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arXiv:quant-ph/0511076 · Physical Review E

Non-Hamiltonian commutators in quantum mechanics

Alessandro Sergi

Published Dec 29, 2005• 48 citations
arXivHTMLPDF

Abstract

The symplectic structure of quantum commutators is first unveiled and then exploited to describe generalized non-Hamiltonian brackets in quantum mechanics. It is easily recognized that quantum-classical systems are described by a particular realization of such a bracket. In light of previous work, this paper explains a unified approach to classical and quantum-classical non-Hamiltonian dynamics. In order to illustrate the use of non-Hamiltonian commutators, it is shown how to define thermodynamic constraints in quantum-classical systems. In particular, quantum-classical Nosé-Hoover equations of motion and the associated stationary density matrix are derived. The non-Hamiltonian commutators for both Nosé-Hoover chains and Nosé-Andersen (constant-pressure, constant-temperature) dynamics are also given. Perspectives of the formalism are discussed.

DOI
10.1103/physreve.72.066125

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The symplectic structure of quantum commutators is first unveiled and then exploited to describe generalized non-Hamiltonian brackets in quantum mechanics. It is easily recognized that quantum-classical systems are described by a particular realization of such a bracket. In light of previous work, this paper explains a unified approach to classical and quantum-classical non-Hamiltonian dynamics. In order to illustrate the use of non-Hamiltonian commutators, it is shown how to define thermodynamic constraints in quantum-classical systems. In particular, quantum-classical Nosé-Hoover equations of motion and the associated stationary density matrix are derived. The non-Hamiltonian commutators for both Nosé-Hoover chains and Nosé-Andersen (constant-pressure, constant-temperature) dynamics are also given. Perspectives of the formalism are discussed.
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In principle, non-Hermitian quantum equations of motion can be formulated using as a starting point either the Heisenberg's or the Schrödinger's picture of quantum dynamics. Here it is shown in both cases how to map the algebra of commutators, defining the time evolution in terms of a non-Hermitian Hamiltonian, onto a non-Hamiltonian algebra with a Hermitian Hamiltonian. The logic behind such a derivation is reversible, so that any Hermitian Hamiltonian can be used in the formulation of non-Hermitian dynamics through a suitable algebra of generalized (non-Hamiltonian) commutators. These results provide a general structure (a template) for non-Hermitian equations of motion to be used in the computer simulation of open quantum systems dynamics.
In principle, non-Hermitian quantum equations of motion can be formulated using as a starting point either the Heisenberg's or the Schrödinger's picture of quantum dynamics. Here it is shown in both cases how to map the algebra of commutators, defining the time evolution in terms of a non-Hermitian Hamiltonian, onto a non-Hamiltonian algebra with a Hermitian Hamiltonian. The logic behind such a derivation is reversible, so that any Hermitian Hamiltonian can be used in the formulation of non-Hermitian dynamics through a suitable algebra of generalized (non-Hamiltonian) commutators. These results provide a general structure (a template) for non-Hermitian equations of motion to be used in the computer simulation of open quantum systems dynamics.
In principle, non-Hermitian quantum equations of motion can be formulated using as a starting point either the Heisenberg’s or the Schrdinger’s picture of quantum dynamics. Here it is shown in both cases how to map the algebra of commutators, defining the time evolution in terms of a non-Hermitian Hamiltonian, onto a non-Hamiltonian algebra with a Hermitian Hamiltonian. The logic behind such a derivation is reversible, so that any Hermitian Hamiltonian can be used in the formulation of non-Hermitian dynamics through a suitable algebra of generalized (non-Hamiltonian) commutators. These results provide a general structure (a template) for non-Hermitian equations of motion to be used in the computer simulation of open quantum systems dynamics.
In this paper we review an approach to the dynamics of open quantum systems based of non-Hermitian Hamiltonians. Non-Hermitian Hamiltonians arise naturally when one wish to study a subsystem interacting with a continuum of states. Moreover, quantum subsystems with probability sinks or sources are naturally described by non-Hermitian Hamiltonians. Herein, we discuss a non-Hermitian formalism based on the density matrix. We show both how to derive the equations of motion of the density matrix and how to define statistical averages properly. It turns out that the laws of evolution of the normalized density matrix are intrinsically non-linear. We also show how to define correlation functions and a non-Hermitian entropy with a non zero production rate. The formalism has been generalized to the case of hybrid quantum-classical systems using a partial Wigner representation. The equations of motion and the statistical averages are defined analogously to the pure quantum case. However, the definition of the entropy requires to introduce a non-Hermitian linear entropy functional.