We consider quantum mechanics on constrained surfaces which have non-Euclidean metrics and variable Gaussian curvature. The old controversy about the ambiguities involving terms in the Hamiltonian of order ${\ensuremath{\Elzxh}}^{2}$ multiplying the Gaussian curvature is addressed. We set out to clarify the matter by considering constraints to be the limits of large restoring forces as the constraint coordinates deviate from their constrained values. We find additional ambiguous terms of order ${\ensuremath{\Elzxh}}^{2}$ involving freedom in the constraining potentials, demonstrating that the classical constrained Hamiltonian or Lagrangian cannot uniquely specify the quantization: the ambiguity of directly quantizing a constrained system is inherently unresolvable. However, there is never any problem with a physical quantum system, which cannot have infinite constraint forces and always fluctuates around the mean constraint values. The issue is addressed from the perspectives of adiabatic approximations in quantum mechanics and Feynman path integrals, and semiclassically in terms of adiabatic actions.
We consider quantum mechanics on constrained surfaces which have non-Euclidean metrics and variable Gaussian curvature. The old controversy about the ambiguities involving terms in the Hamiltonian of order \ensuremath\Elzxh2 multiplying the Gaussian curvature is addressed. We set out to clarify the matter by considering constraints to be the limits of large restoring forces as the constraint coordinates deviate from their constrained values. We find additional ambiguous terms of order \ensuremath\Elzxh2 involving freedom in the constraining potentials, demonstrating that the classical constrained Hamiltonian or Lagrangian cannot uniquely specify the quantization: the ambiguity of directly quantizing a constrained system is inherently unresolvable. However, there is never any problem with a physical quantum system, which cannot have infinite constraint forces and always fluctuates around the mean constraint values. The issue is addressed from the perspectives of adiabatic approximations in quantum mechanics and Feynman path integrals, and semiclassically in terms of adiabatic actions.
We discuss the introduction of constraints in a system of n noninteracting particles which obey the laws of nonrelativistic quantum mechanics. In this paper the particles are first thought of as being unconstrained (described by the 3n Cartesian coordinates of a flat space R), but subject to an external potential V which, in a certian suitable limit, forces the system to remain in a curved subspace V of R. This idea was already employed in a previous work where we have discussed the motion of one constrained particle. It was then shown that in order to obtain a meaningful result the particle wave function should be "uniformly compressed" into a surface (or curve), avoiding, in this way, the tangential forces which correspond to the dissipative constraints of classical mechanics. The resulting Schr\"odinger equation could then be separated in such a way that the part which contained the surface (or curve) variables was independent of the potential V employed in the constraining process. In the present paper we show that this procedure cannot be carried out for all subspaces V of R in the case of a many-particle system, unless V satisfies a certain geometrical condition. The many-particle Schr\"odinger equation (as was already the case of the one-particle systems) contains, besides the kinetic energy term, potentials which are not bending invariants, that is, cannot be obtained from the metric tensor gij of V or its derivatives. This gives rise to different Schr\"odinger equations for isometric subspaces, in striking contrast with the usual quantization procedures which start from the classical Lagrangian of the constrained system.
The motion of a particle rigidly bounded to a surface is discussed, considering the Schr\"odinger equation of a free particle constrained to move, by the action of an external potential, in an infinitely thin sheet of the ordinary three-dimensional space. Contrary to what seems to be the general belief expressed in the literature, this limiting process gives a perfectly well-defined result, provided that we take some simple precautions in the definition of the potentials and wave functions. It can then be shown that the wave function splits into two parts: the normal part, which contains the infinite energies required by the uncertainty principle, and a tangent part which contains "surface potentials" depending both on the Gaussian and mean curvatures. An immediate consequence of these results is the existence of different quantum mechanical properties for two isometric surfaces, as can be seen from the bound state which appears along the edge of a folded (but not stretched) plane. The fact that this surface potential is not a bending invariant (cannot be expressed as a function of the components of the metric tensor and their derivatives) is also interesting from the more general point of view of the quantum mechanics in curved spaces, since it can never be obtained from the classical Lagrangian of an a priori constrained particle without substantial modifications in the usual quantization procedures. Similar calculations are also presented for the case of a particle bounded to a curve. The properties of the constraining spatial potential, necessary to a meaningful limiting process, are discussed in some detail, and, as expected, the resulting Schr\"odinger equation contains a "linear potential" which is a function of the curvature.
