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arXiv:quant-ph/0611222 · Physical Review A

Lindblad rate equations

Adrián A. Budini

Published Nov 20, 2006• 83 citations
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Abstract

In this paper we derive an extra class of non-Markovian master equations where the system state is written as a sum of auxiliary matrixes whose evolution involve Lindblad contributions with local coupling between all of them, resembling the structure of a classical rate equation. The system dynamics may develop strong nonlocal effects such as the dependence of the stationary properties with the system initialization. These equations are derived from alternative microscopic interactions, such as complex environments described in a generalized Born-Markov approximation and tripartite system-environment interactions, where extra unobserved degrees of freedom mediates the entanglement between the system and a Markovian reservoir. Conditions that guarantee the completely positive condition of the solution map are found. Quantum stochastic processes that recover the system dynamics in average are formulated. We exemplify our results by analyzing the dynamical action of nontrivial structured dephasing and depolarizing reservoirs over a single qubit.

DOI
10.1103/physreva.74.053815

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In this paper we derive an extra class of non-Markovian master equations where the system state is written as a sum of auxiliary matrixes whose evolution involve Lindblad contributions with local coupling between all of them, resembling the structure of a classical rate equation. The system dynamics may develop strong nonlocal effects such as the dependence of the stationary properties with the system initialization. These equations are derived from alternative microscopic interactions, such as complex environments described in a generalized Born-Markov approximation and tripartite system-environment interactions, where extra unobserved degrees of freedom mediates the entanglement between the system and a Markovian reservoir. Conditions that guarantee the completely positive condition of the solution map are found. Quantum stochastic processes that recover the system dynamics in average are formulated. We exemplify our results by analyzing the dynamical action of nontrivial structured dephasing and depolarizing reservoirs over a single qubit.
In this paper we demonstrate that Lindblad equations characterized by a random rate variable arise after tracing out a complex structured reservoir. Our results follows from a generalization of the Born-Markov approximation, which relies on the possibility of splitting the complex environment into a direct sum of subreservoirs, each one being able to induce by itself a Markovian system evolution. Strong non-Markovian effects, which microscopically originate from the entanglement with the different subreservoirs, characterize the average system decay dynamics. As an example, we study the anomalous irreversible behavior of a quantum tunneling system described in an effective two-level approximation. Stretched exponential and power law decay behaviors arise from the interplay between the dissipative and unitary hopping dynamics.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..
By considering single chromophore systems whose radiative decay can be written in terms of a nonlocal Lindblad-type evolution, the authors extend the formalism of generalized optical Bloch equations [Y. Zheng and F. L. H. Brown, Phys. Rev. Lett. 90, 238305 (2003)] to non-Markovian dynamics. They demonstrate that photon statistical properties such as bunching and antibunching, as well as sub- and super-Poissonian photon statistics can be fitted in the context of non-Markovian dynamics. The nonlocal effects may arise due to the interaction with a complex structured environment. In this case, the photon statistics can be related with the parameters that define the microscopic system-environment interaction. Alternatively, the authors demonstrate that effective dynamics such as triplet blinking, where the system is coupled via incoherent transitions to an extra dark state, can also be worked out in terms of generalized non-Markovian optical Bloch equations. The corresponding memory contributions are mapped with those that arise from the microscopic approach.
We deduce a class of non-Markovian completely positive master equations which describe a system in a composite bipartite environment, consisting of a Markovian reservoir and additional stationary unobserved degrees of freedom that modulate the dissipative coupling. The entanglement-induced memory effects can persist for arbitrary long times and affect the relaxation to equilibrium, as well as induce corrections to the quantum-regression theorem. By considering the extra degrees of freedom as a discrete manifold of energy levels, strong non-exponential behaviour can arise, such as for example power law and stretched exponential decays. PACS numbers: 03.65.Yz, 42.50.Lc, 03.65.Ta, 05.40.−a 1.
We study the role of correlations with the environment as the source of non-Markovian quantum evolutions. We first focus on the impact that correlations with the environment can have on the dynamical map that evolve the system. We expand the set of initial states of a system and its environment that are known to guarantee completely positive reduced dynamics for the system when the combined state evolves unitarily. We characterize the correlations in the initial state in terms of its quantum discord. The induced maps can be not completely positive when quantum correlations including, but not limited to, entanglement are present. We discuss the implications and limitations of the Markov approximation necessary to derive the Kossakowski-Lindblad master equation. A generalized non-Markovian master equation is derived from the dynamical map of systems correlated with their environment. The physical meaning of not completely positive maps is studied to obtain a consistent theory of non-Markovian quantum dynamics. These are associated to inverse maps necessary to establish correlations and they give rise to a canonical embedding map that is local in time. This master equation goes beyond the Kossakowski-Lindblad master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory. Through out this discussion, the general dynamics of two interacting qubits is used as an example for illustrations.