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arXiv:quant-ph/0602055

Exact solution and perturbation theory in a general quantum system

An Min Wang

Published Feb 5, 2006• 0 citations
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Abstract

By splitting a Hamiltonian into two parts, using the solvability of eigenvalue problem of one part of the Hamiltonian, proving a useful identity and deducing an expansion formula of power of operator binomials, we obtain an explicit and general form of time evolution operator in the representation of solvable part of the Hamiltonian. Further we find out an exact solution of Schrödinger equation in a general time-independent quantum system, and write down its concrete form when the solvable part of this Hamiltonian is taken as the kinetic energy term. Comparing our exact solution with the usual perturbation theory makes some features and significance of our solution clear. Moreover, through deriving out the improved forms of the zeroth, first, second and third order perturbed solutions including the partial contributions from the higher order even all order approximations, we obtain the improved transition probability. In special, we propose the revised Fermi's golden rule. Then we apply our scheme to obtain the improved forms of perturbed energy and perturbed state. In addition, we study an easy understanding example to illustrate our scheme and show its advantage. All of this implies the physical reasons and evidences why our exact solution and perturbative scheme are formally explicit, actually calculable, operationally efficient, conclusively more accurate. Therefore our exact solution and perturbative scheme can be thought of theoretical developments of quantum dynamics. Further applications of our results in quantum theory can be expected.

