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arXiv:quant-ph/9908078

Identity, Geometry, Permutation And The Spin-Statistics Theorem

Michael J. York

Published Aug 25, 1999• 6 citations
arXivHTMLPDF

Abstract

We examine historic formulations of the spin-statistics theorem from a point of view that distinguishes between the observable consequences and the ``symmetrization postulate''. In particular, we make a critical analysis of concepts of particle identity, state distinguishability and permutation, and particle ``labels''. We discuss how to construct unique state vectors and the nature of the full state descriptions required for this -- in particular the elimination of arbitrary $2π$ rotations on fermion spin quantization frames and argue that the failure to do this renders the conventional symmetrization postulate (and previous ``proofs'' of it) at best {\em incomplete}. We discuss particle permutation in a general way for any pairs of particles, whether identical or not, and make an essential distinction between exchange and pure permutation. We prove a revised symmetrization postulate that allows us to construct state vectors that are naturally symmetric under pure permutation, {\em for any spin}. The significance of particle labels (which, in the exchange operation, are not permuted along with other variables) is then that they stand in for any asymmetry (order dependence) that is present in the full state descriptions necessary for unique state vectors but not explicit in the regular state variables. {\em The exchange operation is then the physical transformation that reverses any asymmetry implicit in the labels}. We point out a previously unremarked geometrical asymmetry between all pairs of particles that is present whenever we choose a common frame of reference. We compute the exchange phase for various state vectors using different spin quantization frames, and prove the Pauli Exclusion Principle and its generalization to arbitrary spin.

DOI
10.48550/arxiv.quant-ph/9908078

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The treatment of identical particles in quantum mechanics rests on two (related) principles: the spin‐statistics connection and the Symmetrization Postulate. In light of recent theories (such as q‐deformed commutators) that allow for ‘small’ violations of the spin‐statistics connection and the Symmetrization Postulate, we revisit the issue of how quantum mechanics deals with identical particles and how it supports or fails to support various philosophical stances concerning individuality. As a consequence of the expanded possibilities for quantum statistics, we argue that permutation symmetry is best formulated as a formal property of the state function describing the system of particles rather than as a property of the individual particles.1 Introduction2 Philosophical background2.1 Important terminology2.1.1 Identity2.1.2 Indistinguishability2.1.3 Indiscernibility2.2 When are particles indistinguishable?2.3 The Principle of the Identity of Indiscernibles and quantum mechanics2.4 The Principle of the Identity of Indiscernibles and logic2.5 Particle history2.6 Transcendental individuality3 Some quantum formalism3.1 The Principle of Permutation Invariance and the Symmetrization Postulate3.2 The configuration‐space approach3.3 Commutators and anticommutators, and identical particle statistics3.4 Q‐mutators4 Identical particle statistics: a holistic point of view5 Conclusions

