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arXiv:quant-ph/0605208

Entanglement of Quantum States, Thermodynamical Statistical Distributions and Physical Nature of Temperature

A. Yu. Bogdanov, Yu. I. Bogdanov, K. A. Valiev

Published May 24, 2006• 0 citations
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Abstract

Thermodynamical equilibrium is considered as an effect of quantum entangling of the vacuum state of a system. An explicit mathematical model of multi- particle entangled pure quantum states is developed and analyzed. In the framework, the process of measurement results in probability distributions that exactly correspond to the heat equilibrium of a system in a thermostat.

DOI
10.48550/arxiv.quant-ph/0605208

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Thermodynamical equilibrium is considered as an effect of quantum entangling of the vacuum state of a system. An explicit mathematical model of multi- particle entangled pure quantum states is developed and analyzed. In the framework, the process of measurement results in probability distributions that exactly correspond to the heat equilibrium of a system in a thermostat.
Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum systems. In the present contribution a simple but effective theoretical framework is introduced to clarify the connections between a purely mechanical description and the thermodynamic characterization of the equilibrium state of an isolated quantum system. A salient feature of our approach is the very transparent distinction between the statistical aspects and the dynamical aspects in the description of isolated quantum systems. Like in the classical statistical mechanics, the equilibrium distribution of any property is identified on the basis of the time evolution of the considered system. As a consequence equilibrium properties of quantum system appear to depend on the details of the initial state due to the abundance of constants of the motion in the Schrodinger dynamics. On the other hand the study of the probability distributions of some functions, such as the entropy or the equilibrium state of a subsystem, in statistical ensembles of pure states reveals the crucial role of typicality as the bridge between macroscopic thermodynamics and microscopic quantum dynamics. We shall consider two particular ensembles: the random pure state ensemble and the fixed expectation energy ensemble. The relation between the introduced ensembles, the properties of a given isolated system, and the standard quantum statistical description are discussed throughout the presentation. Finally we point out the conditions which should be satisfied by an ensemble in order to get meaningful thermodynamical characterization of an isolated quantum system.
It is shown that quantum mechanics is, like thermodynamics, a phenomenological theory i.e., not a causal theory, ( not because it is a statistical theory - statistical theories with caused probability distributions can be regarded as causal) but because pure states, i.e., probability distributions of measurement values, cannot inhere in elementary particles and therefore cannot change when their world tubes intersect and hence they cannot be regarded as interacting causally. By a causal theory is meant a theory that specifies the changes in time of the states of causally interacting entities in its domain. The areas in quantum mechanics in which causal interactions are relevant include, though not explicitly, measurement and therefore the Born rule, and, explicitly, the unitary Schrodinger time development of states. The Born rule probabilities are shown to to refer not to conjoint superpositions of eigenstates but to classical mixtures of mutually exclusive eigenvalues and the Schrodinger time development of states is shown to refer to the time development of the states of non-causally interacting elementary particles and hence cannot be regarded as as a causal time development equation, appearances to the contrary notwithstanding. The recognition that quantum mechanics is not a causal theory but a phenomenological theory like thermodynamics does not affect the way it is employed to calculate an predict and hence preserves its empirical success but it does allow a typically simple phenomenological theory explanation of entanglement and other apparently non-local phenomena.
Entanglement is one of the most striking features of quantum mechanics, and yet it is not specifically quantum.More specific to quantum mechanics is the connection between entanglement and thermodynamics, which leads to an identification between entropies and measures of pure state entanglement.Here we search for the roots of this connection, investigating the relation between entanglement and thermodynamics in the framework of general probabilistic theories.We first address the question whether an entangled state can be transformed into another by means of local operations and classical communication.Under two operational requirements, we prove a general version of the Lo-Popescu theorem, which lies at the foundations of the theory of pure-state entanglement.We then consider a resource theory of purity where free operations are random reversible transformations, modelling the scenario where an agent has limited control over the dynamics of a closed system.Our key result is a duality between the resource theory of entanglement and the resource theory of purity, valid for every physical theory where all processes arise from pure states and reversible interactions at the fundamental level.As an application of the main result, we establish a one-to-one correspondence between entropies and measures of pure bipartite entanglement.The correspondence is then used to define entanglement measures in the general probabilistic framework.Finally, we show a duality between the task of information erasure and the task of entanglement generation, whereby the existence of entropy sinks (systems that can absorb arbitrary amounts of information) becomes equivalent to the existence of entanglement sources (correlated systems from which arbitrary amounts of entanglement can be extracted).
Thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a theory of quantum thermodynamics that is applicable for arbitrary small systems, even for single particle systems coupled with a reservoir. We generalize the concept of temperature beyond equilibrium that depends on the detailed dynamics of quantum states. We apply the theory to a cavity system and a two-level system interacting with a reservoir, respectively. The results unravels (1) the emergence of thermodynamics naturally from the exact quantum dynamics in the weak system-reservoir coupling regime without introducing the hypothesis of equilibrium between the system and the reservoir from the beginning; (2) the emergence of thermodynamics in the intermediate system-reservoir coupling regime where the Born-Markovian approximation is broken down; (3) the breakdown of thermodynamics due to the long-time non-Markovian memory effect arisen from the occurrence of localized bound states; (4) the existence of dynamical quantum phase transition characterized by inflationary dynamics associated with negative dynamical temperature. The corresponding dynamical criticality provides a border separating classical and quantum worlds. The inflationary dynamics may also relate to the origin of big bang and universe inflation. And the third law of thermodynamics, allocated in the deep quantum realm, is naturally proved.