a generalized Bogoliubov transformation to construct a set of transformed occupation number states of the harmonic oscillator in the Liouville space. General expressions for the expansion coefficients of these states in the bare number basis are obtained and the properties of these states investigated. The transformation is non-dynamical in nature and divides the transformed basis into disconnected correlation subspaces under the transformation. The basis is complete and orthonormal. Elements of the basis are in general mixed states, and the state with the lowest number indices is the thermal vacuum. Since the Kossakowski–Lindblad (KL) equation remains form invariant under the same transformation, the transformation parameter can be identified to the thermal parameter of the master equation. The transformed states then acquire thermal property through this connection. We also work out the explicit expressions of the transformation matrices between the transformed states and the eigenstates of the KL equation for different temperatures.
Using the parametrically driven harmonic oscillator as a working example, we study two different Markovian approaches to the quantum dynamics of a periodically driven system with dissipation. In the simpler approach, the driving enters the master equation for the reduced density operator only in the Hamiltonian term. An improved master equation is achieved by treating the entire driven system within the Floquet formalism and coupling it to the reservoir as a whole. The different ensuing evolution equations are compared in various representations, particularly as Fokker-Planck equations for the Wigner function. On all levels of approximation, these evolution equations retain the periodicity of the driving, so that their solutions have Floquet form and represent eigenfunctions of a nonunitary propagator over a single period of the driving. We discuss asymptotic states in the long-time limit as well as the conservative and the high-temperature limits. Numerical results obtained within the different Markov approximations are compared with the exact path-integral solution. The application of the improved Floquet-Markov scheme becomes increasingly important when considering stronger driving and lower temperatures.