The British Journal for the Philosophy of Science•Sep 1, 2002•20 citations
We examine historic formulations of the spin-statistics theorem from a point of view that distinguishes between the observable consequences and the symmetrization postulate''. In particular, we make a critical analysis of concepts of particle identity, state distinguishability and permutation, and particle labels''. We discuss how to construct unique state vectors and the nature of the full state descriptions required for this -- in particular the elimination of arbitrary 2π2π2π rotations on fermion spin quantization frames and argue that the failure to do this renders the conventional symmetrization postulate (and previous ``proofs'' of it) at best {\em incomplete}. We discuss particle permutation in a general way for any pairs of particles, whether identical or not, and make an essential distinction between exchange and pure permutation. We prove a revised symmetrization postulate that allows us to construct state vectors that are naturally symmetric under pure permutation, {\em for any spin}. The significance of particle labels (which, in the exchange operation, are not permuted along with other variables) is then that they stand in for any asymmetry (order dependence) that is present in the full state descriptions necessary for unique state vectors but not explicit in the regular state variables. {\em The exchange operation is then the physical transformation that reverses any asymmetry implicit in the labels}. We point out a previously unremarked geometrical asymmetry between all pairs of particles that is present whenever we choose a common frame of reference. We compute the exchange phase for various state vectors using different spin quantization frames, and prove the Pauli Exclusion Principle and its generalization to arbitrary spin.
We discuss the conditions under which identical particles may yet be distinguishable and the relationship between particle permutation and exchange. We show that we can always define permutation-symmetric state vectors. When the particles are completely indistinguishable, then exchange is equivalent to permutation and therefore the exchange eigenvalue for such permutation-symmetric state vectors is always +1. Exchange asymmetry arises when the particles are physically distinguishable, even though otherwise identical, and can be computed from the transformations that arise when the distinguishing features are reversed. There is a fundamental spatial asymmetry between the relative orientations of any two vectors in a common frame of reference that persists even in the limit that the vectors coincide. For a pair of particles this asymmetry between their spin quantization frames renders them distinguishable even when otherwise identical. In the conventional construction, this distinction is not properly accounted for. Particle exchange is then equivalent to reversing this relative orientation --- which requires a relative rotation by 2pi on the spin quantization frame of one particle with respect to the other, thus resulting in the conventional exchange phase.
We consider the implications of the Revised Symmetrization Postulate (see quant-ph/9908078) for states of more than two particles. We show how to create permutation symmetric state vectors and how to derive alternative state vectors that may be asymmetric for any pair by creating asymmetric interdependencies in their state descriptions. Because we can choose any pair to create such an asymmetry, the usual generalized exclusion rules which result, apply simultaneously to any pair. However, we distinguish between simultaneous pairwise exclusion rules and the simultaneous pairwise anti-symmetry of the conventional symmetrization postulate. We show how to construct a variety of state vectors with multiple interdependencies in their state descriptions and various exchange asymmetries - including one which is anti-symmetric under exchange of two bosons - all without violating the spin-statistics theorem. We conjecture that it is possible to construct state vectors for arbitrary mixes of bosons and fermions that emulate the conventional symmetrization postulate in a limited way and give examples. We also prove that it is not possible to define a single state vector that simultaneously obeys the conventional symmetrization postulate in its standard form (in which the exchange phase does not depend on the spins of additional particles that are present) for every pair that can be interchanged.
Abstract. Reasonable requirements of (a) physical invariance under particle permutation and (b) physical completeness of state descriptions [1], enable us to deduce a Symmetric Permutation Rule(SPR): that by taking care with our state descriptions, it is always possible to construct state vectors (or wave functions) that are purely symmetric under pure permutation for all particles, regardless of type distinguishability or spin. The conventional exchange antisymmetry for two identical half-integer spin particles is shown to be due to a subtle interdependence in the individual state descriptions arising from an inherent geometrical asymmetry. For three or more such particles, however, antisymmetrization of the state vector for all pairs simultaneously is shown to be impossible and the SPR makes observably different predictions, although the usual pairwise exclusion rules are maintained. The usual caveat of fermion antisymmetrization – that composite integer spin particles (with fermionic consitituents) behave only approximately like bosons – is no longer necessary. I TERMINOLOGY
Reasonable requirements of (a) physical invariance under particle permutation and (b) physical completeness of state descriptions [1], enable us to deduce a Symmetric Permutation Rule(SPR): that by taking care with our state descriptions, it is always possible to construct state vectors (or wave functions) that are purely symmetric under pure permutation for all particles, regardless of type distinguishability or spin. The conventional exchange antisymmetry for two identical half-integer spin particles is shown to be due to a subtle interdependence in the individual state descriptions arising from an inherent geometrical asymmetry. For three or more such particles, however, antisymmetrization of the state vector for all pairs simultaneously is shown to be impossible and the SPR makes observably different predictions, although the usual pairwise exclusion rules are maintained. The usual caveat of fermion antisymmetrization—that composite integer spin particles (with fermionic constituents) behave only approximately like bosons—is no longer necessary.
The symmetrization postulate (SP) states that wave functions are either completely symmetric or completely antisymmetric under permutations of identical particles. It is shown by one-dimensional counter-examples that SP is not demanded by the usual physical interpretation of the mathematical formalism of wave mechanics unless one makes use of further physical properties of real systems; the error in a standard proof of SP which ignores these properties is pointed out. It is then proved that SP is true for those systems of spinless particles which have the following properties: (a) probability densities are permutation-invariant, (b) allowable wave functions are continuous with continuous gradient, (c) the 3n3n3n-dimensional configuration space is connected, (d) the Hamiltonian is symmetric, and (e) the nodes of allowed wave functions have certain properties. The counterexamples show that SP is not a necessary property of those systems which do not have property (c). The proof is extended to particles with internal degrees of freedom (including spin) by noting that any observable commutes with every permutation and making use of a particular observable acting only on internal variables. Extraneous mathematical assumptions, such as that of the existence of a "complete" set of commuting observables, criticized by Messiah and Greenberg, are not employed. Some comments are made on the conventional nature of the concept of identity for similar particles; the equivalence between the usual formulation in which different species of similar particles are treated as distinct, and that in which they are regarded as identical particles in different internal states, is emphasized.
The treatment of identical particles in quantum mechanics rests on two (related) principles: the spin‐statistics connection and the Symmetrization Postulate. In light of recent theories (such as q‐deformed commutators) that allow for ‘small’ violations of the spin‐statistics connection and the Symmetrization Postulate, we revisit the issue of how quantum mechanics deals with identical particles and how it supports or fails to support various philosophical stances concerning individuality. As a consequence of the expanded possibilities for quantum statistics, we argue that permutation symmetry is best formulated as a formal property of the state function describing the system of particles rather than as a property of the individual particles.1 Introduction2 Philosophical background2.1 Important terminology2.1.1 Identity2.1.2 Indistinguishability2.1.3 Indiscernibility2.2 When are particles indistinguishable?2.3 The Principle of the Identity of Indiscernibles and quantum mechanics2.4 The Principle of the Identity of Indiscernibles and logic2.5 Particle history2.6 Transcendental individuality3 Some quantum formalism3.1 The Principle of Permutation Invariance and the Symmetrization Postulate3.2 The configuration‐space approach3.3 Commutators and anticommutators, and identical particle statistics3.4 Q‐mutators4 Identical particle statistics: a holistic point of view5 Conclusions