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arXiv:quant-ph/0611216

Quantum mechanics in general quantum systems (I): Exact solution

An Min Wang

Published Nov 21, 2006• 0 citations
arXivHTMLPDF

Abstract

Starting from our idea of combining the Feynman path integral spirit and the Dyson series kernel, we find an explicit and general form of time evolution operator that is a $c$-number function and a power series of perturbation including all order approximations in the unperturbed Hamiltonian representation. Based on it, we obtain an exact solution of the Schrödinger equation in general quantum systems independent of time. Comparison of our exact solution with the existed perturbation theory makes some features and significance of our exact solution clear. The conclusions expressly indicate that our exact solution is obviously consistent with the usual time-independent perturbation theory at any order approximation, it explicitly calculates out the expanding coefficients of the unperturbed state in the non-perturbation method, and it fully solves the recurrence equation of the expansion coefficients of final state in the unperturbed Hamiltonian representation from a view of time-dependent perturbation theory. At the same time, the exact solution of the von Neumann equation is also given. Our results can be thought of as theoretical developments of quantum dynamics, and are helpful for understanding the dynamical behavior and related subjects of general quantum systems in both theory and application. Our exact solution, together with its sequence studies on perturbation theory [An Min Wang, quant-ph/0611217] and open system dynamics [An Min Wang, quant-ph/0601051] can be used to establish the foundation of theoretical formulism of quantum mechanics in general quantum systems. Further applications of our exact solution to quantum theory can be expected.