DOI
10.48550/arxiv.quant-ph/0602055

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By splitting a Hamiltonian into two parts, using the solvability of eigenvalue problem of one part of the Hamiltonian, proving a useful identity and deducing an expansion formula of power of operator binomials, we obtain an explicit and general form of time evolution operator in the representation of solvable part of the Hamiltonian. Further we find out an exact solution of Schrödinger equation in a general time-independent quantum system, and write down its concrete form when the solvable part of this Hamiltonian is taken as the kinetic energy term. Comparing our exact solution with the usual perturbation theory makes some features and significance of our solution clear. Moreover, through deriving out the improved forms of the zeroth, first, second and third order perturbed solutions including the partial contributions from the higher order even all order approximations, we obtain the improved transition probability. In special, we propose the revised Fermi's golden rule. Then we apply our scheme to obtain the improved forms of perturbed energy and perturbed state. In addition, we study an easy understanding example to illustrate our scheme and show its advantage. All of this implies the physical reasons and evidences why our exact solution and perturbative scheme are formally explicit, actually calculable, operationally efficient, conclusively more accurate. Therefore our exact solution and perturbative scheme can be thought of theoretical developments of quantum dynamics. Further applications of our results in quantum theory can be expected.
We propose an improved scheme of perturbation theory based on our exact solution [An Min Wang, quant-ph/0611216] in general quantum systems independent of time. Our elementary start-point is to introduce the perturbing parameter as late as possible. Our main skills are Hamiltonian redivision so as to overcome a flaw of the usual perturbation theory, and the perturbing Hamiltonian matrix product decomposition in order to separate the contraction and anti-contraction terms. Our calculational technology is the limit process for eliminating apparent divergences. Our central idea is ``dynamical rearrangement and summation" for the sake of the partial contributions from the high order even all order approximations absorbed in our perturbed solution. Consequently, we obtain the improved forms of the zeroth, first, second and third order perturbed solutions absorbing the partial contributions from the high order even all order approximations of perturbation. Then we deduce the improved transition probability. In special, we propose the revised Fermi's golden rule. Moreover, we apply our scheme to obtain the improved forms of perturbed energy and perturbed state. In addition, we study an easy understanding example of two-state system to illustrate our scheme and show its advantages. All of this implies the physical reasons and evidences why our improved scheme of perturbation theory are actually calculable, operationally efficient, conclusively more accurate. Our improved scheme is the further development and interesting application of our exact solution, and it has been successfully used to study on open system dynamics [An Min Wang, quant-ph/0601051].
Starting from our idea of combining the Feynman path integral spirit and the Dyson series kernel, we find an explicit and general form of time evolution operator that is a ccc-number function and a power series of perturbation including all order approximations in the unperturbed Hamiltonian representation. Based on it, we obtain an exact solution of the Schrödinger equation in general quantum systems independent of time. Comparison of our exact solution with the existed perturbation theory makes some features and significance of our exact solution clear. The conclusions expressly indicate that our exact solution is obviously consistent with the usual time-independent perturbation theory at any order approximation, it explicitly calculates out the expanding coefficients of the unperturbed state in the non-perturbation method, and it fully solves the recurrence equation of the expansion coefficients of final state in the unperturbed Hamiltonian representation from a view of time-dependent perturbation theory. At the same time, the exact solution of the von Neumann equation is also given. Our results can be thought of as theoretical developments of quantum dynamics, and are helpful for understanding the dynamical behavior and related subjects of general quantum systems in both theory and application. Our exact solution, together with its sequence studies on perturbation theory [An Min Wang, quant-ph/0611217] and open system dynamics [An Min Wang, quant-ph/0601051] can be used to establish the foundation of theoretical formulism of quantum mechanics in general quantum systems. Further applications of our exact solution to quantum theory can be expected.
We investigate the exact solution, perturbation theory and master equation of open system dynamics based on our serial studies on quantum mechanics in general quantum systems [An Min Wang, quant-ph/0611216 and quant-ph/0611217]. In a system-environment separated representation, a general and explicit solution of open system dynamics is obtained, and it is an exact solution since it includes all order approximations of perturbation. In terms of the cut-off approximation of perturbation and our improved scheme of perturbation theory, the improved form of the perturbed solution of open systems absorbing the partial contributions from the high order even all order approximations is deduced. Moreover, only under the factorizing initial condition, the exact master equation including all order approximations is proposed. Correspondingly, the perturbed master equation and its improved form different from the existed master equation are given. In special, the Redfield master equation is derived out without using Born-Markov approximation. The solution of open system dynamics in the Milburn model is also gained. As examples, Zurek model of two-state open system and its extension with two transverse fields are studied.
In this paper we prove the following: (1) The basic error of time-dependent perturbation theory is using the sum of first finite order of perturbed solutions to substitute the exact solution in the divergent interval of the series for calculating the transition probability. In addition quantum mechanics neglects the influence of the normality condition in the continuous case. In both cases Fermi golden rule is not a mathematically reasonable deductive inference from the Schrodinger equation. (2) The transition probability per unit time deduced from the exact solution of the Schrodinger equation is zero, which cannot be used to describe the transition processes.
This report discusses two new ideas for using perturbation methods to solve the time-independent Schrödinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix diagonalization methods. That allows a simple, compact derivation of the standard (Rayleigh-Schrödinger) equations. But it also leads to a new iterative solution method that is not based on the usual power series expansion. The iterative method can also be used when the unperturbed system is two-fold degenerate. The second concept is quite different from the first but compatible with it. It is based on the fact that one can replace the true Hamiltonian with a synthetic Hamiltonian having the same eigenvalues. This approach allows one to cancel part of the perturbation and to reduce the size of the off-diagonal matrix elements, giving better convergence of the series. These methods are illustrated by application to three perturbed harmonic oscillator problems--a 1-D oscillator with a linear perturbation, a 1-D oscillator with a quartic perturbation, and a perturbed 2-D oscillator, which involves degenerate states. The iterative method and the synthetic Hamiltonian method are shown to give significantly better results than the standard method.
Quantum mechanics take the sum of first finite order approximate solutions of time-dependent perturbation to substitute the exact solution. From the point of mathematics, it may be correct only in the convergent region of the time-dependent perturbation series. Where is the convergent region of this series? Quantum mechanics did not answer this problem. However it is relative to the question, can we use the Schrodinger equation to describe the transition processes? So it is the most important unsettling problem of physical theory. We find out the time-dependent approximate solution for arbitrary and the exact solution. Then we can prove that: (1) In the neighborhood of the conservation of energy, the series is divergent. The basic error of quantum mechanics is using the sum of the first finite orders approximate solutions to substitute the exact solution in this divergent region. It leads to an infinite error. So the Fermi golden rule is not a mathematically reasonable inference of the. Schrodinger equation (2) The transiton probability per unit time deduced from the exact solution of Schrodinger equation cannot describe the transition processes. This paper is only a prime discussion.