Enviroment - caused dissipation disrupts the hamiltonian evolution of all quantum systems not fully isolated from any bath. We propose and examine a feedback-control scheme to eliminate such dissipation, by tracking the free hamiltonian evolution. We determine a driving-field that maximizes the projection of the actual molecular system onto the freely propagated one. The evolution of a model two level system in a dephasing bath is followed, and the driving field that overcomes the decoherence is calculated. An implementation of the scheme in the laboratory using feedback control is suggested.
Enviroment - caused dissipation disrupts the hamiltonian evolution of all quantum systems not fully isolated from any bath. We propose and examine a feedback-control scheme to eliminate such dissipation, by tracking the free hamiltonian evolution. We determine a driving-field that maximizes the projection of the actual molecular system onto the freely propagated one. The evolution of a model two level system in a dephasing bath is followed, and the driving field that overcomes the decoherence is calculated. An implementation of the scheme in the laboratory using feedback control is suggested.
A molecular system in contact with a bath undergoes strong decoherence processes. We examine a control scheme to minimize dissipation, while maximally retaining coherent evolution, by relating the evolution of the molecule to that of an identical freely propagating system. We seek a driving field that maximizes the projection of the open molecular system onto the freely propagated one. The evolution in time of a molecular system consisting of two nonadiabatically coupled electronic states interacting with a bath is followed. The driving control field that overcomes the decoherence is calculated. A proposition to implement the scheme in the laboratory using feedback control is suggested.
Any real system, no matter how well isolated, unavoidably interacts with the environment. This interaction makes the evolution of a quantum system nonunitary and destroys the coherence of quantum superpositions. This process, known as decoherence, is widely regarded as the most important and fundamental obstacle to the practical realization of quantum information processing. On the other hand, the objectives of quantum control are predicated on the ability to manipulate the system coherently over a period of time. Quantum control has been applied successfully to several experimental systems and coupling such a controlled system to an environment makes the study of coherence loss possible. The standard model of decoherence is formulated in terms of a system, defined by the observables that can be measured, and a reservoir, de¯ned by those degrees of freedom that are not accessed by observation. The vibrational and rotational degree of freedom of diatomic molecules form an experimental model of such a system and bath 1. The nature of the ro-vibrational coupling does not allow a Decoherence Free Subspace, instead we try to identify a Decoherence Resistant Subspace using closed loop control. We set up a learning control loop experiment to monitor the coherence in a vibrational wavepacket, consisting of about 6 vibrational states of the A(1Σ+g ) electronic state, excited by a shaped, ultrashort optical pulse, and then to determine the pulse shape that yielded the longest coherence lifetime. The coherence of the vibrational wavepacket was monitored by measuring the fluorescence quantum beats from the outer turning point of the wave packet's trajectory. The closed loop controller altered the shape of the driving optical pulse to maximize the the depth of modulation of the quantum beats at a prescribed time after excitation, within the constraints of the laser system. The outcome of this closed loop control experiment shows an improvement of the beat decay constant of about 60%, as shown in Fig. (1), a result which occurs for several di®erent pulse shapes. Our experiments show that a number of interesting decoherence-resistant excitations exist. The nature of the dephasing was examined theoretically. Using measured optical pulse shapes, we simulated numerically the molecular wavepacket in the limit of perturbation theory. The experiment and simulations show that there are di®erent mechanisms contributing to the decoherence resistant excitation. The shaped pulse reduces the °uctuations in the wave packet spatial extent, which in turn changes the system reservoir coupling. Other components of the optimal pulse are a sequence of pulses that creates constructive interference of the vibrational wavepacket at the desired time, and chirp which compensates for the anharmonicity of the adiabatic potential. The experimental results show general agreement with numerical simulations. We conclude that wavepackets resistant to dephasing do exist,and that learning algorithms provide an effcient means for finding them.
In this work we propose a strategy using techniques from systems theory to completely eliminate decoherence and also provide conditions under which it can be done. A construction employing an auxiliary system, the bait, which is instrumental to decoupling the system from the environment is presented. Our approach to decoherence control in contrast to other approaches in the literature involves the bilinear input affine model of quantum control system which lends itself to various techniques from classical control theory, but with nontrivial modifications to the quantum regime. The elegance of this approach yields interesting results on open loop decouplability and decoherence free subspaces. Additionally, the feedback control of decoherence may be related to disturbance decoupling for classical input affine systems, which entails careful application of the methods by avoiding all the quantum mechanical pitfalls. In the process of calculating a suitable feedback the system must be restructured due to its tensorial nature of interaction with the environment, which is unique to quantum systems. In the subsequent section we discuss a general information extraction scheme to gain knowledge of the state and the amount of decoherence based on indirect continuous measurement. The analysis of continuous measurement on a decohering quantum system has not been extensively studied before. Finally, a methodology to synthesize feedback parameters itself is given, that technology permitting, could be implemented for practical 2-qubit systems to perform decoherence free quantum computing. The results obtained are qualitatively different and superior to the ones obtained via master equations.
We present a theory for controlling the dynamics of a dissipative, quantum system with a laser field optimized locally in time. The theory is applicable to both weak and strong field control of the quantum dynamics. The theoretical groundwork is based on the equation of motion of the density matrix in Liouville space. Interactions between the molecules and the heat bath are taken into account within a Markov approximation. The derivation of the locally optimized laser field in a feedback form is based on the local optimization theory in the Hilbert space, proposed in a previous paper [M. Sugawara and Y. Fujimura, J. Chem. Phys. 100, 5646 (1994)]. The theory is applied to a simple, two-level quantum system with a dephasing constant. We present both the calculated time evolution of the off-diagonal density matrix element and that of the population of the states in the optimized laser field. These calculations show that the control of the system by the laser field is sufficient to avoid the dephasing effects. We discuss how the dephasing dynamics affects the optimization of the laser field.
Keeping a quantum system in a given instantaneous eigenstate is a control problem with numerous applications, e.g., in quantum information processing. The problem is even more challenging in the setting of open quantum systems, where environment-mediated transitions introduce additional decoherence channels. Adiabatic passage is a well-established solution but requires a sufficiently slow evolution time that is dictated by the adiabatic theorem. Here we develop a systematic projection theory formulation for the transitionless evolution of general open quantum systems described by time-local master equations. We derive a time-convolutionless dynamical equation for the target instantaneous eigenstate of a given time-dependent Hamiltonian. A transitionless dynamics then arises in terms of a competition between the average Hamiltonian gap and the decoherence rate, which implies optimal adiabaticity timescales. We show how eigenstate tracking can be accomplished via control pulses, without explicitly incorporating counter-diabatic driving, thus offering an alternative route to accelerate adiabaticity. We examine rectangular pulses, chaotic signals, and white noise, and find that, remarkably, the effectiveness of eigenstate tracking hardly depends on the details of the control functions. In all cases the control protocol keeps the system in the desired instantaneous eigenstate throughout the entire evolution, along an accelerated adiabatic path.
A scheme to drive and manipulate a finite-dimensional quantum system in decoherence-free subspaces (DFSs) by Lyapunov control is proposed. Control fields are established by the Lyapunov function. This proposal can drive the open quantum system into DFSs and manipulate it to any desired eigenstate of the free Hamiltonian. An example which consists of a four-level system with three long-lived states driven by two lasers is presented to demonstrate the scheme. We have performed numerical simulations of the dynamics of the four-level system, which show that the scheme works well.