We present a novel framework for quantizing constrained quantum systems in which the processes of quantization and constraint enforcement are performed simultaneously. The approach is based on an extension of the stationary action principle, incorporating an information-theoretic term arising from vacuum fluctuations. Constraints are included directly in the Lagrangian via Lagrange multipliers, allowing the subsequent variational procedure to yield the quantum dynamics without ambiguity regarding the order of quantization and reduction. We demonstrate the method through two examples: (i) a one-dimensional system with vanishing local momentum, where the simultaneous approach produces the time-independent Schrödinger equation while conventional reduced and Dirac quantization yield only trivial states, and (ii) a bipartite system with global translational invariance, where all three methods agree. These results show that the proposed framework generalizes standard quantization schemes and provides a consistent treatment of systems with constraints that cannot be expressed as linear operators acting on the wave function. In addition to a unified variational principle for constrained quantum systems, the formalism also offers an information-theoretic perspective on quantum effects arising from vacuum fluctuations.
This dissertation addresses the problem of constructing true degrees of freedom in quantum mechanical systems with constraints. The method developed relies on assuming the behavior of the system of interest is ``nearly classical', or semiclassical, in a precise quantitative sense. The approximation is formulated as a perturbative hierarchy of the expectation values of quantum observables and their non-linear combinations, such as spreads and correlations. We formulate the constraint conditions and additional quantum gauge transformations that arise directly on the aforementioned quantities. We specialize this framework to several situations of particular interest. The first situation considered is the case of a constraint that commutes with all quantum observables, which is appropriate for quantization of a Lie algebra with a single Casimir polynomial. Through explicit order-by order counting argue that the true degrees of freedom are captured correctly at each order of the approximation. The rest of the models considered are motivated by the canonical approach to quantizing general relativity. The homogeneous sector of general relativity splits into classes of models, according to topology, which are described by a finite number of degrees of freedom and can therefore be quantized as quantum mechanical systems, making our construction directly applicable. In the Hamiltonian formulation the dynamics of these systems is governed by the Hamiltonian constraint, which, in the quantum theory, gives rise to several conceptual and technical issues collectively known as the Problem of Time. One of the aspects of this problem that does not possess a general solution is the dynamical interpretation of the theory. We use our construction, truncated at the leading order in quantum corrections, together with the intuition gained from dealing with constrained systems in classical mechanics, to define local notion of dynamics relative to a chosen configuration clock variable. We consider a class of models, where the chosen clock in not globally valid, eventually leading to singular dynamics. Within these models we construct an explicit transformation between dynamical evolution relative to two distinct clocks, thus providing a consistent local dynamical interpretation of the true degrees of freedom of the quantum theory.
We derive an effective Hamiltonian for a quantum system constrained to a submanifold (the constraint manifold) of configuration space (the ambient space) by an infinite restoring force. We pay special attention to how this Hamiltonian depends on quantities which are external to the constraint manifold, such as the extrinsic curvature of the constraint manifold, the curvature of the ambient space, and the constraining potential. In particular, we find the remarkable fact that the twisting of the constraining potential appears as a gauge potential in the constrained Hamiltonian. This gauge potential is closely related to the geometric phase originally discussed by Berry. The constrained Hamiltonian also contains an effective potential depending on the extrinsic curvature of the constraint manifold, the curvature of the ambient space, and the twisting of the constraining potential. The general nature of our analysis allows applications to a wide variety of problems, such as rigid molecules, the evolution of molecular systems along reaction paths, and quantum strip waveguides.
Quantum systems with constraints are often considered in modern theoretical physcics. All realistic field models based on the idea of gauge symmetry are of this type. A partial case of constraints being linear in coordinate and momenta operators is very important. Namely, when one applies semiclassical methods to an arbitrary constrained system, the constraints in "general position case" become linear. In this paper, different mathematicals constructions for the Hilbert space space for the constraint system are discussed. Properties of Gaussian and quasi-Gaussian wave functions for these systems are investigated. An analog of the notion of Maslov complex germ is suggested. Properties of Hamiltonians being quadratic with respect to the coordinate and momenta operators are discussed. The Maslov theorem (it says that there exists a Gaussian eigenfunction of the quantum Hamiltonian iff the classical Hamiltonian system is stable) is generalized to the constrained systems. The case of infinite number degrees of freedom (constrained Fock space) is also discussed.