DOI
10.48550/arxiv.quant-ph/0611216

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Starting from our idea of combining the Feynman path integral spirit and the Dyson series kernel, we find an explicit and general form of time evolution operator that is a ccc-number function and a power series of perturbation including all order approximations in the unperturbed Hamiltonian representation. Based on it, we obtain an exact solution of the Schrödinger equation in general quantum systems independent of time. Comparison of our exact solution with the existed perturbation theory makes some features and significance of our exact solution clear. The conclusions expressly indicate that our exact solution is obviously consistent with the usual time-independent perturbation theory at any order approximation, it explicitly calculates out the expanding coefficients of the unperturbed state in the non-perturbation method, and it fully solves the recurrence equation of the expansion coefficients of final state in the unperturbed Hamiltonian representation from a view of time-dependent perturbation theory. At the same time, the exact solution of the von Neumann equation is also given. Our results can be thought of as theoretical developments of quantum dynamics, and are helpful for understanding the dynamical behavior and related subjects of general quantum systems in both theory and application. Our exact solution, together with its sequence studies on perturbation theory [An Min Wang, quant-ph/0611217] and open system dynamics [An Min Wang, quant-ph/0601051] can be used to establish the foundation of theoretical formulism of quantum mechanics in general quantum systems. Further applications of our exact solution to quantum theory can be expected.
By splitting a Hamiltonian into two parts, using the solvability of eigenvalue problem of one part of the Hamiltonian, proving a useful identity and deducing an expansion formula of power of operator binomials, we obtain an explicit and general form of time evolution operator in the representation of solvable part of the Hamiltonian. Further we find out an exact solution of Schrödinger equation in a general time-independent quantum system, and write down its concrete form when the solvable part of this Hamiltonian is taken as the kinetic energy term. Comparing our exact solution with the usual perturbation theory makes some features and significance of our solution clear. Moreover, through deriving out the improved forms of the zeroth, first, second and third order perturbed solutions including the partial contributions from the higher order even all order approximations, we obtain the improved transition probability. In special, we propose the revised Fermi's golden rule. Then we apply our scheme to obtain the improved forms of perturbed energy and perturbed state. In addition, we study an easy understanding example to illustrate our scheme and show its advantage. All of this implies the physical reasons and evidences why our exact solution and perturbative scheme are formally explicit, actually calculable, operationally efficient, conclusively more accurate. Therefore our exact solution and perturbative scheme can be thought of theoretical developments of quantum dynamics. Further applications of our results in quantum theory can be expected.
We first rewrite the perturbation expansion of the time evolution operator [An Min Wang, quant-ph/0611216] in a form as concise as possible. Then we derive out the perturbation expansion of the time-dependent complete Green operator and prove that it is just the Fourier transformation of the Dyson equation. Moreover, we obtain the perturbation expansion of the complete transition amplitude in the Feynman path integral formulism, and give an integral expression that relates the complete transition amplitude with the unperturbed transition amplitude. Further applications of these results can be expected and will be investigated in the near future.
We propose an improved scheme of perturbation theory based on our exact solution [An Min Wang, quant-ph/0611216] in general quantum systems independent of time. Our elementary start-point is to introduce the perturbing parameter as late as possible. Our main skills are Hamiltonian redivision so as to overcome a flaw of the usual perturbation theory, and the perturbing Hamiltonian matrix product decomposition in order to separate the contraction and anti-contraction terms. Our calculational technology is the limit process for eliminating apparent divergences. Our central idea is ``dynamical rearrangement and summation" for the sake of the partial contributions from the high order even all order approximations absorbed in our perturbed solution. Consequently, we obtain the improved forms of the zeroth, first, second and third order perturbed solutions absorbing the partial contributions from the high order even all order approximations of perturbation. Then we deduce the improved transition probability. In special, we propose the revised Fermi's golden rule. Moreover, we apply our scheme to obtain the improved forms of perturbed energy and perturbed state. In addition, we study an easy understanding example of two-state system to illustrate our scheme and show its advantages. All of this implies the physical reasons and evidences why our improved scheme of perturbation theory are actually calculable, operationally efficient, conclusively more accurate. Our improved scheme is the further development and interesting application of our exact solution, and it has been successfully used to study on open system dynamics [An Min Wang, quant-ph/0601051].
We investigate the exact solution, perturbation theory and master equation of open system dynamics based on our serial studies on quantum mechanics in general quantum systems [An Min Wang, quant-ph/0611216 and quant-ph/0611217]. In a system-environment separated representation, a general and explicit solution of open system dynamics is obtained, and it is an exact solution since it includes all order approximations of perturbation. In terms of the cut-off approximation of perturbation and our improved scheme of perturbation theory, the improved form of the perturbed solution of open systems absorbing the partial contributions from the high order even all order approximations is deduced. Moreover, only under the factorizing initial condition, the exact master equation including all order approximations is proposed. Correspondingly, the perturbed master equation and its improved form different from the existed master equation are given. In special, the Redfield master equation is derived out without using Born-Markov approximation. The solution of open system dynamics in the Milburn model is also gained. As examples, Zurek model of two-state open system and its extension with two transverse fields are studied.
Explicitly time-dependent Hamiltonians are ubiquitous in applications of quantum theory. It is therefore necessary to solve the time-dependent Schrödinger equation directly. The system’s dynamics is associated with a unitary time-evolution operator (a propagator), formally given as an infinite Dyson series. Time-dependent observables are invariant under unitary time-dependent transformations, where it is sometimes useful to transform the time-evolution from the states into the corresponding operators. This is carried out in part (in full) by transforming to the interaction (Heisenberg) picture. The corresponding equations of motion for the time-dependent operators are introduced. For quadratic potential energy functions, the time evolution of quantum expectation values coincides with the corresponding classical dynamics. This is demonstrated and analyzed in detail for Gaussian wave packets and a coherent state. Finally, we derive exact and approximate expressions for time-dependent transition probabilities and transition rates between quantum states. The validity of time-dependent perturbation theory is analyzed by comparison to exact dynamics.
We obtain a complete series solution of stationary Schrödinger's equation in the general quantum systems. It is exact in the sense that any approximation means is not used, or that the whole corrections or contributions from all order perturbations are involved if the perturbation concept is introduced. Furthermore, the useful forms of our exact solution and a new expression the complete Green operator are given out. As a universal and analytical solution, it is helpful for the theoretical derivations and practical calculations in quantum theory.